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Durable sulfonated partially fluorinated polysulfones as membrane for PEM fuel cell

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  • Mohammadi, Maryam
  • Mehdipour-Ataei, Shahram

Abstract

A new structure of sulfonated-partially fluorinated random polysulfone based on a highly fluorinated monomer -decafluorobiphenyl- was developed as the fuel cell membrane. Decafluorobiphenyl was randomly distributed in the structure by applying non-stoichiometric amounts of reactants via a three-step polymerization reaction under mild condition. The random copolymers with sulfonation degrees of 30–60% revealed suitable water uptake and dimensional change with good mechanical stability despite an increased degree of sulfonation. Moreover, higher proton conductivity (71–250 mS/cm at 80 °C and 100% RH) compared to the routine random copolymers (120 mS/cm) was obtained. The optimum sample with 60% sulfonation showed a comparable power density of about 319.5 mW/cm2 with the reported random type polymer. The high current density of 1309 mA/cm2 was remarkable. Notably, with 60% sulfonation, only 4.85% voltage reduction was observed during 100 h OCV hold test under an accelerated ageing condition in fuel cell media.

Suggested Citation

  • Mohammadi, Maryam & Mehdipour-Ataei, Shahram, 2020. "Durable sulfonated partially fluorinated polysulfones as membrane for PEM fuel cell," Renewable Energy, Elsevier, vol. 158(C), pages 421-430.
    • Handle: RePEc:eee:renene:v:158:y:2020:i:c:p:421-430
    DOI: 10.1016/j.renene.2020.05.124
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    References listed on IDEAS

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    Cited by:

    1. Chen, Kui & Laghrouche, Salah & Djerdir, Abdesslem, 2021. "Prognosis of fuel cell degradation under different applications using wavelet analysis and nonlinear autoregressive exogenous neural network," Renewable Energy, Elsevier, vol. 179(C), pages 802-814.
    2. Hyeon-Bee Song & Jong-Hyeok Park & Jin-Soo Park & Moon-Sung Kang, 2021. "Pore-Filled Proton-Exchange Membranes with Fluorinated Moiety for Fuel Cell Application," Energies, MDPI, vol. 14(15), pages 1-13, July.

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