IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v2y2009i2p377-410d5190.html
   My bibliography  Save this article

Direct Utilization of Liquid Fuels in SOFC for Portable Applications: Challenges for the Selection of Alternative Anodes

Author

Listed:
  • Massimiliano Cimenti

    (Department of Chemical and Petroleum Engineering, Schulich School of Engineering, University of Calgary, 2500 University Dr. NW, Calgary, AB T2N 1N4, Canada)

  • Josephine M. Hill

    (Department of Chemical and Petroleum Engineering, Schulich School of Engineering, University of Calgary, 2500 University Dr. NW, Calgary, AB T2N 1N4, Canada)

Abstract

Solid oxide fuel cells (SOFC) have the advantage of being able to operate with fuels other than hydrogen. In particular, liquid fuels are especially attractive for powering portable applications such as small power generators or auxiliary power units, in which case the direct utilization of the fuel would be convenient. Although liquid fuels are easier to handle and transport than hydrogen, their direct use in SOFC can lead to anode deactivation due to carbon formation, especially on traditional nickel/yttria stabilized zirconia (Ni/YSZ) anodes. Significant advances have been made in anodic materials that are resistant to carbon formation but often these materials are less electrochemically active than Ni/YSZ. In this review the challenges of using liquid fuels directly in SOFC, in terms of gas-phase and catalytic reactions within the anode chamber, will be discussed and the alternative anode materials so far investigated will be compared.

Suggested Citation

  • Massimiliano Cimenti & Josephine M. Hill, 2009. "Direct Utilization of Liquid Fuels in SOFC for Portable Applications: Challenges for the Selection of Alternative Anodes," Energies, MDPI, vol. 2(2), pages 1-34, June.
    • Handle: RePEc:gam:jeners:v:2:y:2009:i:2:p:377-410:d:5190
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/2/2/377/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/2/2/377/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Brian C. H. Steele, 1999. "Running on natural gas," Nature, Nature, vol. 400(6745), pages 619-621, August.
    2. Seungdoo Park & John M. Vohs & Raymond J. Gorte, 2000. "Direct oxidation of hydrocarbons in a solid-oxide fuel cell," Nature, Nature, vol. 404(6775), pages 265-267, March.
    3. E. Perry Murray & T. Tsai & S. A. Barnett, 1999. "A direct-methane fuel cell with a ceria-based anode," Nature, Nature, vol. 400(6745), pages 649-651, August.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xu, Qidong & Xia, Lingchao & He, Qijiao & Guo, Zengjia & Ni, Meng, 2021. "Thermo-electrochemical modelling of high temperature methanol-fuelled solid oxide fuel cells," Applied Energy, Elsevier, vol. 291(C).
    2. Yuanwu Xu & Hao Shu & Hongchuan Qin & Xiaolong Wu & Jingxuan Peng & Chang Jiang & Zhiping Xia & Yongan Wang & Xi Li, 2022. "Real-Time State of Health Estimation for Solid Oxide Fuel Cells Based on Unscented Kalman Filter," Energies, MDPI, vol. 15(7), pages 1-17, March.
    3. Thieu, Cam-Anh & Ji, Ho-Il & Kim, Hyoungchul & Yoon, Kyung Joong & Lee, Jong-Ho & Son, Ji-Won, 2019. "Palladium incorporation at the anode of thin-film solid oxide fuel cells and its effect on direct utilization of butane fuel at 600 °C," Applied Energy, Elsevier, vol. 243(C), pages 155-164.
    4. Huaiyu Shao, 2017. "Heat Modeling and Material Development of Mg-Based Nanomaterials Combined with Solid Oxide Fuel Cell for Stationary Energy Storage," Energies, MDPI, vol. 10(11), pages 1-11, November.
    5. Harun, Nor Farida & Tucker, David & Adams, Thomas A., 2016. "Impact of fuel composition transients on SOFC performance in gas turbine hybrid systems," Applied Energy, Elsevier, vol. 164(C), pages 446-461.
    6. Badwal, S.P.S. & Giddey, S. & Kulkarni, A. & Goel, J. & Basu, S., 2015. "Direct ethanol fuel cells for transport and stationary applications – A comprehensive review," Applied Energy, Elsevier, vol. 145(C), pages 80-103.
    7. Shaikh, Shabana P.S. & Muchtar, Andanastuti & Somalu, Mahendra R., 2015. "A review on the selection of anode materials for solid-oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1-8.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sariboğa, Vedat & Öksüzömer, Faruk, 2012. "The investigation of active Ni/YSZ interlayer for Cu-based direct-methane solid oxide fuel cells," Applied Energy, Elsevier, vol. 93(C), pages 707-721.
    2. Cai, Weizi & Zhou, Qian & Xie, Yongmin & Liu, Jiang & Long, Guohui & Cheng, Shuang & Liu, Meilin, 2016. "A direct carbon solid oxide fuel cell operated on a plant derived biofuel with natural catalyst," Applied Energy, Elsevier, vol. 179(C), pages 1232-1241.
    3. Yu, Fangyong & Xiao, Jie & Zhang, Yapeng & Cai, Weizi & Xie, Yongmin & Yang, Naitao & Liu, Jiang & Liu, Meilin, 2019. "New insights into carbon deposition mechanism of nickel/yttrium-stabilized zirconia cermet from methane by in situ investigation," Applied Energy, Elsevier, vol. 256(C).
    4. Mohamad Fairus Rabuni & Tao Li & Mohd Hafiz Dzarfan Othman & Faidzul Hakim Adnan & Kang Li, 2023. "Progress in Solid Oxide Fuel Cells with Hydrocarbon Fuels," Energies, MDPI, vol. 16(17), pages 1-36, September.
    5. Fan, Liyuan & Li, Chao'en & van Biert, Lindert & Zhou, Shou-Han & Tabish, Asif Nadeem & Mokhov, Anatoli & Aravind, Purushothaman Vellayani & Cai, Weiwei, 2022. "Advances on methane reforming in solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    6. Xu, Han & Dang, Zheng, 2016. "Lattice Boltzmann modeling of carbon deposition in porous anode of a solid oxide fuel cell with internal reforming," Applied Energy, Elsevier, vol. 178(C), pages 294-307.
    7. Hu, Boxun & Keane, Michael & Patil, Kailash & Mahapatra, Manoj K. & Pasaogullari, Ugur & Singh, Prabhakar, 2014. "Direct methanol utilization in intermediate temperature liquid-tin anode solid oxide fuel cells," Applied Energy, Elsevier, vol. 134(C), pages 342-348.
    8. Park, Kwangjin & Lee, Sangho & Bae, Gyujong & Bae, Joongmyeon, 2015. "Performance analysis of Cu, Sn and Rh impregnated NiO/CGO91 anode for butane internal reforming SOFC at intermediate temperature," Renewable Energy, Elsevier, vol. 83(C), pages 483-490.
    9. Thieu, Cam-Anh & Ji, Ho-Il & Kim, Hyoungchul & Yoon, Kyung Joong & Lee, Jong-Ho & Son, Ji-Won, 2019. "Palladium incorporation at the anode of thin-film solid oxide fuel cells and its effect on direct utilization of butane fuel at 600 °C," Applied Energy, Elsevier, vol. 243(C), pages 155-164.
    10. Saadabadi, S. Ali & Thallam Thattai, Aditya & Fan, Liyuan & Lindeboom, Ralph E.F. & Spanjers, Henri & Aravind, P.V., 2019. "Solid Oxide Fuel Cells fuelled with biogas: Potential and constraints," Renewable Energy, Elsevier, vol. 134(C), pages 194-214.
    11. Milanese, Marco & Colangelo, Gianpiero & Laforgia, Domenico & de Risi, Arturo, 2017. "Multi-parameter optimization of double-loop fluidized bed solar reactor for thermochemical fuel production," Energy, Elsevier, vol. 134(C), pages 919-932.
    12. Badwal, S.P.S. & Giddey, S. & Kulkarni, A. & Goel, J. & Basu, S., 2015. "Direct ethanol fuel cells for transport and stationary applications – A comprehensive review," Applied Energy, Elsevier, vol. 145(C), pages 80-103.
    13. Freida Ozavize Ayodele & Siti Indati Mustapa & Bamidele Victor Ayodele & Norsyahida Mohammad, 2020. "An Overview of Economic Analysis and Environmental Impacts of Natural Gas Conversion Technologies," Sustainability, MDPI, vol. 12(23), pages 1-18, December.
    14. Yue Teng & Ho Yeon Lee & Haesu Lee & Yoon Ho Lee, 2022. "Effect of Sputtering Pressure on the Nanostructure and Residual Stress of Thin-Film YSZ Electrolyte," Sustainability, MDPI, vol. 14(15), pages 1-9, August.
    15. Gómez, Sergio Yesid & Hotza, Dachamir, 2016. "Current developments in reversible solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 155-174.
    16. Shri Prakash, B. & Senthil Kumar, S. & Aruna, S.T., 2014. "Properties and development of Ni/YSZ as an anode material in solid oxide fuel cell: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 149-179.
    17. Cano-Andrade, S. & Hernandez-Guerrero, A. & von Spakovsky, M.R. & Damian-Ascencio, C.E. & Rubio-Arana, J.C., 2010. "Current density and polarization curves for radial flow field patterns applied to PEMFCs (Proton Exchange Membrane Fuel Cells)," Energy, Elsevier, vol. 35(2), pages 920-927.
    18. Jiao, Yong & Zhang, Liqin & An, Wenting & Zhou, Wei & Sha, Yujing & Shao, Zongping & Bai, Jianping & Li, Si-Dian, 2016. "Controlled deposition and utilization of carbon on Ni-YSZ anodes of SOFCs operating on dry methane," Energy, Elsevier, vol. 113(C), pages 432-443.
    19. Razbani, Omid & Wærnhus, Ivar & Assadi, Mohsen, 2013. "Experimental investigation of temperature distribution over a planar solid oxide fuel cell," Applied Energy, Elsevier, vol. 105(C), pages 155-160.
    20. Budzianowski, Wojciech M., 2016. "A review of potential innovations for production, conditioning and utilization of biogas with multiple-criteria assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1148-1171.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:2:y:2009:i:2:p:377-410:d:5190. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.