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Optimization of Blighia sapida Seed Oil Biodiesel Production: A Sustainable Approach to Renewable Biofuels

Author

Listed:
  • Oyetola Ogunkunle

    (Department of Mechanical, Bioresources and Biomedical Engineering, Science Campus, University of South Africa, Florida 1710, South Africa)

  • Christopher C. Enweremadu

    (Department of Mechanical, Bioresources and Biomedical Engineering, Science Campus, University of South Africa, Florida 1710, South Africa)

Abstract

This study aims to optimize the production of biodiesel from Blighia sapida (Ackee) seed oil, a non-edible and underutilized feedstock, as a sustainable alternative to conventional fossil-based diesel fuels. The transesterification of Blighia sapida seed oil was optimized using Response Surface Methodology (RSM) with a Box–Behnken experimental design. Three process variables, reaction time, temperature, and methanol-to-oil molar ratio, were selected for modeling biodiesel yield. The resulting biodiesel was characterized by physicochemical properties in accordance with ASTM D6751 standards. The optimal transesterification conditions were found to be 60 min, 60 °C, and a methanol-to-oil ratio of 3:1, yielding 98.36% biodiesel. This represents an improvement over the unoptimized yield of 94.3% at a 6:1 molar ratio. Experimental validation produced an average yield of 97.49%, confirming the model’s reliability. The produced biodiesel exhibited a kinematic viscosity of 4.02 mm 2 /s, cetane number of 54.6, flash point of 138 °C, and acid value of 0.421 mg KOH/g, which are all within the ASTM D6751 standard limits. This work is among the first to systematically optimize Blighia sapida biodiesel production using RSM. The results demonstrate its viability as a clean-burning, high-quality biodiesel fuel with promising fuel properties and environmental benefits. Its high cetane number and low methanol requirement enhance its combustion performance and production efficiency, positioning Blighia sapida as a competitive feedstock for sustainable biofuel development.

Suggested Citation

  • Oyetola Ogunkunle & Christopher C. Enweremadu, 2025. "Optimization of Blighia sapida Seed Oil Biodiesel Production: A Sustainable Approach to Renewable Biofuels," Resources, MDPI, vol. 14(6), pages 1-26, May.
    • Handle: RePEc:gam:jresou:v:14:y:2025:i:6:p:89-:d:1664947
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    References listed on IDEAS

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    1. Silalertruksa, Thapat & Gheewala, Shabbir H., 2012. "Environmental sustainability assessment of palm biodiesel production in Thailand," Energy, Elsevier, vol. 43(1), pages 306-314.
    2. Rincón, L.E. & Jaramillo, J.J. & Cardona, C.A., 2014. "Comparison of feedstocks and technologies for biodiesel production: An environmental and techno-economic evaluation," Renewable Energy, Elsevier, vol. 69(C), pages 479-487.
    3. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    4. Ogunkunle, Oyetola & Ahmed, Noor A., 2019. "Performance evaluation of a diesel engine using blends of optimized yields of sand apple (Parinari polyandra) oil biodiesel," Renewable Energy, Elsevier, vol. 134(C), pages 1320-1331.
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