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Adsorbent working pairs for solar thermal energy storage in buildings

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  • Frazzica, Andrea
  • Freni, Angelo

Abstract

In this study, the thermodynamic analysis of several adsorption working pairs for adsorption heat storage applications at domestic level is presented. The selected working pairs employ different working fluids (i.e. water, ethanol, ammonia, methanol) and different adsorbent materials such as classical zeolites, silica gels, alumino-phosphates, composite sorbents and activated carbons. The simulations have been performed taking into account desorption temperatures in the range between 80 °C and 120 °C, compatible with non-concentrating solar thermal collectors, under seasonal heat storage working conditions. The composite sorbent MWCNT-LiCl with both water and methanol as working fluid showed the highest heat storage density under practical working boundary conditions. Among the standard adsorbents, the zeotype AQSOA Z02 showed promising achievable heat storage densities. Classical working pairs, such as zeolite 13X/water, commonly employed for heat storage applications, are not suitable for this working range. Finally, also the influence of the metal to sorbent mass ratio, due to the heat exchanger, was investigated, demonstrating that it can reduce the achievable amount of heat released to the user up to 30%.

Suggested Citation

  • Frazzica, Andrea & Freni, Angelo, 2017. "Adsorbent working pairs for solar thermal energy storage in buildings," Renewable Energy, Elsevier, vol. 110(C), pages 87-94.
    • Handle: RePEc:eee:renene:v:110:y:2017:i:c:p:87-94
    DOI: 10.1016/j.renene.2016.09.047
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    3. Valeria Palomba & Efstratios Varvagiannis & Sotirios Karellas & Andrea Frazzica, 2019. "Hybrid Adsorption-Compression Systems for Air Conditioning in Efficient Buildings: Design through Validated Dynamic Models," Energies, MDPI, vol. 12(6), pages 1-28, March.
    4. An, G.L. & Wang, L.W. & Zhang, Y.H., 2020. "Overall evaluation of single- and multi-halide composites for multi-mode thermal-energy storage," Energy, Elsevier, vol. 212(C).
    5. Wyttenbach, Joël & Bougard, Jacques & Descy, Gilbert & Skrylnyk, Oleksandr & Courbon, Emilie & Frère, Marc & Bruyat, Fabien, 2018. "Performances and modelling of a circular moving bed thermochemical reactor for seasonal storage," Applied Energy, Elsevier, vol. 230(C), pages 803-815.
    6. Mikhaeil, Makram & Gaderer, Matthias & Dawoud, Belal, 2020. "On the development of an innovative adsorber plate heat exchanger for adsorption heat transformation processes; an experimental and numerical study," Energy, Elsevier, vol. 207(C).
    7. Andrea Frazzica & Vincenza Brancato & Belal Dawoud, 2020. "Unified Methodology to Identify the Potential Application of Seasonal Sorption Storage Technology," Energies, MDPI, vol. 13(5), pages 1-17, February.
    8. Frazzica, A. & Brancato, V. & Caprì, A. & Cannilla, C. & Gordeeva, L.G. & Aristov, Y.I., 2020. "Development of “salt in porous matrix” composites based on LiCl for sorption thermal energy storage," Energy, Elsevier, vol. 208(C).
    9. Dias, João M.S. & Costa, Vítor A.F., 2018. "Adsorption heat pumps for heating applications: A review of current state, literature gaps and development challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 317-327.
    10. Alicia Crespo & Cèsar Fernández & Alvaro de Gracia & Andrea Frazzica, 2022. "Solar-Driven Sorption System for Seasonal Heat Storage under Optimal Control: Study for Different Climatic Zones," Energies, MDPI, vol. 15(15), pages 1-23, August.
    11. Roberta Di Bari & Rafael Horn & Björn Nienborg & Felix Klinker & Esther Kieseritzky & Felix Pawelz, 2020. "The Environmental Potential of Phase Change Materials in Building Applications. A Multiple Case Investigation Based on Life Cycle Assessment and Building Simulation," Energies, MDPI, vol. 13(12), pages 1-30, June.
    12. Feng, Changling & E, Jiaqiang & Han, Wei & Deng, Yuanwang & Zhang, Bin & Zhao, Xiaohuan & Han, Dandan, 2021. "Key technology and application analysis of zeolite adsorption for energy storage and heat-mass transfer process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    13. Kuznik, Frédéric & Johannes, Kevyn & Obrecht, Christian & David, Damien, 2018. "A review on recent developments in physisorption thermal energy storage for building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 576-586.
    14. Treier, Matthias S. & Desai, Aditya & Schmidt, Ferdinand P., 2020. "Comparison of storage density and efficiency for cascading adsorption heat storage and sorption assisted water storage," Energy, Elsevier, vol. 194(C).

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