IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v258y2022ics0360544222016504.html
   My bibliography  Save this article

Investigation of the reversible performance degradation mechanism of the PEMFC stack during long-term durability test

Author

Listed:
  • Chu, Tiankuo
  • Wang, Qinpu
  • Xie, Meng
  • Wang, Baoyun
  • Yang, Daijun
  • Li, Bing
  • Ming, Pingwen
  • Zhang, Cunman

Abstract

This paper reports on 3-cell PEMFC stack durability test of 2500 h in dynamic conditions and different recovery procedures. After electrochemical impedance spectroscopy (EIS) analysis, it was determined that the primary cause of the stack performance degradation is the oxidation of platinum (Pt), which is reversible. The air starvation operation reduced the cathode voltage to less than 0.2 V, part of PtO was reduced, and the stack performance loss was partially recovered. However, the recovery of the three cells varies due to defects in the three-cell stack and uneven gas distribution. The fast load-up operation brought the short-term severe air starvation of the three cells to a similar level, the remaining platinum oxide (PtO) was fully reduced, the stack performance improved again, and the voltage consistency of the three cells was restored significantly. With the optimization of operating parameters and combined recovery procedures, the average degradation rate of the stack voltage is 3.08 μV/h within 2500 h. The results indicated that our combined strategy is of huge importance to mitigate the reversible performance degradation and significantly extend the service life of PEMFC stack and be a very appropriate procedure used in laboratories and systems.

Suggested Citation

  • Chu, Tiankuo & Wang, Qinpu & Xie, Meng & Wang, Baoyun & Yang, Daijun & Li, Bing & Ming, Pingwen & Zhang, Cunman, 2022. "Investigation of the reversible performance degradation mechanism of the PEMFC stack during long-term durability test," Energy, Elsevier, vol. 258(C).
    • Handle: RePEc:eee:energy:v:258:y:2022:i:c:s0360544222016504
    DOI: 10.1016/j.energy.2022.124747
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222016504
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.124747?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Mark K. Debe, 2012. "Electrocatalyst approaches and challenges for automotive fuel cells," Nature, Nature, vol. 486(7401), pages 43-51, June.
    2. Chu, Tiankuo & Zhang, Ruofan & Wang, Yanbo & Ou, Mingyang & Xie, Meng & Shao, Hangyu & Yang, Daijun & Li, Bing & Ming, Pingwen & Zhang, Cunman, 2021. "Performance degradation and process engineering of the 10 kW proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 219(C).
    3. Pei, Pucheng & Chen, Huicui, 2014. "Main factors affecting the lifetime of Proton Exchange Membrane fuel cells in vehicle applications: A review," Applied Energy, Elsevier, vol. 125(C), pages 60-75.
    4. Wang, Junye, 2017. "System integration, durability and reliability of fuel cells: Challenges and solutions," Applied Energy, Elsevier, vol. 189(C), pages 460-479.
    5. Chu, Tiankuo & Xie, Meng & Yu, Yue & Wang, Baoyun & Yang, Daijun & Li, Bing & Ming, Pingwen & Zhang, Cunman, 2022. "Experimental study of the influence of dynamic load cycle and operating parameters on the durability of PEMFC," Energy, Elsevier, vol. 239(PD).
    6. Yang, Zirong & Du, Qing & Jia, Zhiwei & Yang, Chunguang & Jiao, Kui, 2019. "Effects of operating conditions on water and heat management by a transient multi-dimensional PEMFC system model," Energy, Elsevier, vol. 183(C), pages 462-476.
    7. Olabi, A.G. & Wilberforce, Tabbi & Abdelkareem, Mohammad Ali, 2021. "Fuel cell application in the automotive industry and future perspective," Energy, Elsevier, vol. 214(C).
    8. Zhang, Qian & Schulze, Mathias & Gazdzicki, Pawel & Friedrich, K. Andreas, 2021. "Comparison of different performance recovery procedures for polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 302(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pei, Pucheng & Meng, Yining & Chen, Dongfang & Ren, Peng & Wang, Mingkai & Wang, Xizhong, 2023. "Lifetime prediction method of proton exchange membrane fuel cells based on current degradation law," Energy, Elsevier, vol. 265(C).
    2. Li, Changzhi & Lin, Wei & Wu, Hangyu & Li, Yang & Zhu, Wenchao & Xie, Changjun & Gooi, Hoay Beng & Zhao, Bo & Zhang, Leiqi, 2023. "Performance degradation decomposition-ensemble prediction of PEMFC using CEEMDAN and dual data-driven model," Renewable Energy, Elsevier, vol. 215(C).
    3. Antoine Bäumler & Jianwen Meng & Abdelmoudjib Benterki & Toufik Azib & Moussa Boukhnifer, 2023. "A System-Level Modeling of PEMFC Considering Degradation Aspect towards a Diagnosis Process," Energies, MDPI, vol. 16(14), pages 1-19, July.
    4. Guan, Dong & Pan, Biyu & Chen, Zhen & Li, Jing & Shen, Hui & Pang, Huan, 2023. "Quantitative modeling and bio-inspired optimization the clamping load on the bipolar plate in PEMFC," Energy, Elsevier, vol. 263(PD).
    5. Yu, Xianxian & Luo, Xiaobing & Tu, Zhengkai, 2023. "Development of a compact high-power density air-cooled proton exchange membrane fuel cell stack with ultrathin steel bipolar plates," Energy, Elsevier, vol. 270(C).
    6. Fan, Lixin & liu, Yang & Luo, Xiaobing & Tu, Zhengkai & Chan, Siew Hwa, 2023. "A novel gas supply configuration for hydrogen utilization improvement in a multi-stack air-cooling PEMFC system with dead-ended anode," Energy, Elsevier, vol. 282(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chu, Tiankuo & Xie, Meng & Yu, Yue & Wang, Baoyun & Yang, Daijun & Li, Bing & Ming, Pingwen & Zhang, Cunman, 2022. "Experimental study of the influence of dynamic load cycle and operating parameters on the durability of PEMFC," Energy, Elsevier, vol. 239(PD).
    2. Chen, Dongfang & Pei, Pucheng & Meng, Yining & Ren, Peng & Li, Yuehua & Wang, Mingkai & Wang, Xizhong, 2022. "Novel extraction method of working condition spectrum for the lifetime prediction and energy management strategy evaluation of automotive fuel cells," Energy, Elsevier, vol. 255(C).
    3. Xiao, Biao & Zhao, Junjie & Fan, Lixin & Liu, Yang & Chan, Siew Hwa & Tu, Zhengkai, 2022. "Effects of moisture dehumidification on the performance and degradation of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 245(C).
    4. Martin, S. & Garcia-Ybarra, P.L. & Castillo, J.L., 2017. "Long-term operation of a proton exchange membrane fuel cell without external humidification," Applied Energy, Elsevier, vol. 205(C), pages 1012-1020.
    5. Huang, Weifeng & Niu, Tong & Zhang, Caizhi & Fu, Zuhang & Zhang, Yuqi & Zhou, Weijiang & Pan, Zehua & Zhang, Kaiqing, 2023. "Experimental study of the performance degradation of proton exchange membrane fuel cell based on a multi-module stack under selected load profiles by clustering algorithm," Energy, Elsevier, vol. 270(C).
    6. Zhao, Junjie & Tu, Zhengkai & Chan, Siew Hwa, 2022. "In-situ measurement of humidity distribution and its effect on the performance of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 239(PD).
    7. Zheng Huang & Laisuo Su & Yunjie Yang & Linsong Gao & Xinyu Liu & Heng Huang & Yubai Li & Yongchen Song, 2023. "Three-Dimensional Simulation on the Effects of Different Parameters and Pt Loading on the Long-Term Performance of Proton Exchange Membrane Fuel Cells," Sustainability, MDPI, vol. 15(4), pages 1-22, February.
    8. Najmi, Aezid-Ul-Hassan & Anyanwu, Ikechukwu S. & Xie, Xu & Liu, Zhi & Jiao, Kui, 2021. "Experimental investigation and optimization of proton exchange membrane fuel cell using different flow fields," Energy, Elsevier, vol. 217(C).
    9. Venkatesan, Suriya & Mitzel, Jens & Wegner, Karsten & Costa, Remi & Gazdzicki, Pawel & Friedrich, Kaspar Andreas, 2022. "Nanomaterials and films for polymer electrolyte membrane fuel cells and solid oxide cells by flame spray pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    10. Komini Babu, S. & Spernjak, D. & Dillet, J. & Lamibrac, A. & Maranzana, G. & Didierjean, S. & Lottin, O. & Borup, R.L. & Mukundan, R., 2019. "Spatially resolved degradation during startup and shutdown in polymer electrolyte membrane fuel cell operation," Applied Energy, Elsevier, vol. 254(C).
    11. Zhang, Tong & Wang, Peiqi & Chen, Huicui & Pei, Pucheng, 2018. "A review of automotive proton exchange membrane fuel cell degradation under start-stop operating condition," Applied Energy, Elsevier, vol. 223(C), pages 249-262.
    12. Zhang, Hongtao & Li, Xianguo & Liu, Xinzhi & Yan, Jinyue, 2019. "Enhancing fuel cell durability for fuel cell plug-in hybrid electric vehicles through strategic power management," Applied Energy, Elsevier, vol. 241(C), pages 483-490.
    13. Li, Yanju & Li, Dongxu & Ma, Zheshu & Zheng, Meng & Lu, Zhanghao & Song, Hanlin & Guo, Xinjia & Shao, Wei, 2022. "Performance analysis and optimization of a novel vehicular power system based on HT-PEMFC integrated methanol steam reforming and ORC," Energy, Elsevier, vol. 257(C).
    14. Saka, Kenan & Orhan, Mehmet Fatih, 2022. "Analysis of stack operating conditions for a polymer electrolyte membrane fuel cell," Energy, Elsevier, vol. 258(C).
    15. Li, Haolong & Chen, Qihong & Zhang, Liyan & Liu, Li & Xiao, Peng, 2023. "Degradation prediction of proton exchange membrane fuel cell based on the multi-inputs Bi-directional long short-term memory," Applied Energy, Elsevier, vol. 344(C).
    16. Vu, Hoang Nghia & Truong Le Tri, Dat & Nguyen, Huu Linh & Kim, Younghyeon & Yu, Sangseok, 2023. "Multifunctional bypass valve for water management and surge protection in a proton-exchange membrane fuel cell supply-air system," Energy, Elsevier, vol. 278(C).
    17. Guan, Dong & Pan, Biyu & Chen, Zhen & Li, Jing & Shen, Hui & Pang, Huan, 2023. "Quantitative modeling and bio-inspired optimization the clamping load on the bipolar plate in PEMFC," Energy, Elsevier, vol. 263(PD).
    18. Eapen, Deepa Elizabeth & Suresh, Resmi & Patil, Sairaj & Rengaswamy, Raghunathan, 2021. "A systems engineering perspective on electrochemical energy technologies and a framework for application driven choice of technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    19. Lochner, Tim & Hallitzky, Laurens & Perchthaler, Markus & Obermaier, Michael & Sabawa, Jarek & Enz, Simon & Bandarenka, Aliaksandr S., 2020. "Local degradation effects in automotive size membrane electrode assemblies under realistic operating conditions," Applied Energy, Elsevier, vol. 260(C).
    20. Xuan, Lingfeng & Wang, Yancheng & Lan, Jinwei & Tao, Kai & Zhou, Caiying & Mei, Deqing, 2023. "Development of cathode ordered membrane electrode assembly based on TiO2 nanowire array and ultrasonic spraying," Energy, Elsevier, vol. 264(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:258:y:2022:i:c:s0360544222016504. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.