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Hydrothermal liquefaction of waste biomass in stirred reactors: One step forward to the integral valorization of municipal sludge

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  • Prestigiacomo, Claudia
  • Laudicina, Vito Armando
  • Siragusa, Angelo
  • Scialdone, Onofrio
  • Galia, Alessandro

Abstract

Hydrothermal liquefaction (HTL) of municipal sludge (MS) was performed at 350 °C for 30 min (subcritical water) and at 400 °C for 0 min (supercritical water) at fixed kinetic severity (LogR0 = 8.9) in static and stirred batch reactors to study the effect of the flow regime on the energy recovery (ER) of the process and on the quality of the products. With adopted experimental procedures it was possible to reduce to less than 10% the yield of lost organic compounds, termed volatiles (VT), and to collect and quantify a liquid hydrocarbon fraction (HC) separated from the biocrude (BC). The highest value of the HC yield, 25% w/w, was obtained in supercritical conditions. The C content of the solid residues (SR) and the H/C ratios of the BC increased when the stirred reactor was used. Quite interestingly in this research we have found, to the best of our knowledge for the first time, that the cumulative ER of the product phases was significantly higher than 100% thus indicating that HTL of MS can be energetically driven by renewable thermal energy, such as solar heat, offering a storage option for it.

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  • Prestigiacomo, Claudia & Laudicina, Vito Armando & Siragusa, Angelo & Scialdone, Onofrio & Galia, Alessandro, 2020. "Hydrothermal liquefaction of waste biomass in stirred reactors: One step forward to the integral valorization of municipal sludge," Energy, Elsevier, vol. 201(C).
    • Handle: RePEc:eee:energy:v:201:y:2020:i:c:s0360544220307131
    DOI: 10.1016/j.energy.2020.117606
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    1. Pedersen, T.H. & Jensen, C.U. & Sandström, L. & Rosendahl, L.A., 2017. "Full characterization of compounds obtained from fractional distillation and upgrading of a HTL biocrude," Applied Energy, Elsevier, vol. 202(C), pages 408-419.
    2. Goyal, H.B. & Seal, Diptendu & Saxena, R.C., 2008. "Bio-fuels from thermochemical conversion of renewable resources: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 504-517, February.
    3. Zhu, Zhe & Rosendahl, Lasse & Toor, Saqib Sohail & Yu, Donghong & Chen, Guanyi, 2015. "Hydrothermal liquefaction of barley straw to bio-crude oil: Effects of reaction temperature and aqueous phase recirculation," Applied Energy, Elsevier, vol. 137(C), pages 183-192.
    4. Konstantinos Anastasakis & Patrick Biller & René B. Madsen & Marianne Glasius & Ib Johannsen, 2018. "Continuous Hydrothermal Liquefaction of Biomass in a Novel Pilot Plant with Heat Recovery and Hydraulic Oscillation," Energies, MDPI, vol. 11(10), pages 1-23, October.
    5. Couto, Eduardo Aguiar & Pinto, Filomena & Varela, Francisco & Reis, Alberto & Costa, Paula & Calijuri, Maria Lúcia, 2018. "Hydrothermal liquefaction of biomass produced from domestic sewage treatment in high-rate ponds," Renewable Energy, Elsevier, vol. 118(C), pages 644-653.
    6. Huang, Hua-jun & Yuan, Xing-zhong & Zhu, Hui-na & Li, Hui & Liu, Yan & Wang, Xue-li & Zeng, Guang-ming, 2013. "Comparative studies of thermochemical liquefaction characteristics of microalgae, lignocellulosic biomass and sewage sludge," Energy, Elsevier, vol. 56(C), pages 52-60.
    7. Qian, Lili & Wang, Shuzhong & Savage, Phillip E., 2020. "Fast and isothermal hydrothermal liquefaction of sludge at different severities: Reaction products, pathways, and kinetics," Applied Energy, Elsevier, vol. 260(C).
    8. Hardi, Flabianus & Mäkelä, Mikko & Yoshikawa, Kunio, 2017. "Non-catalytic hydrothermal liquefaction of pine sawdust using experimental design: Material balances and products analysis," Applied Energy, Elsevier, vol. 204(C), pages 1026-1034.
    9. Xu, Donghai & Lin, Guike & Liu, Liang & Wang, Yang & Jing, Zefeng & Wang, Shuzhong, 2018. "Comprehensive evaluation on product characteristics of fast hydrothermal liquefaction of sewage sludge at different temperatures," Energy, Elsevier, vol. 159(C), pages 686-695.
    10. Dimitriadis, Athanasios & Bezergianni, Stella, 2017. "Hydrothermal liquefaction of various biomass and waste feedstocks for biocrude production: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 113-125.
    11. Zappa, William & Junginger, Martin & van den Broek, Machteld, 2019. "Is a 100% renewable European power system feasible by 2050?," Applied Energy, Elsevier, vol. 233, pages 1027-1050.
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    1. Alherbawi, Mohammad & Parthasarathy, Prakash & Al-Ansari, Tareq & Mackey, Hamish R. & McKay, Gordon, 2021. "Potential of drop-in biofuel production from camel manure by hydrothermal liquefaction and biocrude upgrading: A Qatar case study," Energy, Elsevier, vol. 232(C).
    2. Prestigiacomo, Claudia & Proietto, Federica & Laudicina, Vito Armando & Siragusa, Angelo & Scialdone, Onofrio & Galia, Alessandro, 2021. "Catalytic hydrothermal liquefaction of municipal sludge assisted by formic acid for the production of next-generation fuels," Energy, Elsevier, vol. 232(C).

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