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Performance analysis of Cu, Sn and Rh impregnated NiO/CGO91 anode for butane internal reforming SOFC at intermediate temperature

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  • Park, Kwangjin
  • Lee, Sangho
  • Bae, Gyujong
  • Bae, Joongmyeon

Abstract

In this work, the performance of solid oxide fuel cells (SOFC) consisting of Cu, Sn and Rh impregnated NiO/CGO91 anode is investigated for butane internal reforming mode at an intermediate temperature (600 °C). Steam reforming activities of Ni and Ce0.9Gd0.1O2 (CGO91) and Ni and Y0.08Zr0.92O2 (8YSZ) are tested as anode materials of internal reforming SOFC. In butane steam reforming, NiO/CGO91 shows better performance than NiO/8YSZ. However, butane is incomplete converted over NiO/CGO91 even if the gas hourly space velocity is very low. Cu, Sn and Rh are added to the NiO/CGO91 materials to increase the conversion of butane. Among the additives, the Rh is the most effective, resulting in 100% of butane conversion and no carbon deposition. Moreover, Rh added NiO/CGO91 SOFC single cell have a very low degradation rate when the SOFC sing cell is operated in internal reforming mode using butane.

Suggested Citation

  • Park, Kwangjin & Lee, Sangho & Bae, Gyujong & Bae, Joongmyeon, 2015. "Performance analysis of Cu, Sn and Rh impregnated NiO/CGO91 anode for butane internal reforming SOFC at intermediate temperature," Renewable Energy, Elsevier, vol. 83(C), pages 483-490.
    • Handle: RePEc:eee:renene:v:83:y:2015:i:c:p:483-490
    DOI: 10.1016/j.renene.2015.04.070
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    References listed on IDEAS

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    1. Seungdoo Park & John M. Vohs & Raymond J. Gorte, 2000. "Direct oxidation of hydrocarbons in a solid-oxide fuel cell," Nature, Nature, vol. 404(6775), pages 265-267, March.
    2. E. Perry Murray & T. Tsai & S. A. Barnett, 1999. "A direct-methane fuel cell with a ceria-based anode," Nature, Nature, vol. 400(6745), pages 649-651, August.
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    1. Thieu, Cam-Anh & Ji, Ho-Il & Kim, Hyoungchul & Yoon, Kyung Joong & Lee, Jong-Ho & Son, Ji-Won, 2019. "Palladium incorporation at the anode of thin-film solid oxide fuel cells and its effect on direct utilization of butane fuel at 600 °C," Applied Energy, Elsevier, vol. 243(C), pages 155-164.

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