IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-022-35630-6.html
   My bibliography  Save this article

Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities

Author

Listed:
  • Xinhua Zheng

    (University of Science and Technology of China)

  • Zaichun Liu

    (University of Science and Technology of China)

  • Jifei Sun

    (University of Science and Technology of China)

  • Ruihao Luo

    (University of Science and Technology of China)

  • Kui Xu

    (University of Science and Technology of China)

  • Mingyu Si

    (Beijing Institute of Petrochemical Technology)

  • Ju Kang

    (Beijing Institute of Petrochemical Technology)

  • Yuan Yuan

    (University of Science and Technology of China)

  • Shuang Liu

    (University of Science and Technology of China)

  • Touqeer Ahmad

    (University of Science and Technology of China)

  • Taoli Jiang

    (University of Science and Technology of China)

  • Na Chen

    (University of Science and Technology of China)

  • Mingming Wang

    (University of Science and Technology of China)

  • Yan Xu

    (University of Science and Technology of China)

  • Mingyan Chuai

    (University of Science and Technology of China)

  • Zhengxin Zhu

    (University of Science and Technology of China)

  • Qia Peng

    (University of Science and Technology of China)

  • Yahan Meng

    (University of Science and Technology of China)

  • Kai Zhang

    (University of Science and Technology of China)

  • Weiping Wang

    (University of Science and Technology of China)

  • Wei Chen

    (University of Science and Technology of China)

Abstract

The development of Zn-free anodes to inhibit Zn dendrite formation and modulate high-capacity Zn batteries is highly applauded yet very challenging. Here, we design a robust two-dimensional antimony/antimony-zinc alloy heterostructured interface to regulate Zn plating. Benefiting from the stronger adsorption and homogeneous electric field distribution of the Sb/Sb2Zn3-heterostructured interface in Zn plating, the Zn anode enables an ultrahigh areal capacity of 200 mAh cm−2 with an overpotential of 112 mV and a Coulombic efficiency of 98.5%. An anode-free Zn-Br2 battery using the Sb/Sb2Zn3-heterostructured interface@Cu anode shows an attractive energy density of 274 Wh kg−1 with a practical pouch cell energy density of 62 Wh kg−1. The scaled-up Zn-Br2 battery in a capacity of 500 mAh exhibits over 400 stable cycles. Further, the Zn-Br2 battery module in an energy of 9 Wh (6 V, 1.5 Ah) is integrated with a photovoltaic panel to demonstrate the practical renewable energy storage capabilities. Our superior anode-free Zn batteries enabled by the heterostructured interface enlighten an arena towards large-scale energy storage applications.

Suggested Citation

  • Xinhua Zheng & Zaichun Liu & Jifei Sun & Ruihao Luo & Kui Xu & Mingyu Si & Ju Kang & Yuan Yuan & Shuang Liu & Touqeer Ahmad & Taoli Jiang & Na Chen & Mingming Wang & Yan Xu & Mingyan Chuai & Zhengxin , 2023. "Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-022-35630-6
    DOI: 10.1038/s41467-022-35630-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-35630-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-35630-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    2. Rochelle Weber & Matthew Genovese & A. J. Louli & Samuel Hames & Cameron Martin & Ian G. Hill & J. R. Dahn, 2019. "Long cycle life and dendrite-free lithium morphology in anode-free lithium pouch cells enabled by a dual-salt liquid electrolyte," Nature Energy, Nature, vol. 4(8), pages 683-689, August.
    3. Nyamdash, Batsaikhan & Denny, Eleanor & O'Malley, Mark, 2010. "The viability of balancing wind generation with large scale energy storage," Energy Policy, Elsevier, vol. 38(11), pages 7200-7208, November.
    4. Ning Zhang & Fangyi Cheng & Junxiang Liu & Liubin Wang & Xinghui Long & Xiaosong Liu & Fujun Li & Jun Chen, 2017. "Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    5. Kangli Wang & Kai Jiang & Brice Chung & Takanari Ouchi & Paul J. Burke & Dane A. Boysen & David J. Bradwell & Hojong Kim & Ulrich Muecke & Donald R. Sadoway, 2014. "Lithium–antimony–lead liquid metal battery for grid-level energy storage," Nature, Nature, vol. 514(7522), pages 348-350, October.
    6. Junmin Ge & Ling Fan & Apparao M. Rao & Jiang Zhou & Bingan Lu, 2022. "Surface-substituted Prussian blue analogue cathode for sustainable potassium-ion batteries," Nature Sustainability, Nature, vol. 5(3), pages 225-234, March.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yunxiang Zhao & Shan Guo & Manjing Chen & Bingan Lu & Xiaotan Zhang & Shuquan Liang & Jiang Zhou, 2023. "Tailoring grain boundary stability of zinc-titanium alloy for long-lasting aqueous zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Zhijing Yu & Wei Wang & Yong Zhu & Wei-Li Song & Zheng Huang & Zhe Wang & Shuqiang Jiao, 2023. "Construction of double reaction zones for long-life quasi-solid aluminum-ion batteries by realizing maximum electron transfer," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Xiaotan Zhang & Jiangxu Li & Yanfen Liu & Bingan Lu & Shuquan Liang & Jiang Zhou, 2024. "Single [0001]-oriented zinc metal anode enables sustainable zinc batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Minsung Baek & Jinyoung Kim & Kwanghoon Jeong & Seonmo Yang & Heejin Kim & Jimin Lee & Minkwan Kim & Ki Jae Kim & Jang Wook Choi, 2023. "Naked metallic skin for homo-epitaxial deposition in lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Bomian Zhang & Jinghui Chen & Weiyi Sun & Yubo Shao & Lei Zhang & Kangning Zhao, 2022. "Challenges and Perspectives for Doping Strategy for Manganese-Based Zinc-ion Battery Cathode," Energies, MDPI, vol. 15(13), pages 1-20, June.
    3. Chen, Long Xiang & Xie, Mei Na & Zhao, Pan Pan & Wang, Feng Xiang & Hu, Peng & Wang, Dong Xiang, 2018. "A novel isobaric adiabatic compressed air energy storage (IA-CAES) system on the base of volatile fluid," Applied Energy, Elsevier, vol. 210(C), pages 198-210.
    4. Qin, Chao & Saunders, Gordon & Loth, Eric, 2017. "Offshore wind energy storage concept for cost-of-rated-power savings," Applied Energy, Elsevier, vol. 201(C), pages 148-157.
    5. Durmaz, Tunç, 2016. "Precautionary Storage in Electricity Markets," Discussion Papers 2016/5, Norwegian School of Economics, Department of Business and Management Science.
    6. Chen, Xuejun & Yang, Yongming & Cui, Zhixin & Shen, Jun, 2019. "Vibration fault diagnosis of wind turbines based on variational mode decomposition and energy entropy," Energy, Elsevier, vol. 174(C), pages 1100-1109.
    7. Pedro Crespo Del Granado & Stein Wallace & Zhan Pang, 2016. "The impact of wind uncertainty on the strategic valuation of distributed electricity storage," Computational Management Science, Springer, vol. 13(1), pages 5-27, January.
    8. Muhammad Habib Ur Rehman & Luigi Coppola & Ernestino Lufrano & Isabella Nicotera & Cataldo Simari, 2023. "Enhancing Water Retention, Transport, and Conductivity Performance in Fuel Cell Applications: Nafion-Based Nanocomposite Membranes with Organomodified Graphene Oxide Nanoplatelets," Energies, MDPI, vol. 16(23), pages 1-11, November.
    9. Pin Li & Jinsuo Zhang, 2019. "Is China’s Energy Supply Sustainable? New Research Model Based on the Exponential Smoothing and GM(1,1) Methods," Energies, MDPI, vol. 12(2), pages 1-30, January.
    10. Sung-Fu Hung & Aoni Xu & Xue Wang & Fengwang Li & Shao-Hui Hsu & Yuhang Li & Joshua Wicks & Eduardo González Cervantes & Armin Sedighian Rasouli & Yuguang C. Li & Mingchuan Luo & Dae-Hyun Nam & Ning W, 2022. "A metal-supported single-atom catalytic site enables carbon dioxide hydrogenation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    11. Zheng, Bobo & Xu, Jiuping & Ni, Ting & Li, Meihui, 2015. "Geothermal energy utilization trends from a technological paradigm perspective," Renewable Energy, Elsevier, vol. 77(C), pages 430-441.
    12. Mao, Guozhu & Zou, Hongyang & Chen, Guanyi & Du, Huibin & Zuo, Jian, 2015. "Past, current and future of biomass energy research: A bibliometric analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1823-1833.
    13. Luo, Rongrong & Wang, Liuwei & Yu, Wei & Shao, Feilong & Shen, Haikuo & Xie, Huaqing, 2023. "High energy storage density titanium nitride-pentaerythritol solid–solid composite phase change materials for light-thermal-electric conversion," Applied Energy, Elsevier, vol. 331(C).
    14. Ewa C. E. Rönnebro & Greg Whyatt & Michael Powell & Matthew Westman & Feng (Richard) Zheng & Zhigang Zak Fang, 2015. "Metal Hydrides for High-Temperature Power Generation," Energies, MDPI, vol. 8(8), pages 1-25, August.
    15. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    16. Chang, Chih-Chang & Huang, Wei-Hao & Mai, Van-Phung & Tsai, Jia-Shiuan & Yang, Ruey-Jen, 2021. "Experimental investigation into energy harvesting of NaCl droplet flow over graphene supported by silicon dioxide," Energy, Elsevier, vol. 229(C).
    17. Abbaspour, M. & Satkin, M. & Mohammadi-Ivatloo, B. & Hoseinzadeh Lotfi, F. & Noorollahi, Y., 2013. "Optimal operation scheduling of wind power integrated with compressed air energy storage (CAES)," Renewable Energy, Elsevier, vol. 51(C), pages 53-59.
    18. Díaz-González, Francisco & Sumper, Andreas & Gomis-Bellmunt, Oriol & Villafáfila-Robles, Roberto, 2012. "A review of energy storage technologies for wind power applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2154-2171.
    19. Chen, Hao & Wang, Huanran & Li, Ruixiong & Sun, Hao & Ge, Gangqiang & Ling, Lanning, 2022. "Experimental and analytical investigation of near-isothermal pumped hydro-compressed air energy storage system," Energy, Elsevier, vol. 249(C).
    20. Wang, Jiayu, 2016. "Do light vehicle emissions standards promote environmental goals in Australia?," Conference papers 332692, Purdue University, Center for Global Trade Analysis, Global Trade Analysis Project.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-022-35630-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.