IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v210y2023icp26-39.html
   My bibliography  Save this article

Covalent immobilization of phosphotungstic acid and amino acid on metal-organic frameworks with different structures: Acid-base bifunctional heterogeneous catalyst for the production of biodiesel from insect lipid

Author

Listed:
  • Feng, Weiliang
  • Tie, Xinlong
  • Duan, Xiaoling
  • Yan, Su
  • Fang, Si
  • Sun, Peiyong
  • Gan, Lin
  • Wang, Tielin

Abstract

To provide more acid-base active sites for the conversion of the insect lipid into biodiesel, three bifunctional heterogeneous catalysts (amino acid-PTA/ZIF-8) with different structures were designed and compared by modifying ZIF-8 with amino acid and phosphotungstic acid (PTA) as active species in the current research. The as-prepared amino acid-PTA/ZIF-8 composite catalyst features a large surface area and an increased acidity and basicity, thus combining the merits of acid and base with the heterogeneous microenvironment of ZIF-8. Meanwhile, various methods were used to investigate the physicochemical properties of the synthesized composite catalyst. Furthermore, the effects of reaction conditions on the esterification and transesterification of the acid model lipids were used to assess the best catalytic activity process. The optimum conditions (molar ratio of Arginine/PTA = 2:1, weight ratio of Arg2PTA/ZIF-8 = 3:1, reaction temperature = 60 °C, catalyst loading = 3 wt%, methanol/lipid molar ratio = 9:1, and stirring rate = 500 rpm) resulted in a maximum lipid conversion to biodiesel of 94.15%. In addition, the stability and reusability of the prepared catalysts with different structures during four reaction cycles were also demonstrated. Finally, the physicochemical properties of the biodiesel studied were measured and compared to the ASTM standard. Hence, this work provides great potential for acid-base functionalization of porous materials for future biodiesel production.

Suggested Citation

  • Feng, Weiliang & Tie, Xinlong & Duan, Xiaoling & Yan, Su & Fang, Si & Sun, Peiyong & Gan, Lin & Wang, Tielin, 2023. "Covalent immobilization of phosphotungstic acid and amino acid on metal-organic frameworks with different structures: Acid-base bifunctional heterogeneous catalyst for the production of biodiesel from," Renewable Energy, Elsevier, vol. 210(C), pages 26-39.
  • Handle: RePEc:eee:renene:v:210:y:2023:i:c:p:26-39
    DOI: 10.1016/j.renene.2023.03.120
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123004238
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2023.03.120?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Masteri-Farahani, Majid & Hosseini, Mahdiyeh-Sadat & Forouzeshfar, Newsha, 2020. "Propyl-SO3H functionalized graphene oxide as multipurpose solid acid catalyst for biodiesel synthesis and acid-catalyzed esterification and acetalization reactions," Renewable Energy, Elsevier, vol. 151(C), pages 1092-1101.
    2. Sawangkeaw, Ruengwit & Ngamprasertsith, Somkiat, 2013. "A review of lipid-based biomasses as feedstocks for biofuels production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 97-108.
    3. Karimi, Sabah & Seidi, Farzad & Niakan, Mahsa & Shekaari, Hemayat & Masteri-Farahani, Majid, 2021. "Catalytic dehydration of fructose into 5-hydroxymethylfurfural by propyl sulfonic acid functionalized magnetic graphene oxide nanocomposite," Renewable Energy, Elsevier, vol. 180(C), pages 132-139.
    4. Pan, Hu & Liu, Xiaofang & Zhang, Heng & Yang, Kaili & Huang, Shan & Yang, Song, 2017. "Multi-SO3H functionalized mesoporous polymeric acid catalyst for biodiesel production and fructose-to-biodiesel additive conversion," Renewable Energy, Elsevier, vol. 107(C), pages 245-252.
    5. Feng, Weiliang & Xiong, Huan & Wang, Weiguo & Duan, Xiaoling & Yang, Tong & Wu, Cheng & Yang, Fang & Xiong, Jing & Wang, Teilin & Wang, Cunwen, 2019. "Energy consumption analysis of lipid extraction from black soldier fly biomass," Energy, Elsevier, vol. 185(C), pages 1076-1085.
    6. Zheng, Longyu & Li, Qing & Zhang, Jibin & Yu, Ziniu, 2012. "Double the biodiesel yield: Rearing black soldier fly larvae, Hermetia illucens, on solid residual fraction of restaurant waste after grease extraction for biodiesel production," Renewable Energy, Elsevier, vol. 41(C), pages 75-79.
    7. Zhang, Pingbo & Liu, Yanlei & Fan, Mingming & Jiang, Pingping, 2016. "Catalytic performance of a novel amphiphilic alkaline ionic liquid for biodiesel production: Influence of basicity and conductivity," Renewable Energy, Elsevier, vol. 86(C), pages 99-105.
    8. Xie, Wenlei & Gao, Chunli & Li, Jiangbo, 2021. "Sustainable biodiesel production from low-quantity oils utilizing H6PV3MoW8O40 supported on magnetic Fe3O4/ZIF-8 composites," Renewable Energy, Elsevier, vol. 168(C), pages 927-937.
    9. Surendra, K.C. & Olivier, Robert & Tomberlin, Jeffery K. & Jha, Rajesh & Khanal, Samir Kumar, 2016. "Bioconversion of organic wastes into biodiesel and animal feed via insect farming," Renewable Energy, Elsevier, vol. 98(C), pages 197-202.
    10. Abdelmigeed, Mai O. & Al-Sakkari, Eslam G. & Hefney, Mahmoud S. & Ismail, Fatma M. & Ahmed, Tamer S. & Ismail, Ibrahim M., 2021. "Biodiesel production catalyzed by NaOH/Magnetized ZIF-8: Yield improvement using methanolysis and catalyst reusability enhancement," Renewable Energy, Elsevier, vol. 174(C), pages 253-261.
    11. Nath, Biswajit & Kalita, Pranjal & Das, Bipul & Basumatary, Sanjay, 2020. "Highly efficient renewable heterogeneous base catalyst derived from waste Sesamum indicum plant for synthesis of biodiesel," Renewable Energy, Elsevier, vol. 151(C), pages 295-310.
    12. Lani, Nurul Saadiah & Ngadi, Norzita & Inuwa, Ibrahim Mohammed, 2020. "New route for the synthesis of silica-supported calcium oxide catalyst in biodiesel production," Renewable Energy, Elsevier, vol. 156(C), pages 1266-1277.
    13. Narowska, Beata & Kułażyński, Marek & Łukaszewicz, Marcin & Burchacka, Ewa, 2019. "Use of activated carbons as catalyst supports for biodiesel production," Renewable Energy, Elsevier, vol. 135(C), pages 176-185.
    14. Abdelmigeed, Mai O. & Al-Sakkari, Eslam G. & Hefney, Mahmoud S. & Ismail, Fatma M. & Abdelghany, Amr & Ahmed, Tamer S. & Ismail, Ibrahim M., 2021. "Magnetized ZIF-8 impregnated with sodium hydroxide as a heterogeneous catalyst for high-quality biodiesel production," Renewable Energy, Elsevier, vol. 165(P1), pages 405-419.
    15. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Duan, Xiaoling & Yan, Su & Tie, Xinlong & Lei, Xidan & Liu, Zhiyi & Ma, Zhichao & Wang, Tielin & Feng, Weiliang, 2024. "Bimetallic Ce-Cr doped metal-organic frameworks as a heterogeneous catalyst for highly efficient biodiesel production from insect lipids," Renewable Energy, Elsevier, vol. 224(C).
    2. Sahar, Juma & Farooq, Muhammad & Ramli, Anita & Naeem, Abdul & Khattak, Noor Saeed & Ghazi, Zahid Ali, 2022. "Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil," Renewable Energy, Elsevier, vol. 198(C), pages 306-318.
    3. Antonio Franco & Carmen Scieuzo & Rosanna Salvia & Anna Maria Petrone & Elena Tafi & Antonio Moretta & Eric Schmitt & Patrizia Falabella, 2021. "Lipids from Hermetia illucens , an Innovative and Sustainable Source," Sustainability, MDPI, vol. 13(18), pages 1-23, September.
    4. Costanza Jucker & Daniela Lupi & Christopher Douglas Moore & Maria Giovanna Leonardi & Sara Savoldelli, 2020. "Nutrient Recapture from Insect Farm Waste: Bioconversion with Hermetia illucens (L.) (Diptera: Stratiomyidae)," Sustainability, MDPI, vol. 12(1), pages 1-14, January.
    5. Talal Yusaf & Mohd Kamal Kamarulzaman & Abdullah Adam & Sakinah Hisham & Devarajan Ramasamy & Kumaran Kadirgama & Mahendran Samykano & Sivaraos Subramaniam, 2022. "Physical-Chemical Properties Modification of Hermetia Illucens Larvae Oil and Diesel Fuel for the Internal Combustion Engines Application," Energies, MDPI, vol. 15(21), pages 1-17, October.
    6. Chung-Yiin Wong & Siti-Suhailah Rosli & Yoshimitsu Uemura & Yeek Chia Ho & Arunsri Leejeerajumnean & Worapon Kiatkittipong & Chin-Kui Cheng & Man-Kee Lam & Jun-Wei Lim, 2019. "Potential Protein and Biodiesel Sources from Black Soldier Fly Larvae: Insights of Larval Harvesting Instar and Fermented Feeding Medium," Energies, MDPI, vol. 12(8), pages 1-15, April.
    7. Zhu, Junyu & Liu, Xiangjie & Zhang, Xin & Deng, Bo & Xu, Chao & Zhang, Congcong & Yuan, Qiaoxia, 2023. "Experimental study on black soldier fly (Hermetia illucens L.) larvae hydrothermal liquefaction in methanol-water Co-solvent: Bio-oil yields and properties," Renewable Energy, Elsevier, vol. 218(C).
    8. Kamarulzaman, Mohd Kamal & Hafiz, M. & Abdullah, Adam & Chen, Ang Fuk & Awad, Omar I., 2019. "Combustion, performances and emissions characteristics of black soldier fly larvae oil and diesel blends in compression ignition engine," Renewable Energy, Elsevier, vol. 142(C), pages 569-580.
    9. Ella Cebisa Linganiso & Boitumelo Tlhaole & Lindokuhle Precious Magagula & Silas Dziike & Linda Zikhona Linganiso & Tshwafo Elias Motaung & Nosipho Moloto & Zikhona Nobuntu Tetana, 2022. "Biodiesel Production from Waste Oils: A South African Outlook," Sustainability, MDPI, vol. 14(4), pages 1-21, February.
    10. Xie, Wenlei & Li, Jiangbo, 2023. "Magnetic solid catalysts for sustainable and cleaner biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    11. Gao, Xiu & Chen, Chao & Zhang, Wenlu & Hong, Yanping & Wang, Chunrong & Wu, Guoqiang, 2022. "Sulfated TiO2 supported molybdenum-based catalysts for transesterification of Jatropha seed oil: Effect of molybdenum species and acidity properties," Renewable Energy, Elsevier, vol. 191(C), pages 357-369.
    12. Chung Yiin Wong & Muhammad Naeim Mohd Aris & Hanita Daud & Man Kee Lam & Ching Seong Yong & Hadura Abu Hasan & Siewhui Chong & Pau Loke Show & Oetami Dwi Hajoeningtijas & Yeek Chia Ho & Pei Sean Goh &, 2020. "In-Situ Yeast Fermentation to Enhance Bioconversion of Coconut Endosperm Waste into Larval Biomass of Hermetia illucens : Statistical Augmentation of Larval Lipid Content," Sustainability, MDPI, vol. 12(4), pages 1-10, February.
    13. Sun, Chihe & Hu, Yun & Sun, Fubao & Sun, Yahui & Song, Guojie & Chang, Haixing & Lunprom, Siriporn, 2022. "Comparison of biodiesel production using a novel porous Zn/Al/Co complex oxide prepared from different methods: Physicochemical properties, reaction kinetic and thermodynamic studies," Renewable Energy, Elsevier, vol. 181(C), pages 1419-1430.
    14. Jung, Sungyup & Jung, Jong-Min & Tsang, Yiu Fai & Bhatnagar, Amit & Chen, Wei-Hsin & Lin, Kun-Yi Andrew & Kwon, Eilhann E., 2022. "Biodiesel production from black soldier fly larvae derived from food waste by non-catalytic transesterification," Energy, Elsevier, vol. 238(PA).
    15. Xia, Shaige & Li, Jian & Chen, Guanyi & Tao, Junyu & Li, Wanqing & Zhu, Guangbin, 2022. "Magnetic reusable acid-base bifunctional Co doped Fe2O3–CaO nanocatalysts for biodiesel production from soybean oil and waste frying oil," Renewable Energy, Elsevier, vol. 189(C), pages 421-434.
    16. Dave Mangindaan & Emil Robert Kaburuan & Bayu Meindrawan, 2022. "Black Soldier Fly Larvae ( Hermetia illucens ) for Biodiesel and/or Animal Feed as a Solution for Waste-Food-Energy Nexus: Bibliometric Analysis," Sustainability, MDPI, vol. 14(21), pages 1-18, October.
    17. Caroline Jennings Saul & Heiko Gebauer, 2018. "Digital Transformation as an Enabler for Advanced Services in the Sanitation Sector," Sustainability, MDPI, vol. 10(3), pages 1-18, March.
    18. Zhang, Gaoqiang & Xie, Wenlei, 2024. "Hierarchical porous SAPO-34 decorated with Mo and W oxides for concurrent transesterification-esterifications for efficient biodiesel production from acidic soybean oil," Renewable Energy, Elsevier, vol. 222(C).
    19. Daimary, Niran & Boruah, Pankaj & Eldiehy, Khalifa S.H. & Pegu, Tapan & Bardhan, Pritam & Bora, Utpal & Mandal, Manabendra & Deka, Dhanapati, 2022. "Musa acuminata peel: A bioresource for bio-oil and by-product utilization as a sustainable source of renewable green catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 187(C), pages 450-462.
    20. Mahmoud, Hala R. & El-Molla, Sahar A. & Ibrahim, Marwa M., 2020. "Biodiesel production via stearic acid esterification over mesoporous ZrO2/SiO2 catalysts synthesized by surfactant-assisted sol-gel auto-combustion route," Renewable Energy, Elsevier, vol. 160(C), pages 42-51.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:210:y:2023:i:c:p:26-39. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.