IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v91y2016icp75-82.html
   My bibliography  Save this article

Investigation of SPES as PEM for hydrogen production through electrochemical reforming of aqueous methanol

Author

Listed:
  • Muthumeenal, A.
  • Pethaiah, S. Sundar
  • Nagendran, A.

Abstract

A polymer electrolyte membrane for hydrogen production through methanol electrolysis was prepared by converting poly ether sulfone (PES) into ionomer via sulfonation and fashioned into membrane. The physical and electrochemical properties of the prepared membrane and a single cell using the fabricated membrane are examined using various characterization techniques, such as, FTIR spectrometry, scanning electron microscopy, thermogravimetric analysis, tensile strength measurement, ion exchange capacity, electrochemical impedance spectroscopy and polarization studies. A current density of 0.802 A/cm2 was obtained at a cell voltage of 1.2 V at 80 °C with the sulfonated polyethersulfone (SPES) based membrane electrode assembly (MEA) under suitable fabrication conditions. The energy requirements for hydrogen production are also compared with conventional water electrolysis. The observational results suggest that SPES membrane could be an option to costly perfluorosulfonate membranes in methanol electrolysis for hydrogen production.

Suggested Citation

  • Muthumeenal, A. & Pethaiah, S. Sundar & Nagendran, A., 2016. "Investigation of SPES as PEM for hydrogen production through electrochemical reforming of aqueous methanol," Renewable Energy, Elsevier, vol. 91(C), pages 75-82.
    • Handle: RePEc:eee:renene:v:91:y:2016:i:c:p:75-82
    DOI: 10.1016/j.renene.2016.01.042
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148116300428
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2016.01.042?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Neelakandan, S. & Kanagaraj, P. & Nagendran, A. & Rana, D. & Matsuura, T. & Muthumeenal, A., 2015. "Enhancing proton conduction of sulfonated poly (phenylene ether ether sulfone) membrane by charged surface modifying macromolecules for H2/O2 fuel cells," Renewable Energy, Elsevier, vol. 78(C), pages 306-313.
    2. Muthumeenal, A. & Neelakandan, S. & Kanagaraj, P. & Nagendran, A., 2016. "Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications," Renewable Energy, Elsevier, vol. 86(C), pages 922-929.
    3. M. S. Dresselhaus & I. L. Thomas, 2001. "Alternative energy technologies," Nature, Nature, vol. 414(6861), pages 332-337, November.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Sethu Sundar Pethaiah & Kishor Kumar Sadasivuni & Arunkumar Jayakumar & Deepalekshmi Ponnamma & Chandra Sekhar Tiwary & Gangadharan Sasikumar, 2020. "Methanol Electrolysis for Hydrogen Production Using Polymer Electrolyte Membrane: A Mini-Review," Energies, MDPI, vol. 13(22), pages 1-17, November.
    2. Sanjay Kumar Kar & Akhoury Sudhir Kumar Sinha & Sidhartha Harichandan & Rohit Bansal & Marriyappan Sivagnanam Balathanigaimani, 2023. "Hydrogen economy in India: A status review," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 12(1), January.
    3. Uma Devi, A. & Muthumeenal, A. & Sabarathinam, R.M. & Nagendran, A., 2017. "Fabrication and electrochemical properties of SPVdF-co-HFP/SPES blend proton exchange membranes for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 102(PA), pages 258-265.
    4. Gutiérrez-Martín, F. & Calcerrada, A.B. & de Lucas-Consuegra, A. & Dorado, F., 2020. "Hydrogen storage for off-grid power supply based on solar PV and electrochemical reforming of ethanol-water solutions," Renewable Energy, Elsevier, vol. 147(P1), pages 639-649.
    5. Ju, HyungKuk & Badwal, Sukhvinder & Giddey, Sarbjit, 2018. "A comprehensive review of carbon and hydrocarbon assisted water electrolysis for hydrogen production," Applied Energy, Elsevier, vol. 231(C), pages 502-533.
    6. Zhou, Jing & Cao, Jiamu & Zhang, Yufeng & Liu, Junfeng & Chen, Junyu & Li, Mingxue & Wang, Weiqi & Liu, Xiaowei, 2021. "Overcoming undesired fuel crossover: Goals of methanol-resistant modification of polymer electrolyte membranes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ingabire, Providence Buregeya & Pan, Xueting & Haragirimana, Alphonse & Li, Na & Hu, Zhaoxia & Chen, Shouwen, 2020. "Improved hydroxide conductivity and performance of nanocomposite membrane derived on quaternized polymers incorporated by titanium dioxide modified graphitic carbon nitride for fuel cells," Renewable Energy, Elsevier, vol. 152(C), pages 590-600.
    2. Uma Devi, A. & Muthumeenal, A. & Sabarathinam, R.M. & Nagendran, A., 2017. "Fabrication and electrochemical properties of SPVdF-co-HFP/SPES blend proton exchange membranes for direct methanol fuel cells," Renewable Energy, Elsevier, vol. 102(PA), pages 258-265.
    3. Xiaoqin Si & Rui Lu & Zhitong Zhao & Xiaofeng Yang & Feng Wang & Huifang Jiang & Xiaolin Luo & Aiqin Wang & Zhaochi Feng & Jie Xu & Fang Lu, 2022. "Catalytic production of low-carbon footprint sustainable natural gas," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Cala, Anggie & Maturana-Córdoba, Aymer & Soto-Verjel, Joseph, 2023. "Exploring the pretreatments' influence on pressure reverse osmosis: PRISMA review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    5. Ahmadi, Pouria & Dincer, Ibrahim & Rosen, Marc A., 2014. "Thermoeconomic multi-objective optimization of a novel biomass-based integrated energy system," Energy, Elsevier, vol. 68(C), pages 958-970.
    6. Jacqueline Noga & Gregor Wolbring, 2014. "The Oil and Gas Discourse from the Perspective of the Canadian and Albertan Governments, Non-Governmental Organizations and the Oil and Gas Industry," Energies, MDPI, vol. 7(1), pages 1-20, January.
    7. Sun, Li & Li, Guanru & You, Fengqi, 2020. "Combined internal resistance and state-of-charge estimation of lithium-ion battery based on extended state observer," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    8. Kusworo, Tutuk Djoko & Widayat, Widayat & Utomo, Dani Puji & Pratama, Yulius Harmawan Setya & Arianti, Riska Anindisa Vira, 2020. "Performance evaluation of modified nanohybrid membrane polyethersulfone-nano ZnO (PES-nano ZnO) using three combination effect of PVP, irradiation of ultraviolet and thermal for biodiesel purification," Renewable Energy, Elsevier, vol. 148(C), pages 935-945.
    9. Xu, Jiuping & Li, Li & Zheng, Bobo, 2016. "Wind energy generation technological paradigm diffusion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 436-449.
    10. Sameer Kumar & Jariah Mohd. Jan, 2014. "Research collaboration networks of two OIC nations: comparative study between Turkey and Malaysia in the field of ‘Energy Fuels’, 2009–2011," Scientometrics, Springer;Akadémiai Kiadó, vol. 98(1), pages 387-414, January.
    11. Yan Yan & Jiancheng Guan, 2018. "How multiple networks help in creating knowledge: evidence from alternative energy patents," Scientometrics, Springer;Akadémiai Kiadó, vol. 115(1), pages 51-77, April.
    12. Bocheng Lv & Yu Liu & Weidong Wu & Yan Xie & Jia-Lin Zhu & Yang Cao & Wanyun Ma & Ning Yang & Weidong Chu & Yi Jia & Jinquan Wei & Jia-Lin Sun, 2022. "Local large temperature difference and ultra-wideband photothermoelectric response of the silver nanostructure film/carbon nanotube film heterostructure," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    13. Pitchai Ragupathy & Santoshkumar Dattatray Bhat & Nallathamby Kalaiselvi, 2023. "Electrochemical energy storage and conversion: An overview," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 12(2), March.
    14. Xin Kang & Fengning Yang & Zhiyuan Zhang & Heming Liu & Shiyu Ge & Shuqi Hu & Shaohai Li & Yuting Luo & Qiangmin Yu & Zhibo Liu & Qiang Wang & Wencai Ren & Chenghua Sun & Hui-Ming Cheng & Bilu Liu, 2023. "A corrosion-resistant RuMoNi catalyst for efficient and long-lasting seawater oxidation and anion exchange membrane electrolyzer," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    15. Muthumeenal, A. & Neelakandan, S. & Kanagaraj, P. & Nagendran, A., 2016. "Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications," Renewable Energy, Elsevier, vol. 86(C), pages 922-929.
    16. Huang, Zhe & Lu, Lu & Jiang, Daqian & Xing, Defeng & Ren, Zhiyong Jason, 2017. "Electrochemical hythane production for renewable energy storage and biogas upgrading," Applied Energy, Elsevier, vol. 187(C), pages 595-600.
    17. Jiadong Chen & Chunhong Chen & Minkai Qin & Ben Li & Binbin Lin & Qing Mao & Hongbin Yang & Bin Liu & Yong Wang, 2022. "Reversible hydrogen spillover in Ru-WO3-x enhances hydrogen evolution activity in neutral pH water splitting," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    18. Huang, Junbing & Wang, Yajun & Guo, Lili, 2022. "Energy intensity and energy-specific technological progress: A case study in Guangdong province of China," Renewable Energy, Elsevier, vol. 184(C), pages 990-1001.
    19. José A. Camacho & Lucas Silva Almeida & Mercedes Rodríguez & Jesús Molina, 2022. "Domestic versus foreign energy use: an analysis for four European countries," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 24(4), pages 4602-4622, April.
    20. Tianyu Zhang & Jing Jin & Junmei Chen & Yingyan Fang & Xu Han & Jiayi Chen & Yaping Li & Yu Wang & Junfeng Liu & Lei Wang, 2022. "Pinpointing the axial ligand effect on platinum single-atom-catalyst towards efficient alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-14, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:91:y:2016:i:c:p:75-82. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.