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Dynamic small-scale green ammonia non-renewable and renewable exergy costs up to 2050: Short and long-term projections under IEA energy transition scenarios

Author

Listed:
  • Lima, Alessandro
  • Torrubia, Jorge
  • Torres, César
  • Valero, Alicia
  • Valero, Antonio

Abstract

Ammonia is currently indispensable for fertilizers and is projected to be a fundamental renewable energy vector. This study analyzes the non-renewable and renewable exergy costs associated with a small-scale green ammonia plant under different combinations of water electrolysis technologies (AWE, PEM, SOEC, and AEM) with electricity sources (hydro, wind, photovoltaic, and electricity grid). Our method accounts for both the exergy conversion efficiencies of primary energy sources and the required materials on the infrastructures of the renewables and electrolyzers. Our research projects current, short-term (2030) and long-term (2050) ammonia’s exergy cost based on different IEA’s energy transition scenarios. Our findings highlight the impact of non-renewable exergy consumption on the renewables and electrolyzers infrastructures on ammonia exergy costs. In 2025, these values range between 12.5 and 32.5 MWh/tNH3 whereas in 2050 they might range between 11.5 and 19.1 MWh/tNH3 for SOEC-hydro and PEM-AWE-electricity grid scenarios, respectively. A Grassmann diagram illustrates how non-renewable and renewable exergy costs are split throughout the natural resources of our plant. A discussion about the model’s main features, restrictions and future industrial symbiosis possibilities (Ar, H2, O2) is presented. Our innovative methodology emphasizes the origins of natural resources by conscientiously evaluating their non-renewable and renewable exergy costs.

Suggested Citation

  • Lima, Alessandro & Torrubia, Jorge & Torres, César & Valero, Alicia & Valero, Antonio, 2026. "Dynamic small-scale green ammonia non-renewable and renewable exergy costs up to 2050: Short and long-term projections under IEA energy transition scenarios," Renewable Energy, Elsevier, vol. 256(PB).
  • Handle: RePEc:eee:renene:v:256:y:2026:i:pb:s0960148125015551
    DOI: 10.1016/j.renene.2025.123891
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    1. Blay-Roger, Rubén & Bach, Wolfgang & Bobadilla, Luis F. & Reina, Tomas Ramirez & Odriozola, José A. & Amils, Ricardo & Blay, Vincent, 2024. "Natural hydrogen in the energy transition: Fundamentals, promise, and enigmas," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    2. Asim Kumar Sarker & Abul Kalam Azad & Mohammad G. Rasul & Arun Teja Doppalapudi, 2023. "Prospect of Green Hydrogen Generation from Hybrid Renewable Energy Sources: A Review," Energies, MDPI, vol. 16(3), pages 1-17, February.
    3. Valero, Antonio & Palacino, Bárbara & Ascaso, Sonia & Valero, Alicia, 2022. "Exergy assessment of topsoil fertility," Ecological Modelling, Elsevier, vol. 464(C).
    4. Flórez-Orrego, Daniel & de Oliveira Junior, Silvio, 2017. "Modeling and optimization of an industrial ammonia synthesis unit: An exergy approach," Energy, Elsevier, vol. 137(C), pages 234-250.
    5. César Torres & Antonio Valero, 2021. "The Exergy Cost Theory Revisited," Energies, MDPI, vol. 14(6), pages 1-42, March.
    6. Stefano Mingolla & Paolo Gabrielli & Alessandro Manzotti & Matthew J. Robson & Kevin Rouwenhorst & Francesco Ciucci & Giovanni Sansavini & Magdalena M. Klemun & Zhongming Lu, 2024. "Effects of emissions caps on the costs and feasibility of low-carbon hydrogen in the European ammonia industry," Nature Communications, Nature, vol. 15(1), pages 1-23, December.
    7. Eckl, Florentin & Moita, Ana & Castro, Rui & Neto, Rui Costa, 2025. "Valorization of the by-product oxygen from green hydrogen production: A review," Applied Energy, Elsevier, vol. 378(PA).
    8. Selma Brynolf & Maria Grahn, 2024. "Flexibility with low environmental impact," Nature Energy, Nature, vol. 9(10), pages 1179-1180, October.
    9. Torrubia, Jorge & Valero, Alicia & Valero, Antonio, 2024. "Renewable exergy return on investment (RExROI) in energy systems. The case of silicon photovoltaic panels," Energy, Elsevier, vol. 304(C).
    10. Kate Dooley & Kirstine Lund Christiansen & Jens Friis Lund & Wim Carton & Alister Self, 2024. "Over-reliance on land for carbon dioxide removal in net-zero climate pledges," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    11. Torrubia, Jorge & Valero, Antonio & Valero, Alicia, 2024. "Non-renewable and renewable levelized exergy cost of electricity (LExCOE) with focus on its infrastructure: 1900–2050," Energy, Elsevier, vol. 313(C).
    12. Alessandro Lima & Jorge Torrubia & Alicia Valero & Antonio Valero, 2025. "Non-Renewable and Renewable Exergy Costs of Water Electrolysis in Hydrogen Production," Energies, MDPI, vol. 18(6), pages 1-24, March.
    13. Campion, Nicolas & Nami, Hossein & Swisher, Philip R. & Vang Hendriksen, Peter & Münster, Marie, 2023. "Techno-economic assessment of green ammonia production with different wind and solar potentials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    14. Penkuhn, Mathias & Tsatsaronis, George, 2017. "Comparison of different ammonia synthesis loop configurations with the aid of advanced exergy analysis," Energy, Elsevier, vol. 137(C), pages 854-864.
    15. Pinto, Ricardo & Henriques, Sofia T. & Brockway, Paul E. & Heun, Matthew Kuperus & Sousa, Tânia, 2023. "The rise and stall of world electricity efficiency:1900–2017, results and insights for the renewables transition," Energy, Elsevier, vol. 269(C).
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