IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v35y2010i8p1682-1687.html
   My bibliography  Save this article

High free fatty acid coconut oil as a potential feedstock for biodiesel production in Thailand

Author

Listed:
  • Nakpong, Piyanuch
  • Wootthikanokkhan, Sasiwimol

Abstract

Coconut oil having 12.8% free fatty acid (FFA) was used as a feedstock to produce biodiesel by a two-step process. In the first step, FFA level of the coconut oil was reduced to 0.6% by acid-catalyzed esterification. In the second step, triglycerides in product from the first step were transesterified with methanol by using an alkaline catalyst to produce methyl esters and glycerol. Effect of parameters related to these processes was studied and optimized, including methanol-to-oil ratio, catalyst concentration, reaction temperature, and reaction time. Methyl ester content of the coconut biodiesel was determined by GC to be 98.4% under the optimum condition. The viscosity of coconut biodiesel product was very close to that of Thai petroleum diesel and other measured properties met the Thai biodiesel (B100) specification.

Suggested Citation

  • Nakpong, Piyanuch & Wootthikanokkhan, Sasiwimol, 2010. "High free fatty acid coconut oil as a potential feedstock for biodiesel production in Thailand," Renewable Energy, Elsevier, vol. 35(8), pages 1682-1687.
    • Handle: RePEc:eee:renene:v:35:y:2010:i:8:p:1682-1687
    DOI: 10.1016/j.renene.2009.12.004
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148109005400
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2009.12.004?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ramadhas, A.S. & Muraleedharan, C. & Jayaraj, S., 2005. "Performance and emission evaluation of a diesel engine fueled with methyl esters of rubber seed oil," Renewable Energy, Elsevier, vol. 30(12), pages 1789-1800.
    2. Meher, L.C. & Vidya Sagar, D. & Naik, S.N., 2006. "Technical aspects of biodiesel production by transesterification--a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(3), pages 248-268, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    2. Silitonga, A.S. & Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Mekhilef, S., 2011. "A review on prospect of Jatropha curcas for biodiesel in Indonesia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3733-3756.
    3. Aksoy, Laçine, 2011. "Opium poppy (Papaver somniferum L.) oil for preparation of biodiesel: Optimization of conditions," Applied Energy, Elsevier, vol. 88(12), pages 4713-4718.
    4. Norwazan Abdul Rahim & Mohammad Nazri Mohd Jaafar & Syazwana Sapee & Hazir Farouk Elraheem, 2016. "Effect on Particulate and Gas Emissions by Combusting Biodiesel Blend Fuels Made from Different Plant Oil Feedstocks in a Liquid Fuel Burner," Energies, MDPI, vol. 9(8), pages 1-18, August.
    5. Ong, H.C. & Mahlia, T.M.I. & Masjuki, H.H. & Norhasyima, R.S., 2011. "Comparison of palm oil, Jatropha curcas and Calophyllum inophyllum for biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3501-3515.
    6. Kumar, Niraj & Varun, & Chauhan, Sant Ram, 2013. "Performance and emission characteristics of biodiesel from different origins: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 633-658.
    7. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Liaquat, A.M. & Shahabuddin, M. & Varman, M., 2012. "Prospects of biodiesel from Jatropha in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5007-5020.
    8. Lokman, Ibrahim M. & Rashid, Umer & Taufiq-Yap, Yun Hin & Yunus, Robiah, 2015. "Methyl ester production from palm fatty acid distillate using sulfonated glucose-derived acid catalyst," Renewable Energy, Elsevier, vol. 81(C), pages 347-354.
    9. Takase, Mohammed & Zhao, Ting & Zhang, Min & Chen, Yao & Liu, Hongyang & Yang, Liuqing & Wu, Xiangyang, 2015. "An expatiate review of neem, jatropha, rubber and karanja as multipurpose non-edible biodiesel resources and comparison of their fuel, engine and emission properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 495-520.
    10. Arbab, M.I. & Masjuki, H.H. & Varman, M. & Kalam, M.A. & Imtenan, S. & Sajjad, H., 2013. "Fuel properties, engine performance and emission characteristic of common biodiesels as a renewable and sustainable source of fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 133-147.
    11. Jahirul, M.I. & Rasul, M.G. & Brown, R.J. & Senadeera, W. & Hosen, M.A. & Haque, R. & Saha, S.C. & Mahlia, T.M.I., 2021. "Investigation of correlation between chemical composition and properties of biodiesel using principal component analysis (PCA) and artificial neural network (ANN)," Renewable Energy, Elsevier, vol. 168(C), pages 632-646.
    12. Avinash, A. & Subramaniam, D. & Murugesan, A., 2014. "Bio-diesel—A global scenario," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 517-527.
    13. Mohammad Fauzi, Ahmad Hafiidz & Amin, Nor Aishah Saidina & Mat, Ramli, 2014. "Esterification of oleic acid to biodiesel using magnetic ionic liquid: Multi-objective optimization and kinetic study," Applied Energy, Elsevier, vol. 114(C), pages 809-818.
    14. Tuti Suryati & Euis Julaeha & Kindi Farabi & Hanies Ambarsari & Ace Tatang Hidayat, 2023. "Lauric Acid from the Black Soldier Fly ( Hermetia illucens ) and Its Potential Applications," Sustainability, MDPI, vol. 15(13), pages 1-28, June.
    15. Linhares, Felipe Nunes & Corrêa, Harrison Lourenço & Khalil, Carlos Nagib & Amorim Moreira Leite, Márcia Christina & Guimarães Furtado, Cristina Russi, 2013. "Study of the compatibility of nitrile rubber with Brazilian biodiesel," Energy, Elsevier, vol. 49(C), pages 102-106.
    16. Mueanmas, Chokchai & Nikhom, Ruamporn & Petchkaew, Anida & Iewkittayakorn, Jutarut & Prasertsit, Kulchanart, 2019. "Extraction and esterification of waste coffee grounds oil as non-edible feedstock for biodiesel production," Renewable Energy, Elsevier, vol. 133(C), pages 1414-1425.
    17. Rajesh, K. & Natarajan, M.P. & Devan, P.K. & Ponnuvel, S., 2021. "Coconut fatty acid distillate as novel feedstock for biodiesel production and its characterization as a fuel for diesel engine," Renewable Energy, Elsevier, vol. 164(C), pages 1424-1435.
    18. Yew Heng Teoh & Heoy Geok How & Farooq Sher & Thanh Danh Le & Huu Tho Nguyen & Haseeb Yaqoob, 2021. "Fuel Injection Responses and Particulate Emissions of a CRDI Engine Fueled with Cocos nucifera Biodiesel," Sustainability, MDPI, vol. 13(9), pages 1-17, April.
    19. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Venu, Harish & Raju, V. Dhana & Subramani, Lingesan & Appavu, Prabhu, 2020. "Experimental assessment on the regulated and unregulated emissions of DI diesel engine fuelled with Chlorella emersonii methyl ester (CEME)," Renewable Energy, Elsevier, vol. 151(C), pages 88-102.
    2. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    3. Habibullah, M. & Masjuki, H.H. & Kalam, M.A. & Rahman, S.M. Ashrafur & Mofijur, M. & Mobarak, H.M. & Ashraful, A.M., 2015. "Potential of biodiesel as a renewable energy source in Bangladesh," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 819-834.
    4. Atabani, A.E. & Silitonga, A.S. & Ong, H.C. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Fayaz, H., 2013. "Non-edible vegetable oils: A critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 211-245.
    5. Sharon, H. & Karuppasamy, K. & Soban Kumar, D.R. & Sundaresan, A., 2012. "A test on DI diesel engine fueled with methyl esters of used palm oil," Renewable Energy, Elsevier, vol. 47(C), pages 160-166.
    6. Takase, Mohammed & Zhao, Ting & Zhang, Min & Chen, Yao & Liu, Hongyang & Yang, Liuqing & Wu, Xiangyang, 2015. "An expatiate review of neem, jatropha, rubber and karanja as multipurpose non-edible biodiesel resources and comparison of their fuel, engine and emission properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 495-520.
    7. Karabektas, Murat, 2009. "The effects of turbocharger on the performance and exhaust emissions of a diesel engine fuelled with biodiesel," Renewable Energy, Elsevier, vol. 34(4), pages 989-993.
    8. Senthil Kumar, T. & Senthil Kumar, P. & Annamalai, K., 2015. "Experimental study on the performance and emission measures of direct injection diesel engine with Kapok methyl ester and its blends," Renewable Energy, Elsevier, vol. 74(C), pages 903-909.
    9. Basha, Syed Ameer & Gopal, K. Raja & Jebaraj, S., 2009. "A review on biodiesel production, combustion, emissions and performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1628-1634, August.
    10. Kaya, Canan & Hamamci, Candan & Baysal, Akin & Akba, Osman & Erdogan, Sait & Saydut, Abdurrahman, 2009. "Methyl ester of peanut (Arachis hypogea L.) seed oil as a potential feedstock for biodiesel production," Renewable Energy, Elsevier, vol. 34(5), pages 1257-1260.
    11. Kumar, Niraj & Varun, & Chauhan, Sant Ram, 2013. "Performance and emission characteristics of biodiesel from different origins: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 633-658.
    12. Sathiyamoorthi, R. & Sankaranarayanan, G. & Adhith kumaar, S.B. & Chiranjeevi, T. & Dilip Kumar, D., 2019. "Experimental investigation on performance, combustion and emission characteristics of a single cylinder diesel engine fuelled by biodiesel derived from Cymbopogon Martinii," Renewable Energy, Elsevier, vol. 132(C), pages 394-415.
    13. Siwina, Siraprapha & Leesing, Ratanaporn, 2021. "Bioconversion of durian (Durio zibethinus Murr.) peel hydrolysate into biodiesel by newly isolated oleaginous yeast Rhodotorula mucilaginosa KKUSY14," Renewable Energy, Elsevier, vol. 163(C), pages 237-245.
    14. Haşimoğlu, Can & Ciniviz, Murat & Özsert, İbrahim & İçingür, Yakup & Parlak, Adnan & Sahir Salman, M., 2008. "Performance characteristics of a low heat rejection diesel engine operating with biodiesel," Renewable Energy, Elsevier, vol. 33(7), pages 1709-1715.
    15. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    16. Malhotra, Rashi & Ali, Amjad, 2019. "5-Na/ZnO doped mesoporous silica as reusable solid catalyst for biodiesel production via transesterification of virgin cottonseed oil," Renewable Energy, Elsevier, vol. 133(C), pages 606-619.
    17. Vallinayagam, R. & Vedharaj, S. & Yang, W.M. & Roberts, W.L. & Dibble, R.W., 2015. "Feasibility of using less viscous and lower cetane (LVLC) fuels in a diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1166-1190.
    18. Marco Castellini & Stefano Ubertini & Diego Barletta & Ilaria Baffo & Pietro Buzzini & Marco Barbanera, 2021. "Techno-Economic Analysis of Biodiesel Production from Microbial Oil Using Cardoon Stalks as Carbon Source," Energies, MDPI, vol. 14(5), pages 1-21, March.
    19. Thamsiriroj, Thanasit & Murphy, Jerry D., 2011. "A critical review of the applicability of biodiesel and grass biomethane as biofuels to satisfy both biofuel targets and sustainability criteria," Applied Energy, Elsevier, vol. 88(4), pages 1008-1019, April.
    20. Piotr Łagowski & Grzegorz Wcisło & Dariusz Kurczyński, 2022. "Comparison of the Combustion Process Parameters in a Diesel Engine Powered by Second-Generation Biodiesel Compared to the First-Generation Biodiesel," Energies, MDPI, vol. 15(18), pages 1-21, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:35:y:2010:i:8:p:1682-1687. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.