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Production of Sustainable Adsorbents for CO 2 Capture Applications from Food Biowastes

Author

Listed:
  • Fernando Rubiera

    (Instituto de Ciencia y Tecnología del Carbono (INCAR), CSIC, C/Francisco Pintado Fe 26, 33011 Oviedo, Spain)

  • Carlos Córdoba

    (Instituto de Ciencia y Tecnología del Carbono (INCAR), CSIC, C/Francisco Pintado Fe 26, 33011 Oviedo, Spain)

  • Tamara Pena

    (Instituto de Ciencia y Tecnología del Carbono (INCAR), CSIC, C/Francisco Pintado Fe 26, 33011 Oviedo, Spain)

  • Marta G. Plaza

    (Instituto de Ciencia y Tecnología del Carbono (INCAR), CSIC, C/Francisco Pintado Fe 26, 33011 Oviedo, Spain)

Abstract

Traditional methods to develop biomass-based carbon adsorbents generally involve carbonization followed by chemical or physical activation. However, routes involving the hydrothermal treatment of biomass are receiving growing interest. In this work, two different strategies for the synthesis of sustainable CO 2 adsorbents are compared, i.e., in situ ionic activation and hydrothermal treatment followed by activation with CO 2 . The latter is a green and simple procedure that does not require the addition of chemicals or acid-washing stages, and which leads to carbon adsorbents with relatively high CO 2 adsorption capacity at low pressures, up to 0.64 mmol g −1 at 15 kPa and 50 °C, conditions relevant for postcombustion CO 2 capture applications. On the other hand, in situ ionic activation can lead to carbon adsorbents with superior CO 2 adsorption capacity in the aforementioned conditions, 0.78 mmol g −1 , and with reduced cost and environmental impact compared to conventional chemical activation.

Suggested Citation

  • Fernando Rubiera & Carlos Córdoba & Tamara Pena & Marta G. Plaza, 2024. "Production of Sustainable Adsorbents for CO 2 Capture Applications from Food Biowastes," Energies, MDPI, vol. 17(5), pages 1-20, March.
  • Handle: RePEc:gam:jeners:v:17:y:2024:i:5:p:1205-:d:1350392
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    References listed on IDEAS

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    1. Plaza, M.G. & González, A.S. & Pevida, C. & Pis, J.J. & Rubiera, F., 2012. "Valorisation of spent coffee grounds as CO2 adsorbents for postcombustion capture applications," Applied Energy, Elsevier, vol. 99(C), pages 272-279.
    2. Lorenzo Rosa & Jeffrey A. Reimer & Marjorie S. Went & Paolo D’Odorico, 2020. "Hydrological limits to carbon capture and storage," Nature Sustainability, Nature, vol. 3(8), pages 658-666, August.
    3. Plaza, M.G. & González, A.S. & Pis, J.J. & Rubiera, F. & Pevida, C., 2014. "Production of microporous biochars by single-step oxidation: Effect of activation conditions on CO2 capture," Applied Energy, Elsevier, vol. 114(C), pages 551-562.
    4. Ben-Mansour, R. & Habib, M.A. & Bamidele, O.E. & Basha, M. & Qasem, N.A.A. & Peedikakkal, A. & Laoui, T. & Ali, M., 2016. "Carbon capture by physical adsorption: Materials, experimental investigations and numerical modeling and simulations – A review," Applied Energy, Elsevier, vol. 161(C), pages 225-255.
    5. Goto, Kazuya & Yogo, Katsunori & Higashii, Takayuki, 2013. "A review of efficiency penalty in a coal-fired power plant with post-combustion CO2 capture," Applied Energy, Elsevier, vol. 111(C), pages 710-720.
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