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Extraction and esterification of waste coffee grounds oil as non-edible feedstock for biodiesel production

Author

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  • Mueanmas, Chokchai
  • Nikhom, Ruamporn
  • Petchkaew, Anida
  • Iewkittayakorn, Jutarut
  • Prasertsit, Kulchanart

Abstract

The potential of waste coffee grounds (WCG) as a non-edible feedstock for biodiesel production was evaluated in term of extraction and esterification of waste coffee grounds oil (WCGO). The effect of liquid-solid extraction parameters such as the type and volume of solvent, the extraction time and temperature, and mixing speed were thoroughly investigated. The highest yield of oil extracted from WCGO was 15.47 wt% obtained at a hexane to WCG ratio of 9:1 (v/w) with a mixing speed of 200 rpm and an extraction duration of 5 min at room temperature. An esterification reaction was conducted as a pre-treatment step to reduce the concentration of free fatty acid (FFA), optimized by response surface methodology (RSM) combined with a central composite design (CCD). The results indicated that all the parameters including the methanol (MeOH) to FFA molar ratio, quantity of catalyst, reaction time and temperature were significant for %FFA removal. In the esterification step, the FFA conversion was 95% at the predicted optimization condition which corresponded to the experimental data. Therefore, the results of this study support the utilization of WCGO as a source of non-edible oil feedstock for biodiesel production.

Suggested Citation

  • Mueanmas, Chokchai & Nikhom, Ruamporn & Petchkaew, Anida & Iewkittayakorn, Jutarut & Prasertsit, Kulchanart, 2019. "Extraction and esterification of waste coffee grounds oil as non-edible feedstock for biodiesel production," Renewable Energy, Elsevier, vol. 133(C), pages 1414-1425.
    • Handle: RePEc:eee:renene:v:133:y:2019:i:c:p:1414-1425
    DOI: 10.1016/j.renene.2018.08.102
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    1. Mathiarasi, Ramasamy & Partha, Nagarajan, 2016. "Optimization, kinetics and thermodynamic studies on oil extraction from Daturametel Linn oil seed for biodiesel production," Renewable Energy, Elsevier, vol. 96(PA), pages 583-590.
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    3. Nakpong, Piyanuch & Wootthikanokkhan, Sasiwimol, 2010. "High free fatty acid coconut oil as a potential feedstock for biodiesel production in Thailand," Renewable Energy, Elsevier, vol. 35(8), pages 1682-1687.
    4. Yaakob, Zahira & Mohammad, Masita & Alherbawi, Mohammad & Alam, Zahangir & Sopian, Kamaruzaman, 2013. "Overview of the production of biodiesel from Waste cooking oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 184-193.
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    2. Hiep Nghia Bui & Hoang Quoc Do & Huong Thi Giang Duong & Yuan-Shing Perng & Vu Nguyen Dam & Van-Truc Nguyen & Ha Manh Bui, 2022. "Taguchi optimization and life cycle assessment of biodiesel production from spent ground coffee," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 24(11), pages 12900-12916, November.
    3. di Bitonto, Luigi & Reynel-Ávila, Hilda Elizabeth & Mendoza-Castillo, Didilia Ileana & Bonilla-Petriciolet, Adrián & Durán-Valle, Carlos J. & Pastore, Carlo, 2020. "Synthesis and characterization of nanostructured calcium oxides supported onto biochar and their application as catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 160(C), pages 52-66.
    4. Kamil, Mohammed & Ramadan, Khalid M. & Olabi, Abdul Ghani & Al-Ali, Eman I. & Ma, Xiao & Awad, Omar I., 2020. "Economic, technical, and environmental viability of biodiesel blends derived from coffee waste," Renewable Energy, Elsevier, vol. 147(P1), pages 1880-1894.
    5. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.

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