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Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications

Author

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  • Muthumeenal, A.
  • Neelakandan, S.
  • Kanagaraj, P.
  • Nagendran, A.

Abstract

Chitosan is modified by phthaloylation using an excess of phthalic anhydride at 130 °C and blended with the sulfonated polyethersulfone (SPES) to produce composite blend membranes. In particular the introduction of the phthaloyl group into the chitosan matrix increases its solubility in organic solvent, film formability, flexibility, low methanol permeability and with suitable ion conductivity. SPES and N-phthaloyl chitosan (NPHCs) blend membranes with various compositions were prepared and detailed investigation on water uptake, proton conductivity and methanol permeability has been conducted for its suitability in fuel cell environments. Methanol permeability studies envisaged that NPHCs blend membranes are impervious to methanol. The thermograms display the good thermal stabilities of blend membranes than Nafion-117. Relatively high selectivity parameter values of these membranes indicated their greater advantages over Nafion-117 membrane for targeting on fuel cell applications, especially in direct methanol fuel cell (DMFC) environments.

Suggested Citation

  • Muthumeenal, A. & Neelakandan, S. & Kanagaraj, P. & Nagendran, A., 2016. "Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications," Renewable Energy, Elsevier, vol. 86(C), pages 922-929.
    • Handle: RePEc:eee:renene:v:86:y:2016:i:c:p:922-929
    DOI: 10.1016/j.renene.2015.09.018
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    References listed on IDEAS

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    1. Neelakandan, S. & Kanagaraj, P. & Nagendran, A. & Rana, D. & Matsuura, T. & Muthumeenal, A., 2015. "Enhancing proton conduction of sulfonated poly (phenylene ether ether sulfone) membrane by charged surface modifying macromolecules for H2/O2 fuel cells," Renewable Energy, Elsevier, vol. 78(C), pages 306-313.
    2. Chun, Jeong Hwan & Kim, Sang Gon & Lee, Ji Young & Hyeon, Dong Hun & Chun, Byung-Hee & Kim, Sung Hyun & Park, Ki Tae, 2013. "Crosslinked sulfonated poly(arylene ether sulfone)/silica hybrid membranes for high temperature proton exchange membrane fuel cells," Renewable Energy, Elsevier, vol. 51(C), pages 22-28.
    3. Hasani-Sadrabadi, Mohammad Mahdi & Dashtimoghadam, Erfan & Ghaffarian, Seyed Reza & Hasani Sadrabadi, Mohammad Hossein & Heidari, Mahdi & Moaddel, Homayoun, 2010. "Novel high-performance nanocomposite proton exchange membranes based on poly (ether sulfone)," Renewable Energy, Elsevier, vol. 35(1), pages 226-231.
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    Cited by:

    1. Kusworo, Tutuk Djoko & Widayat, Widayat & Utomo, Dani Puji & Pratama, Yulius Harmawan Setya & Arianti, Riska Anindisa Vira, 2020. "Performance evaluation of modified nanohybrid membrane polyethersulfone-nano ZnO (PES-nano ZnO) using three combination effect of PVP, irradiation of ultraviolet and thermal for biodiesel purification," Renewable Energy, Elsevier, vol. 148(C), pages 935-945.
    2. Nagar, Harsha & Aniya, Vineet & Mondal, Prasenjit, 2020. "High proton conductivity dual modified ionic crosslink membrane for fuel cell application at low humidity condition with molecular dynamics simulations," Renewable Energy, Elsevier, vol. 160(C), pages 1036-1047.
    3. Uma Devi, A. & Muthumeenal, A. & Sabarathinam, R.M. & Nagendran, A., 2017. "Fabrication and electrochemical properties of SPVdF-co-HFP/SPES blend proton exchange membranes for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 102(PA), pages 258-265.
    4. Abdelkareem, Mohammad Ali & Allagui, Anis & Sayed, Enas Taha & El Haj Assad, M. & Said, Zafar & Elsaid, Khaled, 2019. "Comparative analysis of liquid versus vapor-feed passive direct methanol fuel cells," Renewable Energy, Elsevier, vol. 131(C), pages 563-584.
    5. Eman A. El Desouky & Emad A. Soliman & Hessa H. Al-Rasheed & Ayman El-Faham & M. A. Abu-Saied, 2023. "Novel Proton Exchange Membranes Based on Sulfonated Poly(acrylonitrile- co -glycidyl methacrylate)/Poly(vinyl chloride) Composite," Sustainability, MDPI, vol. 15(14), pages 1-24, July.
    6. Simari, C. & Lo Vecchio, C. & Baglio, V. & Nicotera, I., 2020. "Sulfonated polyethersulfone/polyetheretherketone blend as high performing and cost-effective electrolyte membrane for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 159(C), pages 336-345.
    7. Ingabire, Providence Buregeya & Pan, Xueting & Haragirimana, Alphonse & Li, Na & Hu, Zhaoxia & Chen, Shouwen, 2020. "Improved hydroxide conductivity and performance of nanocomposite membrane derived on quaternized polymers incorporated by titanium dioxide modified graphitic carbon nitride for fuel cells," Renewable Energy, Elsevier, vol. 152(C), pages 590-600.
    8. Muthumeenal, A. & Pethaiah, S. Sundar & Nagendran, A., 2016. "Investigation of SPES as PEM for hydrogen production through electrochemical reforming of aqueous methanol," Renewable Energy, Elsevier, vol. 91(C), pages 75-82.

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