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Thermo-catalytic co-pyrolysis of biomass and high-density polyethylene for improving the yield and quality of pyrolysis liquid

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  • Rahman, Md Hafizur
  • Bhoi, Prakashbhai R.
  • Saha, Arpita
  • Patil, Vivek
  • Adhikari, Sushil

Abstract

The overall goal of this research was to study the effects of temperature and pine-to-HDPE ratios on the pyrolysis products. Catalytic co-pyrolysis of pine and HDPE was carried out in a double-column staged reactor, wherein the temperature was varied as 450 °C, 500 °C, and 550 °C for each pine/HDPE ratio of 0/100, 25/75, 50/50, 75/25, and 100/0. Thermal cracking of the feedstock is initiated at the first column, and the zeolitic-based ZSM-5 catalyst offered secondary cracking at a catalyst-to-feedstock ratio of 1:1 in the second column of the reactor. Catalytic pyrolysis of HDPE produced 31 wt% pyrolysis oil (40 MJ/kg calorific value) with a selectivity of above 90% toward gasoline-range hydrocarbons at 500 °C. Comparatively, pine offered 26.3% wt.% pyrolysis liquid yield with 7.9% dark pyrolysis oil (30 MJ/kg calorific value) that has a gasoline selectivity of 69.3%. Thus, the addition of HDPE increased the gasoline selectivity by increasing the hydrogen/carbon effective (H/Ceff) ratio. At pine/HDPE ratio of 25/75, the pyrolysis oil content was 22.5% at 500 °C, which is 3 times more than that of pine pyrolysis. The optimum yield and higher gasoline selectivity were observed at 500 °C for 0/100 and 25/75 pine to HDPE ratios.

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  • Rahman, Md Hafizur & Bhoi, Prakashbhai R. & Saha, Arpita & Patil, Vivek & Adhikari, Sushil, 2021. "Thermo-catalytic co-pyrolysis of biomass and high-density polyethylene for improving the yield and quality of pyrolysis liquid," Energy, Elsevier, vol. 225(C).
  • Handle: RePEc:eee:energy:v:225:y:2021:i:c:s0360544221004801
    DOI: 10.1016/j.energy.2021.120231
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    Cited by:

    1. Arnob Das & Susmita Datta Peu, 2022. "A Comprehensive Review on Recent Advancements in Thermochemical Processes for Clean Hydrogen Production to Decarbonize the Energy Sector," Sustainability, MDPI, vol. 14(18), pages 1-42, September.
    2. Rahman, Md Hafizur & Bhoi, Prakashbhai R. & Menezes, Pradeep L., 2023. "Pyrolysis of waste plastics into fuels and chemicals: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    3. Fan, Yongsheng & Lu, Dongsheng & Han, Yue & Yang, Jiaheng & Qian, Cheng & Li, Binyu, 2023. "Production of light aromatics from biomass components co-pyrolyzed with polyethylene via non-thermal plasma synergistic upgrading," Energy, Elsevier, vol. 265(C).
    4. Chen, Chunxiang & Fan, Dianzhao & Zhao, Jian & Qi, Qianhao & Huang, Xiaodong & Zeng, Tianyang & Bi, Yingxin, 2022. "Study on microwave-assisted co-pyrolysis and bio-oil of Chlorella vulgaris with high-density polyethylene under activated carbon," Energy, Elsevier, vol. 247(C).

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