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Optimized microporous layer for improving polymer exchange membrane fuel cell performance using orthogonal test design

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  • Lin, Rui
  • Diao, Xiaoyu
  • Ma, Tiancai
  • Tang, Shenghao
  • Chen, Liang
  • Liu, Dengcheng

Abstract

The microporous layer of gas diffusion layer plays an important role in water management of polymer exchange membrane fuel cells. Many factors affect the performance of the microporous layer, and these factors are interrelated. In this work, the orthogonal test method is used to study the effects of four factors including hydrophobic agent, the ratio of carbon powder to hydrophobic agent, carbon powder and microporous layer loading. Nine experiments with four factors and three levels are carried out. The effects of these different factors on the microporous layer are studied. The polarization curves and electrochemical impedance spectroscopy of fuel cells are tested and the scanning electron microscopy, contact angle and pore size distribution of MPL are characterized to prove that the conclusions obtained by orthogonal tests are correct and reliable. It is observed that carbon powder, hydrophobic agent and microporous layer loading have significant effects on the performance of fuel cell than that of the ratio of carbon powder to hydrophobic agent. These three factors mainly influence the cells performance by affecting the ohmic resistance and mass transfer resistance. This work provides a reference for the rapid optimization of microporous layer composition and hence improve the water management of the fuel cell.

Suggested Citation

  • Lin, Rui & Diao, Xiaoyu & Ma, Tiancai & Tang, Shenghao & Chen, Liang & Liu, Dengcheng, 2019. "Optimized microporous layer for improving polymer exchange membrane fuel cell performance using orthogonal test design," Applied Energy, Elsevier, vol. 254(C).
    • Handle: RePEc:eee:appene:v:254:y:2019:i:c:s0306261919314011
    DOI: 10.1016/j.apenergy.2019.113714
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    1. Li, Yuehua & Pei, Pucheng & Wu, Ziyao & Ren, Peng & Jia, Xiaoning & Chen, Dongfang & Huang, Shangwei, 2018. "Approaches to avoid flooding in association with pressure drop in proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 224(C), pages 42-51.
    2. Taghiabadi, Mohammad Mohammadi & Zhiani, Mohammad & Silva, Valter, 2019. "Effect of MEA activation method on the long-term performance of PEM fuel cell," Applied Energy, Elsevier, vol. 242(C), pages 602-611.
    3. Cho, Junhyun & Park, Jaeman & Oh, Hwanyeong & Min, Kyoungdoug & Lee, Eunsook & Jyoung, Jy-Young, 2013. "Analysis of the transient response and durability characteristics of a proton exchange membrane fuel cell with different micro-porous layer penetration thicknesses," Applied Energy, Elsevier, vol. 111(C), pages 300-309.
    4. Shahgaldi, Samaneh & Alaefour, Ibrahim & Li, Xianguo, 2018. "Impact of manufacturing processes on proton exchange membrane fuel cell performance," Applied Energy, Elsevier, vol. 225(C), pages 1022-1032.
    5. Afra, Mehran & Nazari, Mohsen & Kayhani, Mohammad Hasan & Sharifpur, M. & Meyer, J.P., 2019. "3D experimental visualization of water flooding in proton exchange membrane fuel cells," Energy, Elsevier, vol. 175(C), pages 967-977.
    6. Kong, Im Mo & Jung, Aeri & Kim, Min Soo, 2016. "Investigations on the double gas diffusion backing layer for performance improvement of self-humidified proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 176(C), pages 149-156.
    7. Ijaodola, O.S. & El- Hassan, Zaki & Ogungbemi, E. & Khatib, F.N. & Wilberforce, Tabbi & Thompson, James & Olabi, A.G., 2019. "Energy efficiency improvements by investigating the water flooding management on proton exchange membrane fuel cell (PEMFC)," Energy, Elsevier, vol. 179(C), pages 246-267.
    8. Lin, Rui & Zhu, Yike & Ni, Meng & Jiang, Zhenghua & Lou, Diming & Han, Lihang & Zhong, Di, 2019. "Consistency analysis of polymer electrolyte membrane fuel cell stack during cold start," Applied Energy, Elsevier, vol. 241(C), pages 420-432.
    9. Barelli, Linda & Bidini, Gianni & Ottaviano, Andrea, 2012. "Optimization of a PEMFC/battery pack power system for a bus application," Applied Energy, Elsevier, vol. 97(C), pages 777-784.
    10. Mahdavi, Arash & Ranjbar, Ali Akbar & Gorji, Mofid & Rahimi-Esbo, Mazaher, 2018. "Numerical simulation based design for an innovative PEMFC cooling flow field with metallic bipolar plates," Applied Energy, Elsevier, vol. 228(C), pages 656-666.
    11. Oh, Hwanyeong & Park, Jaeman & Min, Kyoungdoug & Lee, Eunsook & Jyoung, Jy-Young, 2015. "Effects of pore size gradient in the substrate of a gas diffusion layer on the performance of a proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 149(C), pages 186-193.
    12. Wu, Yifei & Zhao, Hongxia & Zhang, Cunquan & Wang, Lei & Han, Jitian, 2018. "Optimization analysis of structure parameters of steam ejector based on CFD and orthogonal test," Energy, Elsevier, vol. 151(C), pages 79-93.
    13. Pei, Pucheng & Li, Yuehua & Xu, Huachi & Wu, Ziyao, 2016. "A review on water fault diagnosis of PEMFC associated with the pressure drop," Applied Energy, Elsevier, vol. 173(C), pages 366-385.
    14. Li, Wenkai & Zhang, Qinglei & Wang, Chao & Yan, Xiaohui & Shen, Shuiyun & Xia, Guofeng & Zhu, Fengjuan & Zhang, Junliang, 2017. "Experimental and numerical analysis of a three-dimensional flow field for PEMFCs," Applied Energy, Elsevier, vol. 195(C), pages 278-288.
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    5. Yu, Rui Jiao & Guo, Hang & Ye, Fang & Chen, Hao, 2022. "Multi-parameter optimization of stepwise distribution of parameters of gas diffusion layer and catalyst layer for PEMFC peak power density," Applied Energy, Elsevier, vol. 324(C).
    6. Mohammadi, Maryam & Mehdipour-Ataei, Shahram, 2020. "Durable sulfonated partially fluorinated polysulfones as membrane for PEM fuel cell," Renewable Energy, Elsevier, vol. 158(C), pages 421-430.
    7. Xiao, Liusheng & Bian, Miaoqi & Sun, Yushuai & Yuan, Jinliang & Wen, Xiaofei, 2024. "Transport properties evaluation of pore-scale GDLs for PEMFC using orthogonal design method," Applied Energy, Elsevier, vol. 357(C).
    8. Kim, Jaeyeon & Kim, Hyeok & Song, Hyeonjun & Kim, Dasol & Kim, Geon Hwi & Im, Dasom & Jeong, Youngjin & Park, Taehyun, 2021. "Carbon nanotube sheet as a microporous layer for proton exchange membrane fuel cells," Energy, Elsevier, vol. 227(C).

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