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Influence of temperature on biomass pyrolysis in a conical spouted bed reactor

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  • Amutio, M.
  • Lopez, G.
  • Artetxe, M.
  • Elordi, G.
  • Olazar, M.
  • Bilbao, J.

Abstract

Pinewood sawdust flash pyrolysis has been performed in continuous mode in a pilot plant provided with a conical spouted bed reactor, in the 400–600°C range. The influence of temperature on the pyrolysis yields and product properties has been studied. Product analysis has been carried out on-line by means of chromatographic methods. High liquid yields have been achieved, with the maximum bio-oil yield (75wt%) at 500°C. Gas yield is very low at low temperatures and this fraction is mainly composed of carbon dioxide, carbon monoxide and small amounts of methane, hydrogen and C2–C4 hydrocarbons. Bio-oil has been characterized and its major compounds are phenols, specifically guaiacols at low temperatures and catechols at high temperatures. At 600°C, there is an increase in light compounds due to the cracking reactions, but no aromatic compounds have been detected due to the low residence time of the volatiles in the reactor. The fuel properties of the bio-oil have been measured and the results indicate that it can be a potential substitute to conventional fuels, although its heating value should be improved by subjecting to further treatments. Char can be used as energy source or as active carbon. The char obtained at 600°C has a high surface area and is suitable for active carbon production.

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  • Amutio, M. & Lopez, G. & Artetxe, M. & Elordi, G. & Olazar, M. & Bilbao, J., 2012. "Influence of temperature on biomass pyrolysis in a conical spouted bed reactor," Resources, Conservation & Recycling, Elsevier, vol. 59(C), pages 23-31.
    • Handle: RePEc:eee:recore:v:59:y:2012:i:c:p:23-31
    DOI: 10.1016/j.resconrec.2011.04.002
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    1. Alhashimi, Hashim A. & Aktas, Can B., 2017. "Life cycle environmental and economic performance of biochar compared with activated carbon: A meta-analysis," Resources, Conservation & Recycling, Elsevier, vol. 118(C), pages 13-26.
    2. Fernandez, Enara & Santamaria, Laura & Amutio, Maider & Artetxe, Maite & Arregi, Aitor & Lopez, Gartzen & Bilbao, Javier & Olazar, Martin, 2022. "Role of temperature in the biomass steam pyrolysis in a conical spouted bed reactor," Energy, Elsevier, vol. 238(PC).
    3. Hwang, Jae Gyu & Lee, Byeong Kyu & Choi, Myung Kyu & Park, Hoon Chae & Choi, Hang Seok, 2023. "Optimal production of waste tire pyrolysis oil and recovery of high value-added D-limonene in a conical spouted bed reactor," Energy, Elsevier, vol. 262(PB).
    4. Yao, Xiwen & Liu, Qinghua & Kang, Zijian & An, Zhixing & Zhou, Haodong & Xu, Kaili, 2023. "Quantitative study on thermal conversion behaviours and gas emission properties of biomass in nitrogen and in CO2/N2 mixtures by TGA/DTG and a fixed-bed tube furnace," Energy, Elsevier, vol. 270(C).
    5. Zhang, Haifeng & Ju, Shuai & Jin, Xin & Yuan, Yan & Wu, Yingji & Nadda, Ashok Kumar & Pugazhendhi, Arivalagan & Cai, Liping & Xia, Changlei, 2022. "A review of sensor applications towards precise control of pyrolysis of solid waste and biomasses," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    6. Niu, Miaomiao & Sun, Rongyue & Ding, Kuan & Gu, Haiming & Cui, Xiaobo & Wang, Liang & Hu, Jichu, 2022. "Synergistic effect on thermal behavior and product characteristics during co-pyrolysis of biomass and waste tire: Influence of biomass species and waste blending ratios," Energy, Elsevier, vol. 240(C).

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