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Thermodynamic and kinetic modeling of a novel polyamine-based solvent for energy-efficient CO2 capture with energy analysis

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  • Jung, Wonho
  • Lee, Jinwon

Abstract

Polyamine-based solvents (PSs) are regarded to be emerging energy-efficient alternatives to conventional solvents for use in absorption-based CO2 capture. In this paper, we propose a novel polyamine, 3,3′-iminobis (N,N-dimethylpropylamine) (IBDMPA), based aqueous amine solution. The solvent was composed of 45 wt% IBDMPA and 48 wt% water, with a non-amine chemical making up the rest of the mixture. Thermodynamic modeling work of CO2 solubility was carried out using Aspen Plus® V10, and the Elec-NRTL model with the Redlick-Kwong equation was integrated with the equilibrium model. For CO2 solubility modeling, measurement data was obtained from the equilibrium cell and 1H/13C nuclear magnetic resonance and used to validate the CO2 solubility modeling. Kinetic modeling of the proposed PS was conducted using a tertiary amine reaction mechanism, and the measurement data for the overall mass transfer coefficient was obtained using a wetted wall column. PS has cyclic capacity of approximately 1.05 mol-CO2/mol-IBD and overall mass transfer coefficient of 2.51e-03 mol m−2 kPa−1 sec−1, which is much higher than that of conventional MEA 30 wt% solution (0.35 mol-CO2/mol-MEA and 1.05e-03 mol m−2 kPa−1 sec−1). As a result, the minimum energy required for reboiler was calculated to be 2.3 GJ t-CO2−1 at 1 bara of the desorber pressure. Such a low energy demand value supports the commercial feasibility of polyamine-based solvents for large-scale CO2 capture.

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  • Jung, Wonho & Lee, Jinwon, 2022. "Thermodynamic and kinetic modeling of a novel polyamine-based solvent for energy-efficient CO2 capture with energy analysis," Energy, Elsevier, vol. 239(PE).
    • Handle: RePEc:eee:energy:v:239:y:2022:i:pe:s0360544221025962
    DOI: 10.1016/j.energy.2021.122347
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    References listed on IDEAS

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    1. Jung, Wonho & Park, Junhyung & Won, Wangyun & Lee, Kwang Soon, 2018. "Simulated moving bed adsorption process based on a polyethylenimine-silica sorbent for CO2 capture with sensible heat recovery," Energy, Elsevier, vol. 150(C), pages 950-964.
    2. Chu, Fengming & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2016. "CO2 capture using MEA (monoethanolamine) aqueous solution in coal-fired power plants: Modeling and optimization of the absorbing columns," Energy, Elsevier, vol. 109(C), pages 495-505.
    3. Michaelides, Efstathios E., 2021. "Thermodynamic analysis and power requirements of CO2 capture, transportation, and storage in the ocean," Energy, Elsevier, vol. 230(C).
    4. Jung, Wonho & Lee, Kwang Soon, 2019. "Novel short-cut estimation method for the optimum total energy demand of solid sorbents in an adsorption-based CO2 capture process," Energy, Elsevier, vol. 180(C), pages 640-648.
    5. Hosseini-Ardali, Seyed Mohsen & Hazrati-Kalbibaki, Majid & Fattahi, Moslem & Lezsovits, Ferenc, 2020. "Multi-objective optimization of post combustion CO2 capture using methyldiethanolamine (MDEA) and piperazine (PZ) bi-solvent," Energy, Elsevier, vol. 211(C).
    6. Mores, Patricia & Scenna, Nicolás & Mussati, Sergio, 2012. "CO2 capture using monoethanolamine (MEA) aqueous solution: Modeling and optimization of the solvent regeneration and CO2 desorption process," Energy, Elsevier, vol. 45(1), pages 1042-1058.
    7. Wu, Jiafeng & Chen, Yaping & Zhu, Zilong & Zheng, Shuxing, 2020. "Analysis on full CO2 capture schemes in NG/O2 combustion gas and steam mixture cycle (GSMC)," Energy, Elsevier, vol. 191(C).
    8. Wang, Junyao & Sun, Taiwei & Zhao, Jun & Deng, Shuai & Li, Kaixiang & Xu, Yaofeng & Fu, Jianxin, 2019. "Thermodynamic considerations on MEA absorption: Whether thermodynamic cycle could be used as a tool for energy efficiency analysis," Energy, Elsevier, vol. 168(C), pages 380-392.
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    1. Neha Agarwal & Le Cao Nhien & Moonyong Lee, 2022. "Rate-Based Modeling and Assessment of an Amine-Based Acid Gas Removal Process through a Comprehensive Solvent Selection Procedure," Energies, MDPI, vol. 15(18), pages 1-17, September.

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