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The BioSCWG Project: Understanding the Trade-Offs in the Process and Thermal Design of Hydrogen and Synthetic Natural Gas Production

Author

Listed:
  • Mohamed Magdeldin

    (Department of Mechanical Engineering, School of Engineering, Aalto University, Aalto FI-00076, Finland)

  • Thomas Kohl

    (Department of Mechanical Engineering, School of Engineering, Aalto University, Aalto FI-00076, Finland)

  • Cataldo De Blasio

    (Department of Mechanical Engineering, School of Engineering, Aalto University, Aalto FI-00076, Finland
    Department of Chemical Engineering, Åbo Akademi University, Turku 20500, Finland)

  • Mika Järvinen

    (Department of Mechanical Engineering, School of Engineering, Aalto University, Aalto FI-00076, Finland)

  • Song Won Park

    (Department of Chemical Engineering, Universidade de São Paulo, São Paulo 05508-010, Brazil)

  • Reinaldo Giudici

    (Department of Chemical Engineering, Universidade de São Paulo, São Paulo 05508-010, Brazil)

Abstract

This article presents a summary of the main findings from a collaborative research project between Aalto University in Finland and partner universities. A comparative process synthesis, modelling and thermal assessment was conducted for the production of Bio-synthetic natural gas (SNG) and hydrogen from supercritical water refining of a lipid extracted algae feedstock integrated with onsite heat and power generation. The developed reactor models for product gas composition, yield and thermal demand were validated and showed conformity with reported experimental results, and the balance of plant units were designed based on established technologies or state-of-the-art pilot operations. The poly-generative cases illustrated the thermo-chemical constraints and design trade-offs presented by key process parameters such as plant organic throughput, supercritical water refining temperature, nature of desirable coproducts, downstream indirect production and heat recovery scenarios. The evaluated cases favoring hydrogen production at 5 wt. % solid content and 600 °C conversion temperature allowed higher gross syngas and CHP production. However, mainly due to the higher utility demands the net syngas production remained lower compared to the cases favoring BioSNG production. The latter case, at 450 °C reactor temperature, 18 wt. % solid content and presence of downstream indirect production recorded 66.5%, 66.2% and 57.2% energetic, fuel-equivalent and exergetic efficiencies respectively.

Suggested Citation

  • Mohamed Magdeldin & Thomas Kohl & Cataldo De Blasio & Mika Järvinen & Song Won Park & Reinaldo Giudici, 2016. "The BioSCWG Project: Understanding the Trade-Offs in the Process and Thermal Design of Hydrogen and Synthetic Natural Gas Production," Energies, MDPI, vol. 9(10), pages 1-27, October.
  • Handle: RePEc:gam:jeners:v:9:y:2016:i:10:p:838-:d:80785
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    References listed on IDEAS

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    1. Onursal Yakaboylu & John Harinck & K. G. Smit & Wiebren De Jong, 2015. "Supercritical Water Gasification of Biomass: A Literature and Technology Overview," Energies, MDPI, vol. 8(2), pages 1-36, January.
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    2. Granacher, Julia & Nguyen, Tuong-Van & Castro-Amoedo, Rafael & Maréchal, François, 2022. "Overcoming decision paralysis—A digital twin for decision making in energy system design," Applied Energy, Elsevier, vol. 306(PA).
    3. De Blasio, Cataldo & De Gisi, Sabino & Molino, Antonio & Simonetti, Marco & Santarelli, Massimo & Björklund-Sänkiaho, Margareta, 2019. "Concerning operational aspects in supercritical water gasification of kraft black liquor," Renewable Energy, Elsevier, vol. 130(C), pages 891-901.
    4. Vincenzo Palma & Concetta Ruocco & Eugenio Meloni & Antonio Ricca, 2017. "Influence of Catalytic Formulation and Operative Conditions on Coke Deposition over CeO 2 -SiO 2 Based Catalysts for Ethanol Reforming," Energies, MDPI, vol. 10(7), pages 1-13, July.
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    6. Magdeldin, Mohamed & Kohl, Thomas & Järvinen, Mika, 2017. "Techno-economic assessment of the by-products contribution from non-catalytic hydrothermal liquefaction of lignocellulose residues," Energy, Elsevier, vol. 137(C), pages 679-695.
    7. Qi, Xingang & Li, Xujun & Liu, Fan & Lu, Libo & Jin, Hui & Wei, Wenwen & Chen, Yunan & Guo, Liejin, 2023. "Hydrogen production by kraft black liquor supercritical water gasification: Reaction pathway and kinetic," Energy, Elsevier, vol. 282(C).
    8. Nurdiawati, Anissa & Zaini, Ilman Nuran & Irhamna, Adrian Rizqi & Sasongko, Dwiwahju & Aziz, Muhammad, 2019. "Novel configuration of supercritical water gasification and chemical looping for highly-efficient hydrogen production from microalgae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 369-381.
    9. Chia-Nan Wang & Min-Tsong Chou & Hsien-Pin Hsu & Jing-Wein Wang & Sridhar Selvaraj, 2017. "The Efficiency Improvement by Combining HHO Gas, Coal and Oil in Boiler for Electricity Generation," Energies, MDPI, vol. 10(2), pages 1-13, February.
    10. Magdeldin, Mohamed & Järvinen, Mika, 2020. "Supercritical water gasification of Kraft black liquor: Process design, analysis, pulp mill integration and economic evaluation," Applied Energy, Elsevier, vol. 262(C).

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