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Ice-templated nanocellulose porous structure enhances thermochemical storage kinetics in hydrated salt/graphite composites

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  • Salviati, Sergio
  • Carosio, Federico
  • Cantamessa, Francesco
  • Medina, Lilian
  • Berglund, Lars A.
  • Saracco, Guido
  • Fina, Alberto

Abstract

The freeze-drying technique is employed for the production of novel strontium bromide/graphite/nanocellulose composites for thermochemical heat storage application. The aim is to obtain a better control and stability of salt organization within the composite, while maximizing the air/salt and salt/graphite interfacial areas and enhancing mass and heat transfer associated to the salt hydration and dehydration. A comparison with a conventional wet impregnation method is also reported. The morphology was investigated by means of scanning electron microscopy. Differential scanning calorimetry was employed to evaluate the energy storage density, while hydration kinetics were evaluated at 23 °C and 50% RH. The wet impregnation approach delivered materials with a limited porosity while freeze-drying produced highly porous structures with oriented channels for moisture transport across the composite. The organic binder provided an active contribution to the energy storage process, producing energy storage densities up to 764 kJ/kg, 48% greater than the theoretical value. Freeze-dried nanocellulose composites evidenced a significant increase of 54% in the hydration kinetics, compared to the pristine salt. Based on these results, the freeze-drying of ternary composites based on salt hydrate, graphite and nanocellulose is envisaged as a promising route for the production of fast charge and discharge thermochemical storage systems.

Suggested Citation

  • Salviati, Sergio & Carosio, Federico & Cantamessa, Francesco & Medina, Lilian & Berglund, Lars A. & Saracco, Guido & Fina, Alberto, 2020. "Ice-templated nanocellulose porous structure enhances thermochemical storage kinetics in hydrated salt/graphite composites," Renewable Energy, Elsevier, vol. 160(C), pages 698-706.
    • Handle: RePEc:eee:renene:v:160:y:2020:i:c:p:698-706
    DOI: 10.1016/j.renene.2020.07.036
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    2. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2022. "Salt hydrate–based gas-solid thermochemical energy storage: Current progress, challenges, and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    3. Li, Wei & Zhang, Lianjie & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2022. "Thermochemical energy conversion behaviour in the corrugated heat storage unit with porous metal support," Energy, Elsevier, vol. 259(C).
    4. Bryan Li & Louise Buisson & Ruby-Jean Clark & Svetlana Ushak & Mohammed Farid, 2024. "A Eutectic Mixture of Calcium Chloride Hexahydrate and Bischofite with Promising Performance for Thermochemical Energy Storage," Energies, MDPI, vol. 17(3), pages 1-18, January.
    5. Clark, Ruby-Jean & Farid, Mohammed, 2022. "Experimental investigation into cascade thermochemical energy storage system using SrCl2-cement and zeolite-13X materials," Applied Energy, Elsevier, vol. 316(C).
    6. Mazur, Natalia & Blijlevens, Melian A.R. & Ruliaman, Rick & Fischer, Hartmut & Donkers, Pim & Meekes, Hugo & Vlieg, Elias & Adan, Olaf & Huinink, Henk, 2023. "Revisiting salt hydrate selection for domestic heat storage applications," Renewable Energy, Elsevier, vol. 218(C).

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