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Highly selective Pd composite membrane on porous metal support for high-purity hydrogen production through effective ammonia decomposition

Author

Listed:
  • Kim, Tae-Woo
  • Lee, Eun-Han
  • Byun, Segi
  • Seo, Doo-Won
  • Hwang, Hyo-Jung
  • Yoon, Hyung-Chul
  • Kim, Hansung
  • Ryi, Shin-Kun

Abstract

In this study, an alumina sol assisted pretreatment method for porous metal supports was investigated for a highly selective Pd composite membrane for ammonia decomposition. Alumina sol made of boehmite was applied to an yttria-stabilized zirconia (YSZ) filled porous Inconel support. Additionally, a vacuum-assisted, two-step electroless plating of Pd drastically increased the hydrogen selectivity. The hydrogen permeation flux and selectivity (H2/N2) measured at 723 K and a transmembrane pressure difference of 100 kPa were 3.40 × 10−1 mol m−2 s−1 and 8,050, respectively. A highly selective Pd composite membrane was applied to a membrane reactor combined with a Ru/Al2O3 catalyst to efficiently produce high-purity hydrogen by ammonia decomposition. The ammonia decomposition test showed that the membrane reactor was able to achieve a high ammonia conversion (99.6%) and a high hydrogen purity (99.99%) with a hydrogen production rate of 0.25 Nm3 h−1 at 745 K and a gauge pressure of 500 kPa. The Pd composite membrane reactor has the advantage of being able to selectively removing hydrogen, increasing the ammonia conversion rate and high-purity hydrogen production via a one-step reaction combined with purification.

Suggested Citation

  • Kim, Tae-Woo & Lee, Eun-Han & Byun, Segi & Seo, Doo-Won & Hwang, Hyo-Jung & Yoon, Hyung-Chul & Kim, Hansung & Ryi, Shin-Kun, 2022. "Highly selective Pd composite membrane on porous metal support for high-purity hydrogen production through effective ammonia decomposition," Energy, Elsevier, vol. 260(C).
    • Handle: RePEc:eee:energy:v:260:y:2022:i:c:s0360544222020990
    DOI: 10.1016/j.energy.2022.125209
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    References listed on IDEAS

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    1. Chung, Kyong-Hwan & Park, Young-Kwon & Kim, Sun-Jae & Kim, Sang-Chai & Jung, Sang-Chul, 2023. "Green hydrogen production from ammonia water by liquid–plasma cracking on solid acid catalysts," Renewable Energy, Elsevier, vol. 216(C).
    2. Yang, Wei-Wei & Tang, Xin-Yuan & Ma, Xu & Li, Jia-Chen & Xu, Chao & He, Ya-Ling, 2023. "Rapid prediction, optimization and design of solar membrane reactor by data-driven surrogate model," Energy, Elsevier, vol. 285(C).
    3. Tang, Xin-Yuan & Yang, Wei-Wei & Ma, Xu & Cao, Xiangkun Elvis, 2023. "An integrated modeling method for membrane reactors and optimization study of operating conditions," Energy, Elsevier, vol. 268(C).
    4. Tang, Xin-Yuan & Yang, Wei-Wei & Ma, Xu & He, Ya-Ling, 2024. "Bionic leaf-inspired catalyst bed structure for solar membrane reactor aiming at efficient hydrogen production and separation," Applied Energy, Elsevier, vol. 355(C).

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