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Long Term Performance Study of a Direct Methanol Fuel Cell Fed with Alcohol Blends

Author

Listed:
  • Teresa J. Leo

    (Departmento de Sistemas Oceánicos y Navales, ETSI Navales, Universidad Politécnica de Madrid, Madrid 28040, Spain)

  • Miguel A. Raso

    (Departmento de Química Física I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Madrid 28040, Spain)

  • Emilio Navarro

    (Departmento de Motopropulsión y Termofluidodinámica, ETSI Aeronáuticos, Universidad Politécnica de Madrid, Madrid 28040, Spain)

  • Eleuterio Mora

    (Departmento de Ciencias Aplicadas a la Ingeniería Naval, ETSI Navales, Universidad Politécnica de Madrid, Madrid 28040, Spain)

Abstract

The use of alcohol blends in direct alcohol fuel cells may be a more environmentally friendly and less toxic alternative to the use of methanol alone in direct methanol fuel cells. This paper assesses the behaviour of a direct methanol fuel cell fed with aqueous methanol, aqueous ethanol and aqueous methanol/ethanol blends in a long term experimental study followed by modelling of polarization curves. Fuel cell performance is seen to decrease as the ethanol content rises, and subsequent operation with aqueous methanol only partly reverts this loss of performance. It seems that the difference in the oxidation rate of these alcohols may not be the only factor affecting fuel cell performance.

Suggested Citation

  • Teresa J. Leo & Miguel A. Raso & Emilio Navarro & Eleuterio Mora, 2013. "Long Term Performance Study of a Direct Methanol Fuel Cell Fed with Alcohol Blends," Energies, MDPI, vol. 6(1), pages 1-12, January.
    • Handle: RePEc:gam:jeners:v:6:y:2013:i:1:p:282-293:d:22755
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    References listed on IDEAS

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    1. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    2. Nishimura, Akira & Shibuya, Kenichi & Morimoto, Atsushi & Tanaka, Shigeki & Hirota, Masafumi & Nakamura, Yoshihiro & Kojima, Masashi & Narita, Masahiko & Hu, Eric, 2012. "Dominant factor and mechanism of coupling phenomena in single cell of polymer electrolyte fuel cell," Applied Energy, Elsevier, vol. 90(1), pages 73-79.
    3. Barelli, L. & Bidini, G. & Gallorini, F. & Ottaviano, A., 2012. "Dynamic analysis of PEMFC-based CHP systems for domestic application," Applied Energy, Elsevier, vol. 91(1), pages 13-28.
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    Cited by:

    1. Johannes Kiefer, 2015. "Recent Advances in the Characterization of Gaseous and Liquid Fuels by Vibrational Spectroscopy," Energies, MDPI, vol. 8(4), pages 1-33, April.
    2. Chung-Jen Chou & Shyh-Biau Jiang & Tse-Liang Yeh & Li-Duan Tsai & Ku-Yen Kang & Ching-Jung Liu, 2020. "A Portable Direct Methanol Fuel Cell Power Station for Long-Term Internet of Things Applications," Energies, MDPI, vol. 13(14), pages 1-13, July.
    3. Long-Yi Chang & Hung-Cheng Chen, 2014. "Linearization and Input-Output Decoupling for Nonlinear Control of Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 7(2), pages 1-16, January.
    4. Santiago, Óscar & Navarro, Emilio & Raso, Miguel A. & Leo, Teresa J., 2016. "Review of implantable and external abiotically catalysed glucose fuel cells and the differences between their membranes and catalysts," Applied Energy, Elsevier, vol. 179(C), pages 497-522.
    5. Claudio Rabissi & Matteo Zago & Fausto Bresciani & Pawel Gazdzicki & Andrea Casalegno, 2023. "A Novel Accelerated Stress Test for a Representative Enhancement of Cathode Degradation in Direct Methanol Fuel Cells," Energies, MDPI, vol. 16(7), pages 1-14, April.

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