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Renewable hydrogen generation by steam reforming of glycerol over zirconia promoted ceria supported catalyst

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  • Dave, Chirag D.
  • Pant, K.K.

Abstract

The study focuses on hydrogen production from steam reforming of glycerol over nickel based catalyst promoted by zirconia and supported over ceria. Catalyst was prepared by the wet-impregnation method and characterized by BET surface area analysis, X-ray diffraction technique and scanning electron microscopy (SEM) analysis. The performance of the catalyst was evaluated in terms of hydrogen yield, selectivity and glycerol conversion at 700°C in a tubular fixed bed reactor. The effect of glycerol concentration in feed, space time (W/FAO), temperature and time on stream (TOS) was analyzed for the catalyst Ni–ZrO2/CeO2 which showed the complete conversion of glycerol and high H2 yield that corresponds to 3.95mol of H2 out of 7mol. Thermodynamic analysis was also carried out using Aspen HYSYS for system having glycerol concentration 10wt% and 20wt% and experimental results were compared with thermodynamics. Kinetic study was carried out for the steam reforming of glycerol over Ni–ZrO2/CeO2 catalyst using the power law model. The values of activation energy and order of reaction were found to be 43.4kJ/mol and 0.3 respectively.

Suggested Citation

  • Dave, Chirag D. & Pant, K.K., 2011. "Renewable hydrogen generation by steam reforming of glycerol over zirconia promoted ceria supported catalyst," Renewable Energy, Elsevier, vol. 36(11), pages 3195-3202.
    • Handle: RePEc:eee:renene:v:36:y:2011:i:11:p:3195-3202
    DOI: 10.1016/j.renene.2011.03.013
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    References listed on IDEAS

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    1. Adhikari, Sushil & Fernando, Sandun D. & Haryanto, Agus, 2008. "Hydrogen production from glycerin by steam reforming over nickel catalysts," Renewable Energy, Elsevier, vol. 33(5), pages 1097-1100.
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    1. Nicolas Abatzoglou & Clémence Fauteux-Lefebvre, 2016. "Review of catalytic syngas production through steam or dry reforming and partial oxidation of studied liquid compounds," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 5(2), pages 169-187, March.
    2. Pravakar Mohanty & Kamal K. Pant & Ritesh Mittal, 2015. "Hydrogen generation from biomass materials: challenges and opportunities," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 4(2), pages 139-155, March.
    3. Hajjaji, Noureddine & Baccar, Ines & Pons, Marie-Noëlle, 2014. "Energy and exergy analysis as tools for optimization of hydrogen production by glycerol autothermal reforming," Renewable Energy, Elsevier, vol. 71(C), pages 368-380.
    4. Díaz, Gisel Chenard & Tapanes, Neyda de la C. Om & Câmara, Leôncio Diógenes T. & Aranda, Donato A.G., 2014. "Glycerol conversion in the experimental study of catalytic hydrolysis of triglycerides for fatty acids production using Ni or Pd on Al2O3 or SiO2," Renewable Energy, Elsevier, vol. 64(C), pages 113-122.
    5. Palma, Vincenzo & Ruocco, Concetta & Ricca, Antonio, 2018. "Oxidative steam reforming of ethanol in a fluidized bed over CeO2-SiO2 supported catalysts: effect of catalytic formulation," Renewable Energy, Elsevier, vol. 125(C), pages 356-364.
    6. Silva, Joel M. & Soria, M.A. & Madeira, Luis M., 2015. "Challenges and strategies for optimization of glycerol steam reforming process," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1187-1213.
    7. Dou, Binlin & Song, Yongchen & Wang, Chao & Chen, Haisheng & Xu, Yujie, 2014. "Hydrogen production from catalytic steam reforming of biodiesel byproduct glycerol: Issues and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 950-960.
    8. Hajjaji, Noureddine & Chahbani, Amna & Khila, Zouhour & Pons, Marie-Noëlle, 2014. "A comprehensive energy–exergy-based assessment and parametric study of a hydrogen production process using steam glycerol reforming," Energy, Elsevier, vol. 64(C), pages 473-483.
    9. Nahar, Gaurav & Dupont, Valerie, 2014. "Hydrogen production from simple alkanes and oxygenated hydrocarbons over ceria–zirconia supported catalysts: Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 777-796.
    10. Abel Rodrigues & João Carlos Bordado & Rui Galhano dos Santos, 2017. "Upgrading the Glycerol from Biodiesel Production as a Source of Energy Carriers and Chemicals—A Technological Review for Three Chemical Pathways," Energies, MDPI, vol. 10(11), pages 1-36, November.

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