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Enhanced redox performance of cement-modified Fe-based oxygen carrier during biomass chemical looping gasification

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  • Zhang, Xueqi
  • Yip, Alex C.K.
  • Rosas, Santiago
  • Nusheh, Mohammad
  • Pang, Shusheng

Abstract

In this study, a novel Fe-based OC was synthesized based on cement chemically bonded hematite, containing multiple-component calcium ferrites. Its cyclic performance was evaluated over 10 cycles of BCLG at 850, 900 and 950 °C, respectively, in a batch fluidized-bed reactor. Fresh and used OCs were characterized using TGA, XPS, XRD and SEM/EDS techniques. The best cyclic reactivity was achieved at 950 °C, resulting in an average gasification efficiency of 91.3 % and H2/CO ratio of 2.4 due to superior oxygen diffusivity. At 850 °C, the OC underwent elemental reorganization under repeated limited reduction and complete reoxidation. This structure evolution significantly improved the high-temperature redox reactivity of the used OC (OC850-M10) with the maximum mass loss rate of −4%/min during the TGA tests, compared to −2.6 %/min for fresh OC. For used OCs after 10 cycles at 900 °C (OC900-M10) and 950 °C (OC950-M10), increased oxygen vacancies in OC900-M10 compensated for reactivity loss caused by Fe enrichment, while reactive oxygen accessibility in OC950-M10 was moderately constrained by Fe segregation beyond a critical threshold. Despite the agglomeration after 20 cycles at 950 °C, enhanced overlaying of Fe and inert species further homogenized Fe phases, allowing for the restoration of 98 % of active oxygen after gentle crushing. Moreover, the addition of cement also improved crushing strength (>3 N) over cycling, partially due to the growth of Al2O3 flower-shaped phases in internal voids. These findings suggest that chemical incorporation of cement with hematite prolonged OC longevity.

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  • Zhang, Xueqi & Yip, Alex C.K. & Rosas, Santiago & Nusheh, Mohammad & Pang, Shusheng, 2025. "Enhanced redox performance of cement-modified Fe-based oxygen carrier during biomass chemical looping gasification," Energy, Elsevier, vol. 320(C).
    • Handle: RePEc:eee:energy:v:320:y:2025:i:c:s0360544225010357
    DOI: 10.1016/j.energy.2025.135393
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    1. Srirangan, Kajan & Akawi, Lamees & Moo-Young, Murray & Chou, C. Perry, 2012. "Towards sustainable production of clean energy carriers from biomass resources," Applied Energy, Elsevier, vol. 100(C), pages 172-186.
    2. Wu, Shijie & Ren, Zongqiang & Hu, Qiang & Yao, Dingding & Yang, Haiping, 2024. "Upcycling plastic waste into syngas by staged chemical looping gasification with modified Fe-based oxygen carriers," Applied Energy, Elsevier, vol. 353(PB).
    3. Jeff Tollefson, 2025. "Earth breaches 1.5 °C climate limit for the first time: what does it mean?," Nature, Nature, vol. 637(8047), pages 769-770, January.
    4. Schneider, T. & Moffitt, J. & Volz, N. & Müller, D. & Karl, J., 2022. "Long-term effects of ilmenite on a micro-scale bubbling fluidized bed combined heat and power pilot plant for oxygen carrier aided combustion of wood," Applied Energy, Elsevier, vol. 314(C).
    5. Riley, Jarrett & Siriwardane, Ranjani & Tian, Hanjing & Benincosa, William & Poston, James, 2017. "Kinetic analysis of the interactions between calcium ferrite and coal char for chemical looping gasification applications: Identifying reduction routes and modes of oxygen transfer," Applied Energy, Elsevier, vol. 201(C), pages 94-110.
    6. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.
    7. Nguyen, Nhut M. & Alobaid, Falah & Epple, Bernd, 2021. "Chemical looping gasification of torrefied woodchips in a bubbling fluidized bed test rig using iron-based oxygen carriers," Renewable Energy, Elsevier, vol. 172(C), pages 34-45.
    8. Huang, Zhen & Deng, Zhengbing & Chen, Dezhen & He, Fang & Liu, Shuai & Zhao, Kun & Wei, Guoqiang & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2017. "Thermodynamic analysis and kinetic investigations on biomass char chemical looping gasification using Fe-Ni bimetallic oxygen carrier," Energy, Elsevier, vol. 141(C), pages 1836-1844.
    9. Quan, Jinxia & Miao, Zhenwu & Lin, Yousheng & Lv, Juan & Liu, Hailu & Feng, Chunzhou & Jiang, Enchen & Hu, Zhifeng, 2023. "Agglomeration mechanism of Fe2O3/Al2O3 oxygen carrier in chemical looping gasification," Energy, Elsevier, vol. 284(C).
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