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Syngas production by chemical looping gasification using Fe supported on phosphogypsum compound oxygen carrier

Author

Listed:
  • Yang, Jie
  • Wei, Yi
  • Yang, Jing
  • Xiang, Huaping
  • Ma, Liping
  • Zhang, Wei
  • Wang, Lichun
  • Peng, Yuhui
  • Liu, Hongpan

Abstract

Chemical looping gasification (CLG), which is a method for syngas production. The materials for the syngas are low-quality lignite and the industrial waste-phosphogypsum (PG). However, the reaction temperature for the process is high, which consumes a lot of energy. Therefore, in this work, a catalyst has been proposed to lower the reaction temperature in the CLG of syngas. Ellingham diagram has been used as a guide to find the catalyst. Furthermore, theoretical calculations using the thermodynamic software FactSage, have been conducted along with experiments to analyze the performance of compound oxygen carrier in the CLG process. After the analysis, it is suggested that the Fe supported PG has great characteristics with high oxygen carrying capacity, high selective conversion ability of C to CO, excellent activity and recyclability. In addition, compared with the PG applied used as oxygen carrier, the compound oxygen carrier has reduced the temperature to 1023 K with more than 90.00% carbon conversion, whereas more than 70.00% of carbon of lignite is transformed into CO. Additionally, the syngas has the cold gas efficiency of 81.38% and the lower heating value (LHV) 3222.52 kJ/Nm3. And, Fe promotes carbon conversion and syngas production mainly through the reactions: and .

Suggested Citation

  • Yang, Jie & Wei, Yi & Yang, Jing & Xiang, Huaping & Ma, Liping & Zhang, Wei & Wang, Lichun & Peng, Yuhui & Liu, Hongpan, 2019. "Syngas production by chemical looping gasification using Fe supported on phosphogypsum compound oxygen carrier," Energy, Elsevier, vol. 168(C), pages 126-135.
    • Handle: RePEc:eee:energy:v:168:y:2019:i:c:p:126-135
    DOI: 10.1016/j.energy.2018.11.106
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    1. Yang, Jie & Ma, Liping & Yang, Jing & Liu, Hongpan & Liu, Shengyu & Yang, Yingchun & Mu, Liusen & Wei, Yi & Ao, Ran & Guo, Zhiying & Dai, Quxiu & Wang, Huiming, 2019. "Thermodynamic and kinetic analysis of CuO-CaSO4 oxygen carrier in chemical looping gasification," Energy, Elsevier, vol. 188(C).
    2. Pan, Qinghuan & Ma, Liping & Du, Wang & Yang, Jie & Ao, Ran & Yin, Xia & Qing, Sancheng, 2022. "Hydrogen-enriched syngas production by lignite chemical looping gasification with composite oxygen carriers of phosphogypsum and steel slag," Energy, Elsevier, vol. 241(C).
    3. Shah, Vedant & Cheng, Zhuo & Baser, Deven S. & Fan, Jonathan A. & Fan, Liang-Shih, 2021. "Highly Selective Production of Syngas from Chemical Looping Reforming of Methane with CO2 Utilization on MgO-supported Calcium Ferrite Redox Materials," Applied Energy, Elsevier, vol. 282(PA).
    4. Yang, Jie & Dong, Senlin & Xie, Longgui & Cen, Qihong & Zheng, Dalong & Ma, Liping & Dai, Quxiu, 2023. "Analysis of hydrogen-rich syngas generation in chemical looping gasification of lignite: Application of carbide slag as the oxygen carrier, hydrogen carrier, and in-situ carbon capture agent," Energy, Elsevier, vol. 283(C).
    5. Du, Wang & Ma, Liping & Pan, Qinghuan & Dai, Quxiu & Zhang, Mi & Yin, Xia & Xiong, Xiong & Zhang, Wei, 2023. "Full-loop CFD simulation of lignite Chemical Looping Gasification with phosphogypsum as oxygen carrier using a circulating fluidized bed," Energy, Elsevier, vol. 262(PA).
    6. Li, Fenghai & Zhao, Wei & Li, Junguo & Fan, Hongli & Xu, Meiling & Han, Guopeng & Guo, Mingxi & Wang, Zhiqing & Huang, Jiejie & Fang, Yitian, 2023. "Investigation on influencing mechanisms of phosphogypsum (PG) on the ash fusion behaviors of coal," Energy, Elsevier, vol. 268(C).

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