IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v202y2020ics0360544220307519.html
   My bibliography  Save this article

Raman spectroscopy of biochar from the pyrolysis of three typical Chinese biomasses: A novel method for rapidly evaluating the biochar property

Author

Listed:
  • Xu, Jun
  • Liu, Jiawei
  • Ling, Peng
  • Zhang, Xin
  • Xu, Kai
  • He, Limo
  • Wang, Yi
  • Su, Sheng
  • Hu, Song
  • Xiang, Jun

Abstract

Biochar from the pyrolysis of rice husk, pine wood and rice straw under the temperature from 250 °C to 800 °C were obtained and characterized by Raman spectroscopy. The biochar properties and chemical structure evolution were investigated, and correlations between biochar properties and Raman spectral parameters were set up. The results indicate that pyrolysis temperature has a more significant influence on biochar yield than feedstock. The volatile content in raw biomass linearly decreases with the decrease of biochar yield, and the atom H/C ratio of biochar linearly decreases with the decrease of Vdaf (volatile content in dry ash free basis). The change characteristics of Raman bands position and bandwidth indicate that carbon order degree of biochar progressively increases with the increase of pyrolysis temperature, and detailed chemical structure of biochar from different raw biomass can significantly differ from each other. Reasonable correlations between biochar properties including yield, Vdaf, the atom H/C ratio and the fluorescence interference degree in Raman spectrum (defined as α) of biochar have been found. A series of functions were proposed for rapid evaluation of biochar properties. Specially, the correlation that H/C = 0.3652 + 2.2887∗α-2.4035∗α^2 + 0.8221∗α^3 can be universal for carbon-based fuels including biochar, coals, coal chars and bio-oil chars.

Suggested Citation

  • Xu, Jun & Liu, Jiawei & Ling, Peng & Zhang, Xin & Xu, Kai & He, Limo & Wang, Yi & Su, Sheng & Hu, Song & Xiang, Jun, 2020. "Raman spectroscopy of biochar from the pyrolysis of three typical Chinese biomasses: A novel method for rapidly evaluating the biochar property," Energy, Elsevier, vol. 202(C).
    • Handle: RePEc:eee:energy:v:202:y:2020:i:c:s0360544220307519
    DOI: 10.1016/j.energy.2020.117644
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544220307519
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2020.117644?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Park, Sang-Woo & Jang, Cheol-Hyeon, 2012. "Effects of pyrolysis temperature on changes in fuel characteristics of biomass char," Energy, Elsevier, vol. 39(1), pages 187-195.
    2. Bai, Yonghui & Wang, Yulong & Zhu, Shenghua & Li, Fan & Xie, Kechang, 2014. "Structural features and gasification reactivity of coal chars formed in Ar and CO2 atmospheres at elevated pressures," Energy, Elsevier, vol. 74(C), pages 464-470.
    3. Paul E. Brockway & Anne Owen & Lina I. Brand-Correa & Lukas Hardt, 2019. "Estimation of global final-stage energy-return-on-investment for fossil fuels with comparison to renewable energy sources," Nature Energy, Nature, vol. 4(7), pages 612-621, July.
    4. Wang, Guangwei & Zhang, Jianliang & Chang, Weiwei & Li, Rongpeng & Li, Yanjiang & Wang, Chuan, 2018. "Structural features and gasification reactivity of biomass chars pyrolyzed in different atmospheres at high temperature," Energy, Elsevier, vol. 147(C), pages 25-35.
    5. Zhu, Mingming & Zhang, Zhezi & Zhang, Yang & Liu, Pengfei & Zhang, Dongke, 2017. "An experimental investigation into the ignition and combustion characteristics of single droplets of biochar water slurry fuels in air," Applied Energy, Elsevier, vol. 185(P2), pages 2160-2167.
    6. Wang, Zhuozhi & Sun, Rui & Zhao, Yaying & Li, Yupeng & Ren, Xiaohan, 2019. "Effect of steam concentration on demineralized coal char surface behaviors and structural characteristics during the oxy-steam combustion process," Energy, Elsevier, vol. 174(C), pages 339-349.
    7. Xiong, Zhe & Syed-Hassan, Syed Shatir A. & Hu, Xun & Guo, Junhao & Qiu, Jihua & Zhao, Xingyu & Su, Sheng & Hu, Song & Wang, Yi & Xiang, Jun, 2019. "Pyrolysis of the aromatic-poor and aromatic-rich fractions of bio-oil: Characterization of coke structure and elucidation of coke formation mechanism," Applied Energy, Elsevier, vol. 239(C), pages 981-990.
    8. Gao, Cuixia & Su, Bin & Sun, Mei & Zhang, Xiaoling & Zhang, Zhonghua, 2018. "Interprovincial transfer of embodied primary energy in China: A complex network approach," Applied Energy, Elsevier, vol. 215(C), pages 792-807.
    9. Park, Sang-Woo & Jang, Cheol-Hyeon & Baek, Kyung-Ryul & Yang, Jae-Kyung, 2012. "Torrefaction and low-temperature carbonization of woody biomass: Evaluation of fuel characteristics of the products," Energy, Elsevier, vol. 45(1), pages 676-685.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Lianjie & Tan, Yongdong & Cai, Dongqiang & Sun, Jifu & Zhang, Yue & Li, Longzhi & Zhang, Qiang & Zou, Guifu & Song, Zhanlong & Bai, Yonghui, 2022. "Enhanced pyrolysis of woody biomass under interaction of microwave and needle-shape metal and its production properties," Energy, Elsevier, vol. 249(C).
    2. Qin, Liyuan & Wu, Yang & Jiang, Enchen, 2022. "In situ template preparation of porous carbon materials that are derived from swine manure and have ordered hierarchical nanopore structures for energy storage," Energy, Elsevier, vol. 242(C).
    3. Yousef, Samy & Eimontas, Justas & Striūgas, Nerijus & Abdelnaby, Mohammed Ali, 2022. "Gasification kinetics of char derived from metallised food packaging plastics waste pyrolysis," Energy, Elsevier, vol. 239(PB).
    4. Yang, Liu & Guo, Mengyao & Qian, Yiwen & Xu, Deliang & Gholizadeh, Mortaza & Karnowo, & Zhang, Hong & Hu, Xun & Zhang, Shu, 2022. "The effects of interactions between fiberboard-derived volatiles and glucose-derived biochar on N retention and char structure during the decoupled pyrolysis of fiberboard and glucose using a double-b," Renewable Energy, Elsevier, vol. 191(C), pages 134-140.
    5. Zhu, Wenkun & Li, Xiaohui & Sun, Rui & Cao, Zhen & Yuan, Mengfan & Sun, Liutao & Yu, Xin & Wu, Jiangquan, 2022. "Investigation of the CN and C2 emission characteristics and microstructural evolution of coal to char using laser-induced breakdown spectroscopy and Raman spectroscopy," Energy, Elsevier, vol. 240(C).
    6. Jiang, Xu & Xu, Jun & He, Qichen & Wang, Cong & Jiang, Long & Xu, Kai & Wang, Yi & Su, Sheng & Hu, Song & Du, Zhenyi & Xiang, Jun, 2023. "A study of the relationships between coal heterogeneous chemical structure and pyrolysis behaviours: Mechanism and predicting model," Energy, Elsevier, vol. 282(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Batidzirai, B. & Mignot, A.P.R. & Schakel, W.B. & Junginger, H.M. & Faaij, A.P.C., 2013. "Biomass torrefaction technology: Techno-economic status and future prospects," Energy, Elsevier, vol. 62(C), pages 196-214.
    2. Chen, Lichun & Wen, Chang & Wang, Wenyu & Liu, Tianyu & Liu, Enze & Liu, Haowen & Li, Zexin, 2020. "Combustion behaviour of biochars thermally pretreated via torrefaction, slow pyrolysis, or hydrothermal carbonisation and co-fired with pulverised coal," Renewable Energy, Elsevier, vol. 161(C), pages 867-877.
    3. Zhang, Wenda & Sun, Shaozeng & Zhao, Yijun & Zhao, Zujie & Wang, Pengxiang & Feng, Dongdong & Li, Pengfei, 2020. "Effects of total pressure and CO2 partial pressure on the physicochemical properties and reactivity of pressurized coal char produced at rapid heating rate," Energy, Elsevier, vol. 208(C).
    4. Sahu, S.G. & Chakraborty, N. & Sarkar, P., 2014. "Coal–biomass co-combustion: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 575-586.
    5. Melkie Getnet Tadesse & Esubalew Kasaw & Biruk Fentahun & Emil Loghin & Jörn Felix Lübben, 2022. "Banana Peel and Conductive Polymers-Based Flexible Supercapacitors for Energy Harvesting and Storage," Energies, MDPI, vol. 15(7), pages 1-20, March.
    6. Hossain, Mohammad Razib & Singh, Sanjeet & Sharma, Gagan Deep & Apostu, Simona-Andreea & Bansal, Pooja, 2023. "Overcoming the shock of energy depletion for energy policy? Tracing the missing link between energy depletion, renewable energy development and decarbonization in the USA," Energy Policy, Elsevier, vol. 174(C).
    7. Zhu, Bangzhu & Su, Bin & Li, Yingzhu & Ng, Tsan Sheng, 2020. "Embodied energy and intensity in China’s (normal and processing) exports and their driving forces, 2005-2015," Energy Economics, Elsevier, vol. 91(C).
    8. El may, Yassine & Jeguirim, Mejdi & Dorge, Sophie & Trouvé, Gwenaelle & Said, Rachid, 2012. "Study on the thermal behavior of different date palm residues: Characterization and devolatilization kinetics under inert and oxidative atmospheres," Energy, Elsevier, vol. 44(1), pages 702-709.
    9. Zeke Marshall & Paul E. Brockway, 2020. "A Net Energy Analysis of the Global Agriculture, Aquaculture, Fishing and Forestry System," Biophysical Economics and Resource Quality, Springer, vol. 5(2), pages 1-27, June.
    10. Jonathan Dumas & Antoine Dubois & Paolo Thiran & Pierre Jacques & Francesco Contino & Bertrand Cornélusse & Gauthier Limpens, 2022. "The Energy Return on Investment of Whole-Energy Systems: Application to Belgium," Biophysical Economics and Resource Quality, Springer, vol. 7(4), pages 1-34, December.
    11. Tang, Miaohan & Hong, Jingke & Liu, Guiwen & Shen, Geoffrey Qiping, 2019. "Exploring energy flows embodied in China's economy from the regional and sectoral perspectives via combination of multi-regional input–output analysis and a complex network approach," Energy, Elsevier, vol. 170(C), pages 1191-1201.
    12. Qi, Jianhui & Zhao, Jianli & Xu, Yang & Wang, Yongjia & Han, Kuihua, 2018. "Segmented heating carbonization of biomass: Yields, property and estimation of heating value of chars," Energy, Elsevier, vol. 144(C), pages 301-311.
    13. Charles Guay-Boutet, 2023. "Estimating the Disaggregated Standard EROI of Canadian Oil Sands Extracted via Open-pit Mining, 1997–2016," Biophysical Economics and Resource Quality, Springer, vol. 8(1), pages 1-21, March.
    14. Hong, Sanghyun & Kim, Eunsung & Jeong, Saerok, 2023. "Evaluating the sustainability of the hydrogen economy using multi-criteria decision-making analysis in Korea," Renewable Energy, Elsevier, vol. 204(C), pages 485-492.
    15. Zhang, Zihang & Yi, Baojun & Sun, Zhengshuai & Zhang, Qi & Feng, He & Hu, Hongyun & Huang, Xiangguo & Zhao, Chunqing, 2021. "Reaction process and characteristics for coal char gasification under changed CO2/H2O atmosphere in various reaction stages," Energy, Elsevier, vol. 229(C).
    16. Jakub Frankowski & Wojciech Czekała, 2023. "Agricultural Plant Residues as Potential Co-Substrates for Biogas Production," Energies, MDPI, vol. 16(11), pages 1-14, May.
    17. Tran, Khanh-Quang & Luo, Xun & Seisenbaeva, Gulaim & Jirjis, Raida, 2013. "Stump torrefaction for bioenergy application," Applied Energy, Elsevier, vol. 112(C), pages 539-546.
    18. Yousef, Samy & Eimontas, Justas & Striūgas, Nerijus & Abdelnaby, Mohammed Ali, 2022. "Gasification kinetics of char derived from metallised food packaging plastics waste pyrolysis," Energy, Elsevier, vol. 239(PB).
    19. Abd Alla, Sara & Bianco, Vincenzo & Tagliafico, Luca A. & Scarpa, Federico, 2020. "Life-cycle approach to the estimation of energy efficiency measures in the buildings sector," Applied Energy, Elsevier, vol. 264(C).
    20. Mhadi A. Ismael & Morgan R. Heikal & A. Rashid A. Aziz & Cyril Crua & Mohmmed El-Adawy & Zuhaib Nissar & Masri B. Baharom & Ezrann Z. Zainal A. & Firmansyah, 2018. "Investigation of Puffing and Micro-Explosion of Water-in-Diesel Emulsion Spray Using Shadow Imaging," Energies, MDPI, vol. 11(9), pages 1-12, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:202:y:2020:i:c:s0360544220307519. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.