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Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities

Author

Listed:
  • Xinhua Zheng

    (University of Science and Technology of China)

  • Zaichun Liu

    (University of Science and Technology of China)

  • Jifei Sun

    (University of Science and Technology of China)

  • Ruihao Luo

    (University of Science and Technology of China)

  • Kui Xu

    (University of Science and Technology of China)

  • Mingyu Si

    (Beijing Institute of Petrochemical Technology)

  • Ju Kang

    (Beijing Institute of Petrochemical Technology)

  • Yuan Yuan

    (University of Science and Technology of China)

  • Shuang Liu

    (University of Science and Technology of China)

  • Touqeer Ahmad

    (University of Science and Technology of China)

  • Taoli Jiang

    (University of Science and Technology of China)

  • Na Chen

    (University of Science and Technology of China)

  • Mingming Wang

    (University of Science and Technology of China)

  • Yan Xu

    (University of Science and Technology of China)

  • Mingyan Chuai

    (University of Science and Technology of China)

  • Zhengxin Zhu

    (University of Science and Technology of China)

  • Qia Peng

    (University of Science and Technology of China)

  • Yahan Meng

    (University of Science and Technology of China)

  • Kai Zhang

    (University of Science and Technology of China)

  • Weiping Wang

    (University of Science and Technology of China)

  • Wei Chen

    (University of Science and Technology of China)

Abstract

The development of Zn-free anodes to inhibit Zn dendrite formation and modulate high-capacity Zn batteries is highly applauded yet very challenging. Here, we design a robust two-dimensional antimony/antimony-zinc alloy heterostructured interface to regulate Zn plating. Benefiting from the stronger adsorption and homogeneous electric field distribution of the Sb/Sb2Zn3-heterostructured interface in Zn plating, the Zn anode enables an ultrahigh areal capacity of 200 mAh cm−2 with an overpotential of 112 mV and a Coulombic efficiency of 98.5%. An anode-free Zn-Br2 battery using the Sb/Sb2Zn3-heterostructured interface@Cu anode shows an attractive energy density of 274 Wh kg−1 with a practical pouch cell energy density of 62 Wh kg−1. The scaled-up Zn-Br2 battery in a capacity of 500 mAh exhibits over 400 stable cycles. Further, the Zn-Br2 battery module in an energy of 9 Wh (6 V, 1.5 Ah) is integrated with a photovoltaic panel to demonstrate the practical renewable energy storage capabilities. Our superior anode-free Zn batteries enabled by the heterostructured interface enlighten an arena towards large-scale energy storage applications.

Suggested Citation

  • Xinhua Zheng & Zaichun Liu & Jifei Sun & Ruihao Luo & Kui Xu & Mingyu Si & Ju Kang & Yuan Yuan & Shuang Liu & Touqeer Ahmad & Taoli Jiang & Na Chen & Mingming Wang & Yan Xu & Mingyan Chuai & Zhengxin , 2023. "Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-022-35630-6
    DOI: 10.1038/s41467-022-35630-6
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    References listed on IDEAS

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    1. Rochelle Weber & Matthew Genovese & A. J. Louli & Samuel Hames & Cameron Martin & Ian G. Hill & J. R. Dahn, 2019. "Long cycle life and dendrite-free lithium morphology in anode-free lithium pouch cells enabled by a dual-salt liquid electrolyte," Nature Energy, Nature, vol. 4(8), pages 683-689, August.
    2. Nyamdash, Batsaikhan & Denny, Eleanor & O'Malley, Mark, 2010. "The viability of balancing wind generation with large scale energy storage," Energy Policy, Elsevier, vol. 38(11), pages 7200-7208, November.
    3. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    4. Ning Zhang & Fangyi Cheng & Junxiang Liu & Liubin Wang & Xinghui Long & Xiaosong Liu & Fujun Li & Jun Chen, 2017. "Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    5. Junmin Ge & Ling Fan & Apparao M. Rao & Jiang Zhou & Bingan Lu, 2022. "Surface-substituted Prussian blue analogue cathode for sustainable potassium-ion batteries," Nature Sustainability, Nature, vol. 5(3), pages 225-234, March.
    6. Kangli Wang & Kai Jiang & Brice Chung & Takanari Ouchi & Paul J. Burke & Dane A. Boysen & David J. Bradwell & Hojong Kim & Ulrich Muecke & Donald R. Sadoway, 2014. "Lithium–antimony–lead liquid metal battery for grid-level energy storage," Nature, Nature, vol. 514(7522), pages 348-350, October.
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    Citations

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    Cited by:

    1. Minghao Zhang & Chenxi Sun & Guanhong Chen & Yuanhong Kang & Zeheng Lv & Jin Yang & Siyang Li & Pengxiang Lin & Rong Tang & Zhipeng Wen & Cheng Chao Li & Jinbao Zhao & Yang Yang, 2024. "Synergetic bifunctional Cu-In alloy interface enables Ah-level Zn metal pouch cells," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    2. Yahan Meng & Mingming Wang & Jiazhi Wang & Xuehai Huang & Xiang Zhou & Muhammad Sajid & Zehui Xie & Ruihao Luo & Zhengxin Zhu & Zuodong Zhang & Nawab Ali Khan & Yu Wang & Zhenyu Li & Wei Chen, 2024. "Robust bilayer solid electrolyte interphase for Zn electrode with high utilization and efficiency," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    3. Yunxiang Zhao & Shan Guo & Manjing Chen & Bingan Lu & Xiaotan Zhang & Shuquan Liang & Jiang Zhou, 2023. "Tailoring grain boundary stability of zinc-titanium alloy for long-lasting aqueous zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    4. Zhijing Yu & Wei Wang & Yong Zhu & Wei-Li Song & Zheng Huang & Zhe Wang & Shuqiang Jiao, 2023. "Construction of double reaction zones for long-life quasi-solid aluminum-ion batteries by realizing maximum electron transfer," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Xiaotan Zhang & Jiangxu Li & Yanfen Liu & Bingan Lu & Shuquan Liang & Jiang Zhou, 2024. "Single [0001]-oriented zinc metal anode enables sustainable zinc batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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