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Determination of Nitrate Migration and Distribution through Eutric Cambisols in an Area without Anthropogenic Sources of Nitrate (Velika Gorica Well Field, Croatia)

Author

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  • Patricia Buškulić

    (Faculty of Mining, Geology and Petroleum Engineering, University of Zagreb, 10000 Zagreb, Croatia)

  • Jelena Parlov

    (Faculty of Mining, Geology and Petroleum Engineering, University of Zagreb, 10000 Zagreb, Croatia)

  • Zoran Kovač

    (Faculty of Mining, Geology and Petroleum Engineering, University of Zagreb, 10000 Zagreb, Croatia)

  • Tomislav Brenko

    (Faculty of Mining, Geology and Petroleum Engineering, University of Zagreb, 10000 Zagreb, Croatia)

  • Marija Pejić

    (Faculty of Mining, Geology and Petroleum Engineering, University of Zagreb, 10000 Zagreb, Croatia)

Abstract

Natural potential sources of nitrate contamination involve decaying of organic matter, bacterial production, atmospheric deposition, and soil N. The study presents the first results of nitrate distribution and migration through soil horizons of the Eutric Cambisols, one of the most common soils developed in the area of the Zagreb aquifer and situated in an area without potential anthropogenic sources of nitrate (first sanitary protection zone of the Velika Gorica well field). A total of 16 parameters of soil water and 16 parameters of soil were used to conduct statistical techniques and analyse associated factors within the soil zone. The results indicate that in the deepest soil horizon, nitrogen is present mostly as nitrate due to nitrification under aerobic conditions which promote stability and the potential for nitrate transport. It was found that nitrate concentrations are the result of soil N nitrification, caused by a NO 3 − /Cl − molar ratio higher than 1 and the absence of precipitation isotopic signature. The results also show that within the coarse-grained Eutric Cambisols N primarily migrates to deeper parts of unsaturated zone in the form of nitrate and nitrite.

Suggested Citation

  • Patricia Buškulić & Jelena Parlov & Zoran Kovač & Tomislav Brenko & Marija Pejić, 2023. "Determination of Nitrate Migration and Distribution through Eutric Cambisols in an Area without Anthropogenic Sources of Nitrate (Velika Gorica Well Field, Croatia)," Sustainability, MDPI, vol. 15(23), pages 1-19, December.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:23:p:16529-:d:1293563
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    2. S. Leininger & T. Urich & M. Schloter & L. Schwark & J. Qi & G. W. Nicol & J. I. Prosser & S. C. Schuster & C. Schleper, 2006. "Archaea predominate among ammonia-oxidizing prokaryotes in soils," Nature, Nature, vol. 442(7104), pages 806-809, August.
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    1. Nikolina Novotni-Horčička & Tamara Marković & Igor Karlović & Ivan Kovač, 2024. "Application of Hydrochemical Parameters as Tool for Sustainable Management of Water Supply Network," Sustainability, MDPI, vol. 16(21), pages 1-22, November.

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