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Pre-functionalized and lipid-dense post-hydrolysis rice bran as feedstock for FAME production via non-isothermal in-situ (trans)esterification with subcritical methanol

Author

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  • Go, Alchris Woo
  • Quijote, Kristelle L.
  • Alivio, Roxanne Kathlyn O.
  • Ju, Yi-Hsu
  • Gunarto, Chintya
  • Angkawijaya, Artik Elisa
  • Santoso, Shella Permatasari
  • Yuliana, Maria

Abstract

In-situ (trans)esterification (ISTE) of lipids in post-hydrolyzed rice bran (PHRB) with methanol under subcritical conditions has proven to be a suitable feedstock for fatty acid methyl ester (FAME) production. The lipids from PHRB had a fatty acid profile which was primarily composed of oleic (39 wt%) and linoleic (36 wt%) acids, and could potentially result in biodiesel with favorable properties. The PHRBs which were lipid-dense (31.35 and 48.98 wt% on a dry basis) and pre-functionalized (0.55 and 1.21 mmol H+/g dry and lipid-free PHRB), were successfully processed non-isothermally from 30 to 150 °C at high reactor loading of 85% and a solvent-to-solid ratio (SSR) of 4–6 mL/g dry PHRB, which resulted in yields of 26.48 and 35.11 g/100 g dry PHRB, equivalent to a conversion of ∼90% of the fatty acids. Due to the acquired acid sites in the collected PHRB, no additional catalyst was required. Elemental analysis and FT-IR spectroscopy were carried out to test the presence of sulfur and sulfonic sites in the PHRB residues. Furthermore, the recovered solids still exhibited substantial acid sites which were tested for activity through the esterification of oleic acid in methanol and were reused up to 7 cycles.

Suggested Citation

  • Go, Alchris Woo & Quijote, Kristelle L. & Alivio, Roxanne Kathlyn O. & Ju, Yi-Hsu & Gunarto, Chintya & Angkawijaya, Artik Elisa & Santoso, Shella Permatasari & Yuliana, Maria, 2022. "Pre-functionalized and lipid-dense post-hydrolysis rice bran as feedstock for FAME production via non-isothermal in-situ (trans)esterification with subcritical methanol," Renewable Energy, Elsevier, vol. 189(C), pages 13-24.
    • Handle: RePEc:eee:renene:v:189:y:2022:i:c:p:13-24
    DOI: 10.1016/j.renene.2022.02.089
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    References listed on IDEAS

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    1. Flores, Ken P. & Omega, Jan Laurence O. & Cabatingan, Luis K. & Go, Alchris W. & Agapay, Ramelito C. & Ju, Yi-Hsu, 2019. "Simultaneously carbonized and sulfonated sugarcane bagasse as solid acid catalyst for the esterification of oleic acid with methanol," Renewable Energy, Elsevier, vol. 130(C), pages 510-523.
    2. Go, Alchris Woo & Sutanto, Sylviana & Ong, Lu Ki & Tran-Nguyen, Phuong Lan & Ismadji, Suryadi & Ju, Yi-Hsu, 2016. "Developments in in-situ (trans) esterification for biodiesel production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 284-305.
    3. Masteri-Farahani, Majid & Hosseini, Mahdiyeh-Sadat & Forouzeshfar, Newsha, 2020. "Propyl-SO3H functionalized graphene oxide as multipurpose solid acid catalyst for biodiesel synthesis and acid-catalyzed esterification and acetalization reactions," Renewable Energy, Elsevier, vol. 151(C), pages 1092-1101.
    4. Zullaikah, Siti & Rahkadima, Yulia T. & Ju, Yi-Hsu, 2017. "A non-catalytic in situ process to produce biodiesel from a rice milling by-product using a subcritical water-methanol mixture," Renewable Energy, Elsevier, vol. 111(C), pages 764-770.
    5. Ngaosuwan, Kanokwan & Goodwin, James G. & Prasertdham, Piyasan, 2016. "A green sulfonated carbon-based catalyst derived from coffee residue for esterification," Renewable Energy, Elsevier, vol. 86(C), pages 262-269.
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