IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v188y2017icp521-528.html
   My bibliography  Save this article

Investigations on the thermal stability, long-term reliability of LiNO3/KCl – expanded graphite composite as industrial waste heat storage material and its corrosion properties with metals

Author

Listed:
  • Huang, Zhaowen
  • Luo, Zigeng
  • Gao, Xuenong
  • Fang, Xiaoming
  • Fang, Yutang
  • Zhang, Zhengguo

Abstract

The aim of this work was to investigate the properties of LiNO3/KCl-expanded graphite (EG) composite phase change material (PCM) concerning its long-term usage for industrial waste heat storage. Studies on the thermal stability and long-term reliability of this composite PCM as well as its compatibility with metals that commonly used in industries were conducted. By means of thermogravimetric analyzer (TGA) and differential scanning calorimeter (DSC), the initial thermal decomposition temperature of the composite PCM was found to be 315°C, and less than 1% and around 4% changes in phase change temperature and phase change latent heat, respectively, were obtained after repeated melting/solidification cycles. Gravimetric analysis of different metal specimens after enduring 500 thermal cycles in contact with the composite PCM revealed that stainless steel 304L and carbon steel C20 could be considered as more suitable containment materials than brass H68 for long-term use. The results of this work not only confirmed the great potential of LiNO3/KCl-EG composite PCM to be used as industrial waste heat storage medium, but also could facilitate experimental and numerical researches on the LiNO3/KCl-EG composite PCM-assisted latent heat storage systems in future.

Suggested Citation

  • Huang, Zhaowen & Luo, Zigeng & Gao, Xuenong & Fang, Xiaoming & Fang, Yutang & Zhang, Zhengguo, 2017. "Investigations on the thermal stability, long-term reliability of LiNO3/KCl – expanded graphite composite as industrial waste heat storage material and its corrosion properties with metals," Applied Energy, Elsevier, vol. 188(C), pages 521-528.
    • Handle: RePEc:eee:appene:v:188:y:2017:i:c:p:521-528
    DOI: 10.1016/j.apenergy.2016.12.010
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916317743
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.12.010?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Huang, Zhaowen & Gao, Xuenong & Xu, Tao & Fang, Yutang & Zhang, Zhengguo, 2014. "Thermal property measurement and heat storage analysis of LiNO3/KCl – expanded graphite composite phase change material," Applied Energy, Elsevier, vol. 115(C), pages 265-271.
    2. Pereira da Cunha, Jose & Eames, Philip, 2016. "Thermal energy storage for low and medium temperature applications using phase change materials – A review," Applied Energy, Elsevier, vol. 177(C), pages 227-238.
    3. Merlin, Kevin & Soto, Jérôme & Delaunay, Didier & Traonvouez, Luc, 2016. "Industrial waste heat recovery using an enhanced conductivity latent heat thermal energy storage," Applied Energy, Elsevier, vol. 183(C), pages 491-503.
    4. Wang, Tao & Mantha, Divakar & Reddy, Ramana G., 2013. "Novel low melting point quaternary eutectic system for solar thermal energy storage," Applied Energy, Elsevier, vol. 102(C), pages 1422-1429.
    5. Peng, Qiang & Ding, Jing & Wei, Xiaolan & Yang, Jianping & Yang, Xiaoxi, 2010. "The preparation and properties of multi-component molten salts," Applied Energy, Elsevier, vol. 87(9), pages 2812-2817, September.
    6. Miró, Laia & Gasia, Jaume & Cabeza, Luisa F., 2016. "Thermal energy storage (TES) for industrial waste heat (IWH) recovery: A review," Applied Energy, Elsevier, vol. 179(C), pages 284-301.
    7. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Du, Lichan & Ding, Jing & Tian, Heqing & Wang, Weilong & Wei, Xiaolan & Song, Ming, 2017. "Thermal properties and thermal stability of the ternary eutectic salt NaCl-CaCl2-MgCl2 used in high-temperature thermal energy storage process," Applied Energy, Elsevier, vol. 204(C), pages 1225-1230.
    2. Yu, Qinghua & Jiang, Zhu & Cong, Lin & Lu, Tiejun & Suleiman, Bilyaminu & Leng, Guanghui & Wu, Zhentao & Ding, Yulong & Li, Yongliang, 2019. "A novel low-temperature fabrication approach of composite phase change materials for high temperature thermal energy storage," Applied Energy, Elsevier, vol. 237(C), pages 367-377.
    3. Zhao, Y. & Zhao, C.Y. & Markides, C.N. & Wang, H. & Li, W., 2020. "Medium- and high-temperature latent and thermochemical heat storage using metals and metallic compounds as heat storage media: A technical review," Applied Energy, Elsevier, vol. 280(C).
    4. Zhang, Suling & Wu, Wei & Wang, Shuangfeng, 2018. "Experimental investigations of Alum/expanded graphite composite phase change material for thermal energy storage and its compatibility with metals," Energy, Elsevier, vol. 161(C), pages 508-516.
    5. Wei, Xiaolan & Qin, Bo & Yang, Chuntao & Wang, Weilong & Ding, Jing & Wang, Yan & Peng, Qiang, 2019. "Nox emission of ternary nitrate molten salts in high-temperature heat storage and transfer process," Applied Energy, Elsevier, vol. 236(C), pages 147-154.
    6. Jiang, Feng & Zhang, Lingling & She, Xiaohui & Li, Chuan & Cang, Daqiang & Liu, Xianglei & Xuan, Yimin & Ding, Yulong, 2020. "Skeleton materials for shape-stabilization of high temperature salts based phase change materials: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    7. Luu, Minh Tri & Milani, Dia & Nomvar, Mobin & Abbas, Ali, 2020. "A design protocol for enhanced discharge exergy in phase change material heat battery," Applied Energy, Elsevier, vol. 265(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sardari, Pouyan Talebizadeh & Mohammed, Hayder I. & Giddings, Donald & walker, Gavin S. & Gillott, Mark & Grant, David, 2019. "Numerical study of a multiple-segment metal foam-PCM latent heat storage unit: Effect of porosity, pore density and location of heat source," Energy, Elsevier, vol. 189(C).
    2. Ding, Zhixiong & Wu, Wei & Leung, Michael, 2021. "Advanced/hybrid thermal energy storage technology: material, cycle, system and perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    3. Jiang, Feng & Zhang, Lingling & She, Xiaohui & Li, Chuan & Cang, Daqiang & Liu, Xianglei & Xuan, Yimin & Ding, Yulong, 2020. "Skeleton materials for shape-stabilization of high temperature salts based phase change materials: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    4. Li, Zhi & Lu, Yiji & Huang, Rui & Chang, Jinwei & Yu, Xiaonan & Jiang, Ruicheng & Yu, Xiaoli & Roskilly, Anthony Paul, 2021. "Applications and technological challenges for heat recovery, storage and utilisation with latent thermal energy storage," Applied Energy, Elsevier, vol. 283(C).
    5. Du, Lichan & Ding, Jing & Tian, Heqing & Wang, Weilong & Wei, Xiaolan & Song, Ming, 2017. "Thermal properties and thermal stability of the ternary eutectic salt NaCl-CaCl2-MgCl2 used in high-temperature thermal energy storage process," Applied Energy, Elsevier, vol. 204(C), pages 1225-1230.
    6. Lin, Yaxue & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal performances and applications of thermal energy storage systems with inorganic phase change materials," Energy, Elsevier, vol. 165(PA), pages 685-708.
    7. Zauner, Christoph & Hengstberger, Florian & Mörzinger, Benjamin & Hofmann, Rene & Walter, Heimo, 2017. "Experimental characterization and simulation of a hybrid sensible-latent heat storage," Applied Energy, Elsevier, vol. 189(C), pages 506-519.
    8. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    9. Khan, Zakir & Khan, Zulfiqar Ahmad, 2017. "Experimental investigations of charging/melting cycles of paraffin in a novel shell and tube with longitudinal fins based heat storage design solution for domestic and industrial applications," Applied Energy, Elsevier, vol. 206(C), pages 1158-1168.
    10. Tian, Heqing & Du, Lichan & Wei, Xiaolan & Deng, Suyan & Wang, Weilong & Ding, Jing, 2017. "Enhanced thermal conductivity of ternary carbonate salt phase change material with Mg particles for solar thermal energy storage," Applied Energy, Elsevier, vol. 204(C), pages 525-530.
    11. Du, Kun & Calautit, John & Eames, Philip & Wu, Yupeng, 2021. "A state-of-the-art review of the application of phase change materials (PCM) in Mobilized-Thermal Energy Storage (M-TES) for recovering low-temperature industrial waste heat (IWH) for distributed heat," Renewable Energy, Elsevier, vol. 168(C), pages 1040-1057.
    12. Lukas Hegner & Stefan Krimmel & Rebecca Ravotti & Dominic Festini & Jörg Worlitschek & Anastasia Stamatiou, 2021. "Experimental Feasibility Study of a Direct Contact Latent Heat Storage Using an Ester as a Bio-Based Storage Material," Energies, MDPI, vol. 14(2), pages 1-26, January.
    13. Mohammad, Mehedi Bin & Brooks, Geoffrey Alan & Rhamdhani, M. Akbar, 2017. "Thermal analysis of molten ternary lithium-sodium-potassium nitrates," Renewable Energy, Elsevier, vol. 104(C), pages 76-87.
    14. Xu, Yang & Ren, Qinlong & Zheng, Zhang-Jing & He, Ya-Ling, 2017. "Evaluation and optimization of melting performance for a latent heat thermal energy storage unit partially filled with porous media," Applied Energy, Elsevier, vol. 193(C), pages 84-95.
    15. Hu, Nan & Li, Zi-Rui & Xu, Zhe-Wen & Fan, Li-Wu, 2022. "Rapid charging for latent heat thermal energy storage: A state-of-the-art review of close-contact melting," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    16. Tao, Y.B. & He, Ya-Ling, 2018. "A review of phase change material and performance enhancement method for latent heat storage system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 93(C), pages 245-259.
    17. Englmair, Gerald & Moser, Christoph & Furbo, Simon & Dannemand, Mark & Fan, Jianhua, 2018. "Design and functionality of a segmented heat-storage prototype utilizing stable supercooling of sodium acetate trihydrate in a solar heating system," Applied Energy, Elsevier, vol. 221(C), pages 522-534.
    18. Yu, Xiaoli & Li, Zhi & Lu, Yiji & Huang, Rui & Roskilly, Anthony Paul, 2019. "Investigation of organic Rankine cycle integrated with double latent thermal energy storage for engine waste heat recovery," Energy, Elsevier, vol. 170(C), pages 1098-1112.
    19. Yuan, Yanping & Zhang, Nan & Li, Tianyu & Cao, Xiaoling & Long, Weiyue, 2016. "Thermal performance enhancement of palmitic-stearic acid by adding graphene nanoplatelets and expanded graphite for thermal energy storage: A comparative study," Energy, Elsevier, vol. 97(C), pages 488-497.
    20. Giovanni Salvatore Sau & Valerio Tripi & Anna Chiara Tizzoni & Raffaele Liberatore & Emiliana Mansi & Annarita Spadoni & Natale Corsaro & Mauro Capocelli & Tiziano Delise & Anna Della Libera, 2021. "High-Temperature Chloride-Carbonate Phase Change Material: Thermal Performances and Modelling of a Packed Bed Storage System for Concentrating Solar Power Plants," Energies, MDPI, vol. 14(17), pages 1-17, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:188:y:2017:i:c:p:521-528. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.