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Carbon negative methanol production for CO2 utilization: Process design and 4E analysis

Author

Listed:
  • Tang, Zongyue
  • Zhang, Leiyu
  • Wang, Lei
  • Gao, Ruxing
  • Jun, Ki-Won
  • Kim, Seok Ki
  • Zhang, Chundong
  • Yang, Yingju
  • Wan, Hui
  • Guan, Guofeng

Abstract

To produce alternative fuel and reduce CO2 emissions, the CO2-to-methanol (CTM) process is currently considered to be an effective technical pathway. However, the base CTM process suffers from high energy consumption and low carbon efficiency. Therefore, this work proposed an optimized CTM process integrating double-effect distillation, waste heat recovery, and H2 stripping technologies. Compared to the base CTM process, the optimized CTM process significantly enhances the techno-economic-environmental performances. Meanwhile, it realizes zero external heat requirements and negative carbon emissions. In order to quantitatively evaluate the improvements in the process performances, we conducted detailed technical-economic-environmental analyses. From the technical perspective, the energy efficiency and exergy efficiency of the optimized CTM process are 10.28 % and 4.84 % higher than that of the base CTM process, respectively. From the economic perspective, the methanol production cost in the optimized CTM process is lower by 18.40 $/tonne MeOH compared to the base CTM process. As for the environmental perspective, the GWP of the optimized CTM process is reduced by 336.42 kg CO2-eq/tonne MeOH compared with the base CTM process. In summary, the optimized CTM process offers an energy-efficient, cost-saving, and environment-friendly solution for CO2 conversion.

Suggested Citation

  • Tang, Zongyue & Zhang, Leiyu & Wang, Lei & Gao, Ruxing & Jun, Ki-Won & Kim, Seok Ki & Zhang, Chundong & Yang, Yingju & Wan, Hui & Guan, Guofeng, 2024. "Carbon negative methanol production for CO2 utilization: Process design and 4E analysis," Energy, Elsevier, vol. 313(C).
    • Handle: RePEc:eee:energy:v:313:y:2024:i:c:s0360544224038428
    DOI: 10.1016/j.energy.2024.134064
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    as
    1. Herz, Gregor & Rix, Christopher & Jacobasch, Eric & Müller, Nils & Reichelt, Erik & Jahn, Matthias & Michaelis, Alexander, 2021. "Economic assessment of Power-to-Liquid processes – Influence of electrolysis technology and operating conditions," Applied Energy, Elsevier, vol. 292(C).
    2. Yang, Qingchun & Xu, Simin & Zhang, Jinliang & Liu, Chenglin & Zhang, Dawei & Zhou, Huairong & Mei, Shumei & Gao, Minglin & Liu, Hongyan, 2021. "Thermodynamic and techno-economic analyses of a novel integrated process of coal gasification and methane tri-reforming to ethylene glycol with low carbon emission and high efficiency," Energy, Elsevier, vol. 229(C).
    3. Liu, Yigang & Li, Guoxuan & Chen, Zhengrun & Shen, Yuanyuan & Zhang, Hongru & Wang, Shuai & Qi, Jianguang & Zhu, Zhaoyou & Wang, Yinglong & Gao, Jun, 2020. "Comprehensive analysis of environmental impacts and energy consumption of biomass-to-methanol and coal-to-methanol via life cycle assessment," Energy, Elsevier, vol. 204(C).
    4. Huang, Yue & Zhu, Lin & He, Yangdong & Wang, Yuan & Hao, Qiang & Zhu, Yifei, 2023. "Carbon dioxide utilization based on exergoenvironmental sustainability assessment: A case study of CO2 hydrogenation to methanol," Energy, Elsevier, vol. 273(C).
    5. Gu, Hongfei & Liu, Jianzi & Zhou, Xingchen & Wu, Qiwei & Liu, Yaodong & Yu, Shuaixian & Qiu, Wenying & Xu, Jianguo, 2023. "Modelling of a novel electricity and methanol co-generation using heat recovery and CO2 capture: Comprehensive thermodynamic, economic, and environmental analyses," Energy, Elsevier, vol. 278(C).
    6. Wang, Yuting & Chen, Heng & Qiao, Shichao & Pan, Peiyuan & Xu, Gang & Dong, Yuehong & Jiang, Xue, 2023. "A novel methanol-electricity cogeneration system based on the integration of water electrolysis and plasma waste gasification," Energy, Elsevier, vol. 267(C).
    7. Qiu, Fei & Sun, Zhen & Li, Huiping & Qian, Qian, 2023. "Process simulation and multi-aspect analysis of methanol production through blast furnace gas and landfill gas," Energy, Elsevier, vol. 285(C).
    8. Lee, Boreum & Lee, Hyunjun & Lim, Dongjun & Brigljević, Boris & Cho, Wonchul & Cho, Hyun-Seok & Kim, Chang-Hee & Lim, Hankwon, 2020. "Renewable methanol synthesis from renewable H2 and captured CO2: How can power-to-liquid technology be economically feasible?," Applied Energy, Elsevier, vol. 279(C).
    9. Anicic, B. & Trop, P. & Goricanec, D., 2014. "Comparison between two methods of methanol production from carbon dioxide," Energy, Elsevier, vol. 77(C), pages 279-289.
    10. Zhang, Qi & Gao, Jintong & Wang, Yujie & Wang, Lin & Yu, Zaihai & Song, Dayong, 2019. "Exergy-based analysis combined with LCA for waste heat recovery in coal-fired CHP plants," Energy, Elsevier, vol. 169(C), pages 247-262.
    11. Galusnyak, Stefan Cristian & Petrescu, Letitia & Chisalita, Dora Andreea & Cormos, Calin-Cristian, 2022. "Life cycle assessment of methanol production and conversion into various chemical intermediates and products," Energy, Elsevier, vol. 259(C).
    12. Rahmat, Yoga & Maier, Simon & Moser, Francisco & Raab, Moritz & Hoffmann, Christian & Repke, Jens-Uwe & Dietrich, Ralph-Uwe, 2023. "Techno-economic and exergy analysis of e-methanol production under fixed operating conditions in Germany," Applied Energy, Elsevier, vol. 351(C).
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