IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v112y2013icp52-59.html
   My bibliography  Save this article

Hydrogen production and purification from the water–gas shift reaction on CuO/CeO2–TiO2 catalysts

Author

Listed:
  • Maciel, Cristhiane Guimarães
  • Silva, Tatiana de Freitas
  • Assaf, Elisabete Moreira
  • Assaf, José Mansur

Abstract

The present study evaluates the use of copper catalysts supported on ceria and/or titania for water–gas shift reaction (WGSR). The effect of metal-support interaction coupled with structural properties such as surface area and oxidation state favor the conversion of CO to CO2 and the hydrogen formation. The strong copper–ceria interaction promotes the good performance of the CuCe system, while the poor interaction between titania and copper disadvantaged the performance of the CuTi catalyst. However, the addition of ceria into the titania support hampers the transformation of anatase to rutile phase, facilitates the reduction of metal species and favors the metal-support interaction. The combined results of these features are a better performance for CuCeTi catalyst compared to the system only containing ceria or titania. The catalytic evaluation has revealed that both CuCeTi and CuCe catalysts produce significant amounts of H2 during the WGSR process and favor a H2/CO ratio close to 2. The use of these catalysts for WGSR, especially at high temperature (HT-WGSR), showed good performance, fulfilling the goal of CO in reducing levels for hydrogen fuel cell applications.

Suggested Citation

  • Maciel, Cristhiane Guimarães & Silva, Tatiana de Freitas & Assaf, Elisabete Moreira & Assaf, José Mansur, 2013. "Hydrogen production and purification from the water–gas shift reaction on CuO/CeO2–TiO2 catalysts," Applied Energy, Elsevier, vol. 112(C), pages 52-59.
    • Handle: RePEc:eee:appene:v:112:y:2013:i:c:p:52-59
    DOI: 10.1016/j.apenergy.2013.06.003
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261913005102
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2013.06.003?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wang, Xiaoyue & Li, Haibo & Liu, Yong & Zhao, Wenxia & Liang, Chaolun & Huang, Hong & Mo, Delin & Liu, Zhong & Yu, Xiao & Deng, Youjun & Shen, Hui, 2012. "Hydrothermal synthesis of well-aligned hierarchical TiO2 tubular macrochannel arrays with large surface area for high performance dye-sensitized solar cells," Applied Energy, Elsevier, vol. 99(C), pages 198-205.
    2. Khobragade, Murnal & Majhi, Sachchit & Pant, K.K., 2012. "Effect of K and CeO2 promoters on the activity of Co/SiO2 catalyst for liquid fuel production from syngas," Applied Energy, Elsevier, vol. 94(C), pages 385-394.
    3. Guo, Yong & Azmat, Muhammad Usman & Liu, Xiaohui & Wang, Yanqin & Lu, Guanzhong, 2012. "Effect of support’s basic properties on hydrogen production in aqueous-phase reforming of glycerol and correlation between WGS and APR," Applied Energy, Elsevier, vol. 92(C), pages 218-223.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chen, Wei-Hsin & Chen, Chia-Yang, 2020. "Water gas shift reaction for hydrogen production and carbon dioxide capture: A review," Applied Energy, Elsevier, vol. 258(C).
    2. Renda, Simona & Ricca, Antonio & Palma, Vincenzo, 2020. "Precursor salts influence in Ruthenium catalysts for CO2 hydrogenation to methane," Applied Energy, Elsevier, vol. 279(C).
    3. Wang, Shuofeng & Ji, Changwei & Zhang, Bo & Liu, Xiaolong, 2014. "Lean burn performance of a hydrogen-blended gasoline engine at the wide open throttle condition," Applied Energy, Elsevier, vol. 136(C), pages 43-50.
    4. Gradisher, Logan & Dutcher, Bryce & Fan, Maohong, 2015. "Catalytic hydrogen production from fossil fuels via the water gas shift reaction," Applied Energy, Elsevier, vol. 139(C), pages 335-349.
    5. Lee, Chan Hyun & Lee, Ki Bong, 2017. "Sorption-enhanced water gas shift reaction for high-purity hydrogen production: Application of a Na-Mg double salt-based sorbent and the divided section packing concept," Applied Energy, Elsevier, vol. 205(C), pages 316-322.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Bin & Wang, Shifeng & Tang, Yuanyuan & Tsang, Chi-Wing & Dai, Jinchuan & Leung, Michael K.H. & Lu, Xiao-Ying, 2019. "Micro/nanostructured MnCo2O4.5 anodes with high reversible capacity and excellent rate capability for next generation lithium-ion batteries," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    2. Li, Chunlin & Xu, Hengyong & Hou, Shoufu & Sun, Jian & Meng, Fanqiong & Ma, Junguo & Tsubaki, Noritatsu, 2013. "SiC foam monolith catalyst for pressurized adiabatic methane reforming," Applied Energy, Elsevier, vol. 107(C), pages 297-303.
    3. Ding, Mingyue & Tu, Junling & Qiu, Minghuang & Wang, Tiejun & Ma, Longlong & Li, Yuping, 2015. "Impact of potassium promoter on Cu–Fe based mixed alcohols synthesis catalyst," Applied Energy, Elsevier, vol. 138(C), pages 584-589.
    4. Lee, Hyo Mun & Yoon, Jong Ho, 2018. "Power performance analysis of a transparent DSSC BIPV window based on 2 year measurement data in a full-scale mock-up," Applied Energy, Elsevier, vol. 225(C), pages 1013-1021.
    5. Su, Shanhe & Liu, Tie & Wang, Yuan & Chen, Xiaohang & Wang, Jintong & Chen, Jincan, 2014. "Performance optimization analyses and parametric design criteria of a dye-sensitized solar cell thermoelectric hybrid device," Applied Energy, Elsevier, vol. 120(C), pages 16-22.
    6. Fantozzi, F. & Frassoldati, A. & Bartocci, P. & Cinti, G. & Quagliarini, F. & Bidini, G. & Ranzi, E.M., 2016. "An experimental and kinetic modeling study of glycerol pyrolysis," Applied Energy, Elsevier, vol. 184(C), pages 68-76.
    7. Wang, Zhen & Wang, Yiping & Vivar, Marta & Fuentes, Manuel & Zhu, Li & Qin, Lianwei, 2014. "Photovoltaic and photocatalytic performance study of SOLWAT system for the degradation of Methylene Blue, Acid Red 26 and 4-Chlorophenol," Applied Energy, Elsevier, vol. 120(C), pages 1-10.
    8. Rahimpour, Mohammad Reza & Jafari, Mitra & Iranshahi, Davood, 2013. "Progress in catalytic naphtha reforming process: A review," Applied Energy, Elsevier, vol. 109(C), pages 79-93.
    9. Mohammed Al-asadi & Norbert Miskolczi, 2020. "High Temperature Pyrolysis of Municipal Plastic Waste Using Me/Ni/ZSM-5 Catalysts: The Effect of Metal/Nickel Ratio," Energies, MDPI, vol. 13(5), pages 1-11, March.
    10. Seretis, A. & Tsiakaras, P., 2016. "Aqueous phase reforming (APR) of glycerol over platinum supported on Al2O3 catalyst," Renewable Energy, Elsevier, vol. 85(C), pages 1116-1126.
    11. Long, Yun-Duo & Fang, Zhen & Su, Tong-Chao & Yang, Qing, 2014. "Co-production of biodiesel and hydrogen from rapeseed and Jatropha oils with sodium silicate and Ni catalysts," Applied Energy, Elsevier, vol. 113(C), pages 1819-1825.
    12. Saebea, Dang & Authayanun, Suthida & Patcharavorachot, Yaneeporn & Paengjuntuek, Woranee & Arpornwichanop, Amornchai, 2013. "Use of different renewable fuels in a steam reformer integrated into a solid oxide fuel cell: Theoretical analysis and performance comparison," Energy, Elsevier, vol. 51(C), pages 305-313.
    13. Hug, Hubert & Bader, Michael & Mair, Peter & Glatzel, Thilo, 2014. "Biophotovoltaics: Natural pigments in dye-sensitized solar cells," Applied Energy, Elsevier, vol. 115(C), pages 216-225.
    14. He, Yan-Rong & Yan, Fang-Fang & Yu, Han-Qing & Yuan, Shi-Jie & Tong, Zhong-Hua & Sheng, Guo-Ping, 2014. "Hydrogen production in a light-driven photoelectrochemical cell," Applied Energy, Elsevier, vol. 113(C), pages 164-168.
    15. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Liu, Yongjun & Liu, Hui, 2016. "Characteristics of hydrogen produced by pulsed discharge in ethanol solution," Applied Energy, Elsevier, vol. 168(C), pages 122-129.
    16. Liu, Dashuai & Dou, Binlin & Zhang, Hua & Zhao, Longfei & Wu, Kai & Zeng, Pingchao & Chen, Haisheng & Xu, Yujie, 2022. "Comparison of gelatinous and calcined magnesia supported Ni or/and Co-based catalysts for aqueous phase reforming of glycerol," Renewable Energy, Elsevier, vol. 186(C), pages 656-666.
    17. Das, Satyen Kumar & Mohanty, Pravakar & Majhi, Sachchit & Pant, Kamal Kishore, 2013. "CO-hydrogenation over silica supported iron based catalysts: Influence of potassium loading," Applied Energy, Elsevier, vol. 111(C), pages 267-276.
    18. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Rajaei, Kourosh & Tarighi, Sara, 2018. "Oxidation of bio-renewable glycerol to value-added chemicals through catalytic and electro-chemical processes," Applied Energy, Elsevier, vol. 230(C), pages 1347-1379.
    19. Schwengber, Carine Aline & Alves, Helton José & Schaffner, Rodolfo Andrade & da Silva, Fernando Alves & Sequinel, Rodrigo & Bach, Vanessa Rossato & Ferracin, Ricardo José, 2016. "Overview of glycerol reforming for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 259-266.
    20. Ishaque, Kashif & Salam, Zainal & Lauss, George, 2014. "The performance of perturb and observe and incremental conductance maximum power point tracking method under dynamic weather conditions," Applied Energy, Elsevier, vol. 119(C), pages 228-236.

    More about this item

    Keywords

    WGSR; H2 production; CO purification; Fuel cells;
    All these keywords.

    JEL classification:

    • H2 - Public Economics - - Taxation, Subsidies, and Revenue

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:112:y:2013:i:c:p:52-59. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.