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Study on the hydrodeoxygenative upgrading of crude bio-oil produced from woody biomass by fast pyrolysis

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  • Kim, Tae-Seung
  • Oh, Shinyoung
  • Kim, Jae-Young
  • Choi, In-Gyu
  • Choi, Joon Weon

Abstract

Crude bio-oil produced from fast pyrolysis of yellow poplar wood was subjected to HDO (hydrodeoxygenation) for the purpose of reducing water content as well as increasing heating value. HDO was performed in an autoclave reactor at three different reaction factors: temperature (250–370 °C), reaction time (40–120 min), and Pd/C catalyst loading (0–6 wt%) under hydrogen atmosphere. After completion of HDO, gas, char, and two immiscible liquid products (light oil and heavy oil) were obtained. Liquid products were less acidic and contained less water than crude bio-oil. Water content of heavy oil was ranged between 0.4 wt% and 1.9 wt%. Heating values of heavy oil were estimated between 28.7 and 37.4 MJ/kg, which was about twice higher than that of crude bio-oil. Elemental analysis revealed that heavy oil had a lower O/C ratio (0.17–0.36) than crude bio-oil (0.71). H/C ratio of heavy oil decreased from 1.50 to 1.32 with an increase of temperature from 250 °C to 350 °C, respectively.

Suggested Citation

  • Kim, Tae-Seung & Oh, Shinyoung & Kim, Jae-Young & Choi, In-Gyu & Choi, Joon Weon, 2014. "Study on the hydrodeoxygenative upgrading of crude bio-oil produced from woody biomass by fast pyrolysis," Energy, Elsevier, vol. 68(C), pages 437-443.
    • Handle: RePEc:eee:energy:v:68:y:2014:i:c:p:437-443
    DOI: 10.1016/j.energy.2014.03.004
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    1. Demirbas, Ayhan, 2009. "Political, economic and environmental impacts of biofuels: A review," Applied Energy, Elsevier, vol. 86(Supplemen), pages 108-117, November.
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    2. Li, Zhixia & Huang, Zhentao & Ding, Shilei & Li, Fuwei & Wang, Zhaohe & Lin, Hongfei & Chen, Congjin, 2018. "Catalytic conversion of waste cooking oil to fuel oil: Catalyst design and effect of solvent," Energy, Elsevier, vol. 157(C), pages 270-277.
    3. Bartłomiej Igliński & Wojciech Kujawski & Urszula Kiełkowska, 2023. "Pyrolysis of Waste Biomass: Technical and Process Achievements, and Future Development—A Review," Energies, MDPI, vol. 16(4), pages 1-26, February.
    4. Ochoa, Aitor & Vicente, Héctor & Sierra, Irene & Arandes, José M. & Castaño, Pedro, 2020. "Implications of feeding or cofeeding bio-oil in the fluid catalytic cracker (FCC) in terms of regeneration kinetics and energy balance," Energy, Elsevier, vol. 209(C).
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    6. Zhang, Zhaoxia & Bi, Peiyan & Jiang, Peiwen & Fan, Minghui & Deng, Shumei & Zhai, Qi & Li, Quanxin, 2015. "Production of gasoline fraction from bio-oil under atmospheric conditions by an integrated catalytic transformation process," Energy, Elsevier, vol. 90(P2), pages 1922-1930.
    7. Zhang, Xinghua & Chen, Lungang & Kong, Wei & Wang, Tiejun & Zhang, Qi & Long, Jinxing & Xu, Ying & Ma, Longlong, 2015. "Upgrading of bio-oil to boiler fuel by catalytic hydrotreatment and esterification in an efficient process," Energy, Elsevier, vol. 84(C), pages 83-90.
    8. Prajitno, Hermawan & Insyani, Rizki & Park, Jongkeun & Ryu, Changkook & Kim, Jaehoon, 2016. "Non-catalytic upgrading of fast pyrolysis bio-oil in supercritical ethanol and combustion behavior of the upgraded oil," Applied Energy, Elsevier, vol. 172(C), pages 12-22.
    9. Jahromi, Hossein & Agblevor, Foster A., 2017. "Upgrading of pinyon-juniper catalytic pyrolysis oil via hydrodeoxygenation," Energy, Elsevier, vol. 141(C), pages 2186-2195.
    10. Lee, Hyung Won & Jun, Bo Ram & Kim, Hannah & Kim, Do Heui & Jeon, Jong-Ki & Park, Sung Hoon & Ko, Chang Hyun & Kim, Tae-Wan & Park, Young-Kwon, 2015. "Catalytic hydrodeoxygenation of 2-methoxy phenol and dibenzofuran over Pt/mesoporous zeolites," Energy, Elsevier, vol. 81(C), pages 33-40.
    11. Gollakota, Anjani R.K. & Reddy, Madhurima & Subramanyam, Malladi D. & Kishore, Nanda, 2016. "A review on the upgradation techniques of pyrolysis oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 1543-1568.

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