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Mild Hydrothermal Liquefaction of High Water Content Agricultural Residue for Bio-Crude Oil Production: A Parametric Study

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  • Yongsheng Zhang

    (School of Chemical Engineering and Energy, Zhengzhou University, 100 Science Avenue, Zhengzhou 450001, China
    School of Engineering, University of Guelph, Guelph, ON N1G 2W1, Canada)

  • Jamie Minaret

    (School of Engineering, University of Guelph, Guelph, ON N1G 2W1, Canada)

  • Zhongshun Yuan

    (Institute for Chemicals and Fuels from Alternative Resources (ICFAR), Department of Chemical and Biochemical Engineering, Western University, London, ON N6G 5B9, Canada)

  • Animesh Dutta

    (School of Engineering, University of Guelph, Guelph, ON N1G 2W1, Canada)

  • Chunbao (Charles) Xu

    (Institute for Chemicals and Fuels from Alternative Resources (ICFAR), Department of Chemical and Biochemical Engineering, Western University, London, ON N6G 5B9, Canada)

Abstract

Depleting petroleum reserves together with the associated environmental concerns have intensified the exploration of alternatives to petroleum. Wet food processing wastes present promising bioresources for liquid fuel production via hydrothermal liquefaction (HTL) followed by additional upgrading. In this study, tomato plant waste (TPW) was utilized as a feedstock for the production of bio-crude oils via HTL at medium-temperature (220–280 °C) in water or a water–ethanol (17/3, v / v ) medium in a 600 mL autoclave reactor. Effects of various operating parameters, such as catalysts (H 2 SO 4 or KOH), reaction time (15–60 min) and reaction temperature (220–280 °C) on product yields were investigated. This study showed that a high yield (45.1 wt%) of bio-crude oil was achieved from HTL of TPW in water–ethanol medium at 250 °C in the presence of acid catalyst H 2 SO 4 . The oil, gas and solid residue (SR) products were analyzed for their chemical and structural properties.

Suggested Citation

  • Yongsheng Zhang & Jamie Minaret & Zhongshun Yuan & Animesh Dutta & Chunbao (Charles) Xu, 2018. "Mild Hydrothermal Liquefaction of High Water Content Agricultural Residue for Bio-Crude Oil Production: A Parametric Study," Energies, MDPI, vol. 11(11), pages 1-13, November.
  • Handle: RePEc:gam:jeners:v:11:y:2018:i:11:p:3129-:d:182332
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    References listed on IDEAS

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