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Influence of torrefaction on the characteristics and pyrolysis behavior of cellulose

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  • Wang, Shurong
  • Dai, Gongxin
  • Ru, Bin
  • Zhao, Yuan
  • Wang, Xiaoliu
  • Xiao, Gang
  • Luo, Zhongyang

Abstract

The influence of torrefaction on cellulose structural characteristics and the resulting pyrolysis behavior was investigated in this study. Torrefaction reduced O/C ratio in cellulose and increased its high heating value. The crystallinity of cellulose increased slightly first and then decreased sharply with the increase of torrefaction temperature, which could be ascribed to competitive degradation between crystalline region and amorphous region, as indicated by 13C CP/MAS NMR analysis. Besides, the cleavage of β-1,4-glycosidic bond and the dehydration of hydroxyl were the major reactions occurring in torrefaction. Avrami-Erofeev model was found to be the most suitable kinetic reaction model for explaining the thermogravimetric weight loss during the pyrolysis of the raw and torrefied cellulose. A distributed activation energy model based on Avrami-Erofeev model was subsequently used to reveal the pyrolytic kinetics. It was found that the changes in cellulose structure influenced the kinetic parameters greatly. Torrefaction also changed pyrolytic product distribution. The yields of furfural, alicyclic ketones and anhydrosugars increased while that of 5-hydroxymethyl-furfural decreased as torrefaction temperature increased.

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  • Wang, Shurong & Dai, Gongxin & Ru, Bin & Zhao, Yuan & Wang, Xiaoliu & Xiao, Gang & Luo, Zhongyang, 2017. "Influence of torrefaction on the characteristics and pyrolysis behavior of cellulose," Energy, Elsevier, vol. 120(C), pages 864-871.
    • Handle: RePEc:eee:energy:v:120:y:2017:i:c:p:864-871
    DOI: 10.1016/j.energy.2016.11.135
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    5. González Martínez, María & Dupont, Capucine & da Silva Perez, Denilson & Mortha, Gérard & Thiéry, Sébastien & Meyer, Xuân-mi & Gourdon, Christophe, 2020. "Understanding the torrefaction of woody and agricultural biomasses through their extracted macromolecular components. Part 1: Experimental thermogravimetric solid mass loss," Energy, Elsevier, vol. 205(C).
    6. Zhang, Li & Yao, Zonglu & Zhao, Lixin & Li, Zhihe & Yi, Weiming & Kang, Kang & Jia, Jixiu, 2021. "Synthesis and characterization of different activated biochar catalysts for removal of biomass pyrolysis tar," Energy, Elsevier, vol. 232(C).
    7. Huang, Shengxiong & Lei, Can & Qin, Jie & Yi, Cheng & Chen, Tao & Yao, Lingling & Li, Bo & Wen, Yujiao & Zhou, Zhi & Xia, Mao, 2022. "Properties, kinetics and pyrolysis products distribution of oxidative torrefied camellia shell in different oxygen concentration," Energy, Elsevier, vol. 251(C).
    8. Chai, Meiyun & Xie, Li & Yu, Xi & Zhang, Xingguang & Yang, Yang & Rahman, Md. Maksudur & Blanco, Paula H. & Liu, Ronghou & Bridgwater, Anthony V. & Cai, Junmeng, 2021. "Poplar wood torrefaction: Kinetics, thermochemistry and implications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    9. Margareta Novian Cahyanti & Tharaka Rama Krishna C. Doddapaneni & Marten Madissoo & Linnar Pärn & Indrek Virro & Timo Kikas, 2021. "Torrefaction of Agricultural and Wood Waste: Comparative Analysis of Selected Fuel Characteristics," Energies, MDPI, vol. 14(10), pages 1-19, May.
    10. Chen, Dengyu & Cen, Kehui & Cao, Xiaobing & Chen, Fan & Zhang, Jie & Zhou, Jianbin, 2021. "Insight into a new phenolic-leaching pretreatment on bamboo pyrolysis: Release characteristics of pyrolytic volatiles, upgradation of three phase products, migration of elements, and energy yield," Renewable and Sustainable Energy Reviews, Elsevier, vol. 136(C).
    11. Singh, Rishikesh Kumar & Chakraborty, Jyoti Prasad & Sarkar, Arnab, 2020. "Optimizing the torrefaction of pigeon pea stalk (cajanus cajan) using response surface methodology (RSM) and characterization of solid, liquid and gaseous products," Renewable Energy, Elsevier, vol. 155(C), pages 677-690.
    12. Riaz, Sajid & Oluwoye, Ibukun & Al-Abdeli, Yasir M., 2022. "Oxidative torrefaction of densified woody biomass: Performance, combustion kinetics and thermodynamics," Renewable Energy, Elsevier, vol. 199(C), pages 908-918.
    13. Chen, Dongyu & Gao, Dongxiao & Capareda, Sergio C. & E, Shuang & Jia, Fengrui & Wang, Ying, 2020. "Influences of hydrochloric acid washing on the thermal decomposition behavior and thermodynamic parameters of sweet sorghum stalk," Renewable Energy, Elsevier, vol. 148(C), pages 1244-1255.
    14. Guo, Feiqiang & Li, Xiaolei & Wang, Yan & Liu, Yuan & Li, Tiantao & Guo, Chenglong, 2017. "Characterization of Zhundong lignite and biomass co-pyrolysis in a thermogravimetric analyzer and a fixed bed reactor," Energy, Elsevier, vol. 141(C), pages 2154-2163.
    15. Tang, Shouhang & Zhou, Sicheng & Li, Ge & Xin, Shanzhi & Huang, Fang & Liu, Xiaoye & Huang, Kai & Zeng, Lixi & Mi, Tie, 2023. "Combination of torrefaction and catalytic fast pyrolysis for aromatic hydrocarbon production from herbaceous medicine waste," Energy, Elsevier, vol. 270(C).
    16. Su, Yinhai & Zhang, Shuping & Liu, Lingqin & Xu, Dan & Qi, Penggang & Xiong, Yuanquan, 2020. "Combination of acid washing and torrefaction on Co-production of syngas and phenoli-riched bio-oil via low-temperature catalytic pyrolysis," Energy, Elsevier, vol. 210(C).
    17. Łukasz Sobol & Jacek Łyczko & Arkadiusz Dyjakon & Ryszard Sroczyński, 2023. "Relationship between Odor Adsorption Ability and Physical–Hydraulic Properties of Torrefied Biomass: Initial Study," Energies, MDPI, vol. 16(4), pages 1-18, February.
    18. Fan, Yuyang & Li, Luwei & Tippayawong, Nakorn & Xia, Shengpeng & Cao, Fengzhu & Yang, Xingwei & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2019. "Quantitative structure-reactivity relationships for pyrolysis and gasification of torrefied xylan," Energy, Elsevier, vol. 188(C).
    19. Arkadiusz Dyjakon & Tomasz Noszczyk & Łukasz Sobol & Dominika Misiakiewicz, 2021. "Influence of Torrefaction Temperature and Climatic Chamber Operation Time on Hydrophobic Properties of Agri-Food Biomass Investigated Using the EMC Method," Energies, MDPI, vol. 14(17), pages 1-19, August.
    20. Dai, Leilei & Wang, Yunpu & Liu, Yuhuan & Ruan, Roger & He, Chao & Yu, Zhenting & Jiang, Lin & Zeng, Zihong & Tian, Xiaojie, 2019. "Integrated process of lignocellulosic biomass torrefaction and pyrolysis for upgrading bio-oil production: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 20-36.
    21. Gu, Tianbao & Fu, Zhufu & Berning, Torsten & Li, Xuantian & Yin, Chungen, 2021. "A simplified kinetic model based on a universal description for solid fuels pyrolysis: Theoretical derivation, experimental validation, and application demonstration," Energy, Elsevier, vol. 225(C).
    22. Xin, Shanzhi & Huang, Fang & Qi, Wei & Mi, Tie, 2020. "Pyrolysis of torrefied herbal medicine wastes: Characterization of pyrolytic products," Energy, Elsevier, vol. 210(C).
    23. Arkadiusz Dyjakon & Tomasz Noszczyk & Martyna Smędzik, 2019. "The Influence of Torrefaction Temperature on Hydrophobic Properties of Waste Biomass from Food Processing," Energies, MDPI, vol. 12(24), pages 1-17, December.
    24. Xin, Shanzhi & Mi, Tie & Liu, Xiaoye & Huang, Fang, 2018. "Effect of torrefaction on the pyrolysis characteristics of high moisture herbaceous residues," Energy, Elsevier, vol. 152(C), pages 586-593.
    25. Tharaka Rama Krishna C. Doddapaneni & Timo Kikas, 2023. "Advanced Applications of Torrefied Biomass: A Perspective View," Energies, MDPI, vol. 16(4), pages 1-8, February.

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