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Sulfonated polyethersulfone/polyetheretherketone blend as high performing and cost-effective electrolyte membrane for direct methanol fuel cells

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  • Simari, C.
  • Lo Vecchio, C.
  • Baglio, V.
  • Nicotera, I.

Abstract

Blended electrolyte membranes based on sulfonated Polyethersulfone (sPES) and sulfonated Poly(ether ether ketone) (sPEEK) were prepared in two different ratios (i.e. 50/50 and 25/75) via a simple, scalable and inexpensive solution casting process to investigate their suitability for direct methanol fuel cell (DMFC) applications. Thermo-mechanical analysis revealed higher flexibility and thermal resistance with the blending of these two macromolecules, without any evidence of phase-segregation, and with good chemical stability. Furthermore, the proton transport was facilitated while the methanol permeability was dramatically reduced. The DMFC tests confirmed outstanding performance by using the membrane with the blend ratio 25/75, reaching a power density of about 130 mW cm−2 at 80 °C in 4 M methanol solution. These features and the cost-effectiveness of sPES-SPEEK membranes make them interesting candidates for use in next-generation DMFCs.

Suggested Citation

  • Simari, C. & Lo Vecchio, C. & Baglio, V. & Nicotera, I., 2020. "Sulfonated polyethersulfone/polyetheretherketone blend as high performing and cost-effective electrolyte membrane for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 159(C), pages 336-345.
    • Handle: RePEc:eee:renene:v:159:y:2020:i:c:p:336-345
    DOI: 10.1016/j.renene.2020.06.053
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    References listed on IDEAS

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    1. Muthumeenal, A. & Neelakandan, S. & Kanagaraj, P. & Nagendran, A., 2016. "Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications," Renewable Energy, Elsevier, vol. 86(C), pages 922-929.
    2. Chuesutham, Thirayu & Sirivat, Anuvat & Paradee, Nophawan & Changkhamchom, Sairung & Wattanakul, Karnthidaporn & Anumart, Songsak & Krathumkhet, Nattinee & Khampim, Jarumat, 2019. "Improvement of sulfonated poly(ether ether ketone)/Y zeolite -SO3H via organo-functionalization method for direct methanol fuel cell," Renewable Energy, Elsevier, vol. 138(C), pages 243-249.
    3. Uma Devi, A. & Muthumeenal, A. & Sabarathinam, R.M. & Nagendran, A., 2017. "Fabrication and electrochemical properties of SPVdF-co-HFP/SPES blend proton exchange membranes for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 102(PA), pages 258-265.
    4. Nagar, Harsha & Sahu, Nivedita & Basava Rao, V.V. & Sridhar, S., 2020. "Surface modification of sulfonated polyethersulfone membrane with polyaniline nanoparticles for application in direct methanol fuel cell," Renewable Energy, Elsevier, vol. 146(C), pages 1262-1277.
    5. Sopian, Kamaruzzaman & Wan Daud, Wan Ramli, 2006. "Challenges and future developments in proton exchange membrane fuel cells," Renewable Energy, Elsevier, vol. 31(5), pages 719-727.
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    1. Oroujzadeh, Maryam & Mehdipour-Ataei, Shahram, 2025. "Highly fluorinated poly arylene ethers containing sulfonated naphthol pendants with improved proton conductivity as a polymer electrolyte for proton exchange membrane fuel cells," Renewable Energy, Elsevier, vol. 240(C).

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