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Catalytic hydrodeoxygenation of 2-methoxy phenol and dibenzofuran over Pt/mesoporous zeolites

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  • Lee, Hyung Won
  • Jun, Bo Ram
  • Kim, Hannah
  • Kim, Do Heui
  • Jeon, Jong-Ki
  • Park, Sung Hoon
  • Ko, Chang Hyun
  • Kim, Tae-Wan
  • Park, Young-Kwon

Abstract

The hydrodeoxygenation of 2-methoxy phenol and dibenzofuran, which are representative model compounds of bio-oil, was performed using two different Pt/mesoporous zeolite catalysts, Pt/mesoporous Y and Pt/mesoporous MFI. The reforming of 2-methoxy phenol and dibenzofuran via catalytic hydrodeoxygenation was investigated using a batch reactor at 40 bar and 250 °C. The characteristics of the catalysts were analyzed by N2 adsorption-desorption, X-ray diffraction, and NH3 temperature programmed desorption. Pt/mesoporous zeolite catalysts containing both strong acid sites and mesopores showed the higher conversion of 2-methoxy phenol than Pt/SiO2 and Pt/Si-MCM-48 with no acid sites, Pt/γ-Al2O3, and a mixture of mesoporous Y and Pt/SiO2, indicating the importance of both Pt and strong acid sites for high catalytic activity. Among the two Pt/mesoporous zeolite catalysts tested, the conversion of 2-methoxy phenol to cyclohexane over Pt/mesoporous Y was much higher than that over the Pt/mesoporous MFI. This was attributed to the better textural properties, such as surface area, pore volume and micropore size, compared to those of Pt/mesoporous MFI. The catalytic conversions of dibenzofuran obtained using two Pt/mesoporous zeolite catalysts were similar and the main products were 1,1′-bicyclohexyl, cyclopentylmethyl-cyclohexane and cyclohexane. In addition, the reaction mechanisms of 2-methoxy phenol and dibenzofuran over Pt/mesoporous zeolite were suggested.

Suggested Citation

  • Lee, Hyung Won & Jun, Bo Ram & Kim, Hannah & Kim, Do Heui & Jeon, Jong-Ki & Park, Sung Hoon & Ko, Chang Hyun & Kim, Tae-Wan & Park, Young-Kwon, 2015. "Catalytic hydrodeoxygenation of 2-methoxy phenol and dibenzofuran over Pt/mesoporous zeolites," Energy, Elsevier, vol. 81(C), pages 33-40.
    • Handle: RePEc:eee:energy:v:81:y:2015:i:c:p:33-40
    DOI: 10.1016/j.energy.2014.11.058
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    1. Kim, Tae-Seung & Oh, Shinyoung & Kim, Jae-Young & Choi, In-Gyu & Choi, Joon Weon, 2014. "Study on the hydrodeoxygenative upgrading of crude bio-oil produced from woody biomass by fast pyrolysis," Energy, Elsevier, vol. 68(C), pages 437-443.
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