IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v260y2022ics0360544222020990.html
   My bibliography  Save this article

Highly selective Pd composite membrane on porous metal support for high-purity hydrogen production through effective ammonia decomposition

Author

Listed:
  • Kim, Tae-Woo
  • Lee, Eun-Han
  • Byun, Segi
  • Seo, Doo-Won
  • Hwang, Hyo-Jung
  • Yoon, Hyung-Chul
  • Kim, Hansung
  • Ryi, Shin-Kun

Abstract

In this study, an alumina sol assisted pretreatment method for porous metal supports was investigated for a highly selective Pd composite membrane for ammonia decomposition. Alumina sol made of boehmite was applied to an yttria-stabilized zirconia (YSZ) filled porous Inconel support. Additionally, a vacuum-assisted, two-step electroless plating of Pd drastically increased the hydrogen selectivity. The hydrogen permeation flux and selectivity (H2/N2) measured at 723 K and a transmembrane pressure difference of 100 kPa were 3.40 × 10−1 mol m−2 s−1 and 8,050, respectively. A highly selective Pd composite membrane was applied to a membrane reactor combined with a Ru/Al2O3 catalyst to efficiently produce high-purity hydrogen by ammonia decomposition. The ammonia decomposition test showed that the membrane reactor was able to achieve a high ammonia conversion (99.6%) and a high hydrogen purity (99.99%) with a hydrogen production rate of 0.25 Nm3 h−1 at 745 K and a gauge pressure of 500 kPa. The Pd composite membrane reactor has the advantage of being able to selectively removing hydrogen, increasing the ammonia conversion rate and high-purity hydrogen production via a one-step reaction combined with purification.

Suggested Citation

  • Kim, Tae-Woo & Lee, Eun-Han & Byun, Segi & Seo, Doo-Won & Hwang, Hyo-Jung & Yoon, Hyung-Chul & Kim, Hansung & Ryi, Shin-Kun, 2022. "Highly selective Pd composite membrane on porous metal support for high-purity hydrogen production through effective ammonia decomposition," Energy, Elsevier, vol. 260(C).
    • Handle: RePEc:eee:energy:v:260:y:2022:i:c:s0360544222020990
    DOI: 10.1016/j.energy.2022.125209
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222020990
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.125209?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ryi, Shin-Kun & Lee, Chun-Boo & Lee, Sung-Wook & Hwang, Kyung-Ran & Park, Jong-Soo, 2012. "Hydrogen recovery from ethylene mixture with PD-AU composite membrane," Energy, Elsevier, vol. 47(1), pages 3-10.
    2. Chiari, Luca & Zecca, Antonio, 2011. "Constraints of fossil fuels depletion on global warming projections," Energy Policy, Elsevier, vol. 39(9), pages 5026-5034, September.
    3. Chen, Wei-Hsin & Escalante, Jamin, 2020. "Influence of vacuum degree on hydrogen permeation through a Pd membrane in different H2/N2 gas mixtures," Renewable Energy, Elsevier, vol. 155(C), pages 1245-1263.
    4. Hosseini, Seyed Ehsan & Andwari, Amin Mahmoudzadeh & Wahid, Mazlan Abdul & Bagheri, Ghobad, 2013. "A review on green energy potentials in Iran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 533-545.
    5. Muhammad Aziz & Agung Tri Wijayanta & Asep Bayu Dani Nandiyanto, 2020. "Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization," Energies, MDPI, vol. 13(12), pages 1-25, June.
    6. Velazquez Abad, Anthony & Dodds, Paul E., 2020. "Green hydrogen characterisation initiatives: Definitions, standards, guarantees of origin, and challenges," Energy Policy, Elsevier, vol. 138(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chung, Kyong-Hwan & Park, Young-Kwon & Kim, Sun-Jae & Kim, Sang-Chai & Jung, Sang-Chul, 2023. "Green hydrogen production from ammonia water by liquid–plasma cracking on solid acid catalysts," Renewable Energy, Elsevier, vol. 216(C).
    2. Tang, Xin-Yuan & Yang, Wei-Wei & Ma, Xu & Cao, Xiangkun Elvis, 2023. "An integrated modeling method for membrane reactors and optimization study of operating conditions," Energy, Elsevier, vol. 268(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ishaq, H. & Dincer, I., 2021. "Comparative assessment of renewable energy-based hydrogen production methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    2. Azadnia, Amir Hossein & McDaid, Conor & Andwari, Amin Mahmoudzadeh & Hosseini, Seyed Ehsan, 2023. "Green hydrogen supply chain risk analysis: A european hard-to-abate sectors perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    3. Konstantin Gomonov & Marina Reshetnikova & Svetlana Ratner, 2023. "Economic Analysis of Recently Announced Green Hydrogen Projects in Russia: A Multiple Case Study," Energies, MDPI, vol. 16(10), pages 1-15, May.
    4. Lee, Sung-Wook & Park, Jong-Soo & Lee, Chun-Boo & Lee, Dong-Wook & Kim, Hakjoo & Ra, Ho Won & Kim, Sung-Hyun & Ryi, Shin-Kun, 2014. "H2 recovery and CO2 capture after water–gas shift reactor using synthesis gas from coal gasification," Energy, Elsevier, vol. 66(C), pages 635-642.
    5. Hosseini, Seyed Ehsan & Wahid, Mazlan Abdul, 2014. "Development of biogas combustion in combined heat and power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 868-875.
    6. Amirinia, Gholamreza & Mafi, Somayeh & Mazaheri, Said, 2017. "Offshore wind resource assessment of Persian Gulf using uncertainty analysis and GIS," Renewable Energy, Elsevier, vol. 113(C), pages 915-929.
    7. Hong, Sanghyun & Kim, Eunsung & Jeong, Saerok, 2023. "Evaluating the sustainability of the hydrogen economy using multi-criteria decision-making analysis in Korea," Renewable Energy, Elsevier, vol. 204(C), pages 485-492.
    8. Michel Noussan & Pier Paolo Raimondi & Rossana Scita & Manfred Hafner, 2020. "The Role of Green and Blue Hydrogen in the Energy Transition—A Technological and Geopolitical Perspective," Sustainability, MDPI, vol. 13(1), pages 1-26, December.
    9. Richard P. van Leeuwen & Annelies E. Boerman & Edmund W. Schaefer & Gerwin Hoogsteen & Yashar S. Hajimolana, 2022. "Model Supported Business Case Scenario Analysis for Decentral Hydrogen Conversion, Storage and Consumption within Energy Hubs," Energies, MDPI, vol. 15(6), pages 1-22, March.
    10. Lambert, Jerry & Hanel, Andreas & Fendt, Sebastian & Spliethoff, Hartmut, 2023. "Evaluation of sector-coupled energy systems using different foresight horizons," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    11. Andwari, Amin Mahmoudzadeh & Aziz, Azhar Abdul & Said, Mohd Farid Muhamad & Latiff, Zulkarnain Abdul, 2014. "Experimental investigation of the influence of internal and external EGR on the combustion characteristics of a controlled auto-ignition two-stroke cycle engine," Applied Energy, Elsevier, vol. 134(C), pages 1-10.
    12. Olabi, A.G. & Wilberforce, Tabbi & Abdelkareem, Mohammad Ali, 2021. "Fuel cell application in the automotive industry and future perspective," Energy, Elsevier, vol. 214(C).
    13. Jingna Kou & Wei Li & Rui Zhang & Dingxiong Shi, 2023. "Hydrogen as a Transition Tool in a Fossil Fuel Resource Region: Taking China’s Coal Capital Shanxi as an Example," Sustainability, MDPI, vol. 15(15), pages 1-19, August.
    14. Muhammad Aziz, 2021. "Liquid Hydrogen: A Review on Liquefaction, Storage, Transportation, and Safety," Energies, MDPI, vol. 14(18), pages 1-29, September.
    15. Förster, Robert & Kaiser, Matthias & Wenninger, Simon, 2023. "Future vehicle energy supply - sustainable design and operation of hybrid hydrogen and electric microgrids," Applied Energy, Elsevier, vol. 334(C).
    16. Najafi, G. & Ghobadian, B. & Mamat, R. & Yusaf, T. & Azmi, W.H., 2015. "Solar energy in Iran: Current state and outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 49(C), pages 931-942.
    17. Neeraj Sharma & Rajat Agrawal, 2017. "Locating a Wind Energy Project: A Case of a Leading Oil and Gas Producer in India," Vision, , vol. 21(2), pages 172-194, June.
    18. Hosseini, Seyed Ehsan & Wahid, Mazlan Abdul & Aghili, Nasim, 2013. "The scenario of greenhouse gases reduction in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 400-409.
    19. Carlos A. Castilla-Martinez & Romain Moury & Salem Ould-Amara & Umit B. Demirci, 2021. "Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances," Energies, MDPI, vol. 14(21), pages 1-50, October.
    20. Yaghoubi, Jafar & Yazdanpanah, Masoud & Komendantova, Nadejda, 2019. "Iranian agriculture advisors' perception and intention toward biofuel: Green way toward energy security, rural development and climate change mitigation," Renewable Energy, Elsevier, vol. 130(C), pages 452-459.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:260:y:2022:i:c:s0360544222020990. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.