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Technoeconomic assessment of hydrothermal liquefaction oil from lignin with catalytic upgrading for renewable fuel and chemical production

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  • LiLu T. Funkenbusch
  • Michael E. Mullins
  • Lennart Vamling
  • Tallal Belkhieri
  • Nattapol Srettiwat
  • Olumide Winjobi
  • David R. Shonnard
  • Tony N. Rogers

Abstract

Lignin is a readily available by‐product of the Kraft pulping process, and may be processed via hydrothermal liquefaction (HTL) to produce a bio‐oil suitable for cofeeding into a petroleum refinery hydrotreatment unit. HTL of lignin is performed in near‐critical water and, in addition to the bio‐oil, produces an aqueous organic and solid char phase. The aqueous organics are primarily phenolics, which may be converted into valuable coproducts via liquid–liquid extraction and hydrotreatment to benzene, toluene, ethylbenzene, and xylenes (BTEX) compounds. Three technological scenarios were developed: a current technology case, a state‐of‐the‐art research case, and an optimal case based on product targets provided by refiners. For a large Kraft pulp mill (400 metric tons/day of dry lignin), a renewable fuel production of 65–70 million L/year, with capital costs of $114–125 million and a final per liter cost of $0.41–0.44 were estimated. The BTEX coproduct yield ranged from 16.8–18.0 million L/year. An economic analysis of the process revealed that the hydrotreatment steps have the highest installed capital costs, while the liquid–liquid extraction process is the largest operating cost. Based on these results, the minimum selling price (MSP) of the biofuel is between $3.52 and $3.86/gallon, and the MSP of BTEX is between $1.65 and $2.00 per liter. With current technology, coproduction of BTEX does not offset the cost of biofuel production. Improved technology to further lower bio‐oil oxygen content and decrease both capital and operating costs are needed to make HTL‐based fuels competitive with fossil fuel‐based options. This article is categorized under: Energy Research & Innovation > Science and Materials Bioenergy > Economics and Policy Bioenergy > Systems and Infrastructure

Suggested Citation

  • LiLu T. Funkenbusch & Michael E. Mullins & Lennart Vamling & Tallal Belkhieri & Nattapol Srettiwat & Olumide Winjobi & David R. Shonnard & Tony N. Rogers, 2019. "Technoeconomic assessment of hydrothermal liquefaction oil from lignin with catalytic upgrading for renewable fuel and chemical production," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 8(1), January.
  • Handle: RePEc:bla:wireae:v:8:y:2019:i:1:n:e319
    DOI: 10.1002/wene.319
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    References listed on IDEAS

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    1. Azadi, Pooya & Inderwildi, Oliver R. & Farnood, Ramin & King, David A., 2013. "Liquid fuels, hydrogen and chemicals from lignin: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 506-523.
    2. Toor, Saqib Sohail & Rosendahl, Lasse & Rudolf, Andreas, 2011. "Hydrothermal liquefaction of biomass: A review of subcritical water technologies," Energy, Elsevier, vol. 36(5), pages 2328-2342.
    3. Zhu, Yunhua & Biddy, Mary J. & Jones, Susanne B. & Elliott, Douglas C. & Schmidt, Andrew J., 2014. "Techno-economic analysis of liquid fuel production from woody biomass via hydrothermal liquefaction (HTL) and upgrading," Applied Energy, Elsevier, vol. 129(C), pages 384-394.
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    1. Abraham Castro Garcia & Shuo Cheng & Jeffrey S. Cross, 2022. "Lignin Gasification: Current and Future Viability," Energies, MDPI, vol. 15(23), pages 1-17, November.
    2. Jukka Lappalainen & David Baudouin & Ursel Hornung & Julia Schuler & Kristian Melin & Saša Bjelić & Frédéric Vogel & Jukka Konttinen & Tero Joronen, 2020. "Sub- and Supercritical Water Liquefaction of Kraft Lignin and Black Liquor Derived Lignin," Energies, MDPI, vol. 13(13), pages 1-45, June.
    3. Sennai Mesfun & Leonidas Matsakas & Ulrika Rova & Paul Christakopoulos, 2019. "Technoeconomic Assessment of Hybrid Organosolv–Steam Explosion Pretreatment of Woody Biomass," Energies, MDPI, vol. 12(21), pages 1-18, November.
    4. Michał Wojcieszyk & Lotta Knuutila & Yuri Kroyan & Mário de Pinto Balsemão & Rupali Tripathi & Juha Keskivali & Anna Karvo & Annukka Santasalo-Aarnio & Otto Blomstedt & Martti Larmi, 2021. "Performance of Anisole and Isobutanol as Gasoline Bio-Blendstocks for Spark Ignition Engines," Sustainability, MDPI, vol. 13(16), pages 1-19, August.
    5. Cao, Yang & He, Mingjing & Dutta, Shanta & Luo, Gang & Zhang, Shicheng & Tsang, Daniel C.W., 2021. "Hydrothermal carbonization and liquefaction for sustainable production of hydrochar and aromatics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).

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