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Study of high voltage applied to the membrane electrode assemblies of proton exchange membrane fuel cells as an accelerated degradation technique

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  • Jung, Guo-Bin
  • Chuang, Kai-Yuan
  • Jao, Ting-Chu
  • Yeh, Chia-Chen
  • Lin, Chih-Yuan

Abstract

The durability of proton exchange membrane fuel cells has been extensively studied. The main aim of the present study was to elucidate membrane electrode assembly (MEA) degradation mechanisms using an accelerated degradation technique (ADT). An ADT experiment was performed by applying 1.5V to an MEA with hydrogen and nitrogen feeding to the anode and cathode, respectively, to simulate the high voltage generated during fuel cell shutdown and restart. This study adopted in situ as well as ex situ techniques, such as polarization curves, AC impedance, cyclic voltammetry (CV), linear sweep voltammetry (LSV), SEM and TEM to analyze the MEA before and after ADT experiments. Results show that the ADT could dramatically reduce the duration of the experiment while still observing MEA degradation. Current output at 0.4V decreased by 41% after performing ADT for 60min. LSV showed unchanging hydrogen crossover through the MEA, implying membrane degradation could be ignored during ADT evaluation. An increase in charge transfer resistance seen by AC impedance, shifts in the electrochemical surface area and double layering suggested that the main degradation mechanism during ADT evaluation is degradation of the carbon supporting the catalyst layer.

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  • Jung, Guo-Bin & Chuang, Kai-Yuan & Jao, Ting-Chu & Yeh, Chia-Chen & Lin, Chih-Yuan, 2012. "Study of high voltage applied to the membrane electrode assemblies of proton exchange membrane fuel cells as an accelerated degradation technique," Applied Energy, Elsevier, vol. 100(C), pages 81-86.
    • Handle: RePEc:eee:appene:v:100:y:2012:i:c:p:81-86
    DOI: 10.1016/j.apenergy.2012.06.046
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    1. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    2. Oh, Si-Doek & Kim, Ki-Young & Oh, Shuk-Bum & Kwak, Ho-Young, 2012. "Optimal operation of a 1-kW PEMFC-based CHP system for residential applications," Applied Energy, Elsevier, vol. 95(C), pages 93-101.
    3. Kazim, Ayoub, 2003. "Introduction of PEM fuel-cell vehicles in the transportation sector of the United Arab Emirates," Applied Energy, Elsevier, vol. 74(1-2), pages 125-133, January.
    4. Lee, Yongtaek & Kim, Bosung & Kim, Yongchan & Li, Xianguo, 2011. "Degradation of gas diffusion layers through repetitive freezing," Applied Energy, Elsevier, vol. 88(12), pages 5111-5119.
    5. Panha, Karachakorn & Fowler, Michael & Yuan, Xiao-Zi & Wang, Haijiang, 2012. "Accelerated durability testing via reactants relative humidity cycling on PEM fuel cells," Applied Energy, Elsevier, vol. 93(C), pages 90-97.
    6. Perng, Shiang-Wuu & Wu, Horng-Wen, 2010. "Effect of the prominent catalyst layer surface on reactant gas transport and cell performance at the cathodic side of a PEMFC," Applied Energy, Elsevier, vol. 87(4), pages 1386-1399, April.
    7. Barelli, L. & Bidini, G. & Gallorini, F. & Ottaviano, A., 2012. "Dynamic analysis of PEMFC-based CHP systems for domestic application," Applied Energy, Elsevier, vol. 91(1), pages 13-28.
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    10. Taghiabadi, Mohammad Mohammadi & Zhiani, Mohammad & Silva, Valter, 2019. "Effect of MEA activation method on the long-term performance of PEM fuel cell," Applied Energy, Elsevier, vol. 242(C), pages 602-611.
    11. Ma, Rui & Yang, Tao & Breaz, Elena & Li, Zhongliang & Briois, Pascal & Gao, Fei, 2018. "Data-driven proton exchange membrane fuel cell degradation predication through deep learning method," Applied Energy, Elsevier, vol. 231(C), pages 102-115.
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