IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v218y2018icp417-429.html
   My bibliography  Save this article

Evaluating CO2 desorption performance in CO2-loaded aqueous tri-solvent blend amines with and without solid acid catalysts

Author

Listed:
  • Zhang, Xiaowen
  • Zhang, Rui
  • Liu, Helei
  • Gao, Hongxia
  • Liang, Zhiwu

Abstract

To enhance the energy efficiency of the CO2 desorption process, the regeneration behaviors of the CO2-loaded 6 M MEA-AMP-PZ (monoethanolamine, 2-amino-2-methyl-1-propanol and piperazine) tri-solvent blends with different AMP/PZ molar ratios with four different solid acid catalysts (H-ZSM-5, γ-Al2O3, SAPO-34 and SO42−/TiO2) and a blank at 96 °C were investigated in terms of CO2 desorption rate, cyclic capacity and relative heat duty. For the no-catalytic runs, the results showed that all the tri-solvent blended amines greatly increased CO2 desorption rate, cyclic capacity and decreased the relative heat duty in comparison with 5 M MEA. The 13C NMR analysis indicated that the 3 M MEA-2.5 M AMP-0.5 M PZ blend with the highest AMP/PZ ratio produced the largest amount of bicarbonate and less carbamate, which resulted in the best desorption performance. With regard to catalyst, when the solid acid catalysts were introduced, the regeneration performance of the blend was further improved. The best of the blends along with H-ZSM-5 provided the combination with the best performance in CO2 desorption, and reduced the relative heat duty by 61.6% as compared to 5 M MEA without catalyst (100%). Five relevant physicochemical properties of the catalyst were obtained and used to better understand the catalytic regeneration process. A possible catalytic CO2 desorption mechanism was analyzed. The results revealed that the mesopore surface area coupled with total acid sites of the catalyst had the most positive influence on improving the CO2 desorption performance. Findings from this work imply that the combination of solid acid catalyst with tri-solvent blended amines is a promising alternative method for further reduction of solvent regeneration energy requirement.

Suggested Citation

  • Zhang, Xiaowen & Zhang, Rui & Liu, Helei & Gao, Hongxia & Liang, Zhiwu, 2018. "Evaluating CO2 desorption performance in CO2-loaded aqueous tri-solvent blend amines with and without solid acid catalysts," Applied Energy, Elsevier, vol. 218(C), pages 417-429.
    • Handle: RePEc:eee:appene:v:218:y:2018:i:c:p:417-429
    DOI: 10.1016/j.apenergy.2018.02.087
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918302125
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.02.087?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Xiao, Min & Liu, Helei & Idem, Raphael & Tontiwachwuthikul, Paitoon & Liang, Zhiwu, 2016. "A study of structure–activity relationships of commercial tertiary amines for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 184(C), pages 219-229.
    2. El Hadri, Nabil & Quang, Dang Viet & Goetheer, Earl L.V. & Abu Zahra, Mohammad R.M., 2017. "Aqueous amine solution characterization for post-combustion CO2 capture process," Applied Energy, Elsevier, vol. 185(P2), pages 1433-1449.
    3. Wu, Handong & Gao, Lin & Jin, Hongguang & Li, Sheng, 2017. "Low-energy-penalty principles of CO2 capture in polygeneration systems," Applied Energy, Elsevier, vol. 203(C), pages 571-581.
    4. Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
    5. Lee, Jong Sung & Lee, Jae Won & Kang, Yong Tae, 2015. "CO2 absorption/regeneration enhancement in DI water with suspended nanoparticles for energy conversion application," Applied Energy, Elsevier, vol. 143(C), pages 119-129.
    6. Wang, Peng & Guo, Yafei & Zhao, Chuanwen & Yan, Junjie & Lu, Ping, 2017. "Biomass derived wood ash with amine modification for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 201(C), pages 34-44.
    7. Oh, Se-Young & Binns, Michael & Cho, Habin & Kim, Jin-Kuk, 2016. "Energy minimization of MEA-based CO2 capture process," Applied Energy, Elsevier, vol. 169(C), pages 353-362.
    8. Yan, Shuiping & Fang, Mengxiang & Wang, Zhen & Luo, Zhongyang, 2012. "Regeneration performance of CO2-rich solvents by using membrane vacuum regeneration technology: Relationships between absorbent structure and regeneration efficiency," Applied Energy, Elsevier, vol. 98(C), pages 357-367.
    9. Shakerian, Farid & Kim, Ki-Hyun & Szulejko, Jan E. & Park, Jae-Woo, 2015. "A comparative review between amines and ammonia as sorptive media for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 148(C), pages 10-22.
    10. Zhang, Rui & Zhang, Xiaowen & Yang, Qi & Yu, Hai & Liang, Zhiwu & Luo, Xiao, 2017. "Analysis of the reduction of energy cost by using MEA-MDEA-PZ solvent for post-combustion carbon dioxide capture (PCC)," Applied Energy, Elsevier, vol. 205(C), pages 1002-1011.
    11. Yang, Jie & Yu, Xinhai & An, Lin & Tu, Shan-Tung & Yan, Jinyue, 2017. "CO2 capture with the absorbent of a mixed ionic liquid and amine solution considering the effects of SO2 and O2," Applied Energy, Elsevier, vol. 194(C), pages 9-18.
    12. Goto, Kazuya & Yogo, Katsunori & Higashii, Takayuki, 2013. "A review of efficiency penalty in a coal-fired power plant with post-combustion CO2 capture," Applied Energy, Elsevier, vol. 111(C), pages 710-720.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Xiaowen & Liu, Helei & Liang, Zhiwu & Idem, Raphael & Tontiwachwuthikul, Paitoon & Jaber Al-Marri, Mohammed & Benamor, Abdelbaki, 2018. "Reducing energy consumption of CO2 desorption in CO2-loaded aqueous amine solution using Al2O3/HZSM-5 bifunctional catalysts," Applied Energy, Elsevier, vol. 229(C), pages 562-576.
    2. Xiao, Min & Liu, Helei & Gao, Hongxia & Olson, Wilfred & Liang, Zhiwu, 2019. "CO2 capture with hybrid absorbents of low viscosity imidazolium-based ionic liquids and amine," Applied Energy, Elsevier, vol. 235(C), pages 311-319.
    3. Zarei, Fariba & Bagherzadeh Jahromi, Farideh & Elhambakhsh, Abbas & Keshavarz, Peyman, 2023. "Enhanced CO2 absorption and reduced regeneration energy consumption using modified magnetic NPs," Energy, Elsevier, vol. 278(C).
    4. Zhang, Weifeng & Xu, Yuanlong & Wang, Qiuhua, 2022. "Coupled CO2 absorption and mineralization with low-concentration monoethanolamine," Energy, Elsevier, vol. 241(C).
    5. Alivand, Masood S. & Mazaheri, Omid & Wu, Yue & Stevens, Geoffrey W. & Scholes, Colin A. & Mumford, Kathryn A., 2019. "Development of aqueous-based phase change amino acid solvents for energy-efficient CO2 capture: The role of antisolvent," Applied Energy, Elsevier, vol. 256(C).
    6. Siti Aishah Mohd Rozaiddin & Kok Keong Lau, 2022. "A Review on Enhancing Solvent Regeneration in CO 2 Absorption Process Using Nanoparticles," Sustainability, MDPI, vol. 14(8), pages 1-33, April.
    7. Zhang, Xiaowen & Huang, Yufei & Gao, Hongxia & Luo, Xiao & Liang, Zhiwu & Tontiwachwuthikul, Paitoon, 2019. "Zeolite catalyst-aided tri-solvent blend amine regeneration: An alternative pathway to reduce the energy consumption in amine-based CO2 capture process," Applied Energy, Elsevier, vol. 240(C), pages 827-841.
    8. Gao, Hongxia & Huang, Yufei & Zhang, Xiaowen & Bairq, Zain Ali Saleh & Huang, Yangqiang & Tontiwachwuthikul, Paitoon & Liang, Zhiwu, 2020. "Catalytic performance and mechanism of SO42−/ZrO2/SBA-15 catalyst for CO2 desorption in CO2-loaded monoethanolamine solution," Applied Energy, Elsevier, vol. 259(C).
    9. Zhou, Xiaobin & Liu, Chao & Zhang, Jie & Fan, Yinming & Zhu, Yinian & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Hongxiang & Zhu, Zongqiang, 2023. "Novel 2-amino-2-methyl-1-propanol-based biphasic solvent for energy-efficient carbon dioxide capture using tetraethylenepentamine as a phase change regulator," Energy, Elsevier, vol. 270(C).
    10. Liu, Sen & Gao, Hongxia & He, Chuan & Liang, Zhiwu, 2019. "Experimental evaluation of highly efficient primary and secondary amines with lower energy by a novel method for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 233, pages 443-452.
    11. Guo, Hui & Li, Chenxu & Shi, Xiaoqin & Li, Hui & Shen, Shufeng, 2019. "Nonaqueous amine-based absorbents for energy efficient CO2 capture," Applied Energy, Elsevier, vol. 239(C), pages 725-734.
    12. Lijun Li & Yingying Liu & Kejing Wu & Changjun Liu & Siyang Tang & Hairong Yue & Houfang Lu & Bin Liang, 2020. "Catalytic solvent regeneration of a CO2‐loaded MEA solution using an acidic catalyst from industrial rough metatitanic acid," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(2), pages 449-460, April.
    13. Xiao, Min & Zheng, Wenchao & Liu, Helei & Luo, Xiao & Gao, Hongxia & Liang, Zhiwu, 2021. "Thermodynamic analysis of carbamate formation and carbon dioxide absorption in N-methylaminoethanol solution," Applied Energy, Elsevier, vol. 281(C).
    14. Dehbani, Maryam & Rashidi, Hamed, 2023. "Simultaneous use of microfluidics, ultrasound and alcoholic solvents for improving CO2 desorption process," Energy, Elsevier, vol. 276(C).
    15. Ammar Bany Ata & Peter Maximilian Seufert & Christian Heinze & Falah Alobaid & Bernd Epple, 2021. "Optimization of Integrated Gasification Combined-Cycle Power Plant for Polygeneration of Power and Chemicals," Energies, MDPI, vol. 14(21), pages 1-24, November.
    16. Wang, Rujie & Liu, Shanshan & Wang, Lidong & Li, Qiangwei & Zhang, Shihan & Chen, Bo & Jiang, Lei & Zhang, Yifeng, 2019. "Superior energy-saving splitter in monoethanolamine-based biphasic solvents for CO2 capture from coal-fired flue gas," Applied Energy, Elsevier, vol. 242(C), pages 302-310.
    17. Shen, Yao & Jiang, Chenkai & Zhang, Shihan & Chen, Jun & Wang, Lidong & Chen, Jianmeng, 2018. "Biphasic solvent for CO2 capture: Amine property-performance and heat duty relationship," Applied Energy, Elsevier, vol. 230(C), pages 726-733.
    18. Zhou, Xiaobin & Jing, Guohua & Lv, Bihong & Liu, Fan & Zhou, Zuoming, 2019. "Low-viscosity and efficient regeneration of carbon dioxide capture using a biphasic solvent regulated by 2-amino-2-methyl-1-propanol," Applied Energy, Elsevier, vol. 235(C), pages 379-390.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ali Saleh Bairq, Zain & Gao, Hongxia & Huang, Yufei & Zhang, Haiyan & Liang, Zhiwu, 2019. "Enhancing CO2 desorption performance in rich MEA solution by addition of SO42−/ZrO2/SiO2 bifunctional catalyst," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    2. Zhang, Xiaowen & Liu, Helei & Liang, Zhiwu & Idem, Raphael & Tontiwachwuthikul, Paitoon & Jaber Al-Marri, Mohammed & Benamor, Abdelbaki, 2018. "Reducing energy consumption of CO2 desorption in CO2-loaded aqueous amine solution using Al2O3/HZSM-5 bifunctional catalysts," Applied Energy, Elsevier, vol. 229(C), pages 562-576.
    3. Barzagli, Francesco & Giorgi, Claudia & Mani, Fabrizio & Peruzzini, Maurizio, 2018. "Reversible carbon dioxide capture by aqueous and non-aqueous amine-based absorbents: A comparative analysis carried out by 13C NMR spectroscopy," Applied Energy, Elsevier, vol. 220(C), pages 208-219.
    4. Muhammad Asif & Muhammad Suleman & Ihtishamul Haq & Syed Asad Jamal, 2018. "Post‐combustion CO2 capture with chemical absorption and hybrid system: current status and challenges," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(6), pages 998-1031, December.
    5. Cheng, Chin-hung & Li, Kangkang & Yu, Hai & Jiang, Kaiqi & Chen, Jian & Feron, Paul, 2018. "Amine-based post-combustion CO2 capture mediated by metal ions: Advancement of CO2 desorption using copper ions," Applied Energy, Elsevier, vol. 211(C), pages 1030-1038.
    6. Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
    7. Gao, Hongxia & Huang, Yufei & Zhang, Xiaowen & Bairq, Zain Ali Saleh & Huang, Yangqiang & Tontiwachwuthikul, Paitoon & Liang, Zhiwu, 2020. "Catalytic performance and mechanism of SO42−/ZrO2/SBA-15 catalyst for CO2 desorption in CO2-loaded monoethanolamine solution," Applied Energy, Elsevier, vol. 259(C).
    8. Ji, Long & Yu, Hai & Li, Kangkang & Yu, Bing & Grigore, Mihaela & Yang, Qi & Wang, Xiaolong & Chen, Zuliang & Zeng, Ming & Zhao, Shuaifei, 2018. "Integrated absorption-mineralisation for low-energy CO2 capture and sequestration," Applied Energy, Elsevier, vol. 225(C), pages 356-366.
    9. Liu, Sen & Gao, Hongxia & He, Chuan & Liang, Zhiwu, 2019. "Experimental evaluation of highly efficient primary and secondary amines with lower energy by a novel method for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 233, pages 443-452.
    10. Pereira, Luís M.C. & Llovell, Fèlix & Vega, Lourdes F., 2018. "Thermodynamic characterisation of aqueous alkanolamine and amine solutions for acid gas processing by transferable molecular models," Applied Energy, Elsevier, vol. 222(C), pages 687-703.
    11. Xiao, Min & Liu, Helei & Gao, Hongxia & Olson, Wilfred & Liang, Zhiwu, 2019. "CO2 capture with hybrid absorbents of low viscosity imidazolium-based ionic liquids and amine," Applied Energy, Elsevier, vol. 235(C), pages 311-319.
    12. Meng, Fanzhi & Meng, Yuan & Ju, Tongyao & Han, Siyu & Lin, Li & Jiang, Jianguo, 2022. "Research progress of aqueous amine solution for CO2 capture: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    13. Zhang, Rui & Yang, Qi & Yu, Bing & Yu, Hai & Liang, Zhiwu, 2018. "Toward to efficient CO2 capture solvent design by analyzing the effect of substituent type connected to N-atom," Energy, Elsevier, vol. 144(C), pages 1064-1072.
    14. Zhang, Rui & Zhang, Xiaowen & Yang, Qi & Yu, Hai & Liang, Zhiwu & Luo, Xiao, 2017. "Analysis of the reduction of energy cost by using MEA-MDEA-PZ solvent for post-combustion carbon dioxide capture (PCC)," Applied Energy, Elsevier, vol. 205(C), pages 1002-1011.
    15. Pereira, Luís M.C. & Vega, Lourdes F., 2018. "A systematic approach for the thermodynamic modelling of CO2-amine absorption process using molecular-based models," Applied Energy, Elsevier, vol. 232(C), pages 273-291.
    16. Qi, Guojie & Liu, Kun & House, Alan & Salmon, Sonja & Ambedkar, Balraj & Frimpong, Reynolds A. & Remias, Joseph E. & Liu, Kunlei, 2018. "Laboratory to bench-scale evaluation of an integrated CO2 capture system using a thermostable carbonic anhydrase promoted K2CO3 solvent with low temperature vacuum stripping," Applied Energy, Elsevier, vol. 209(C), pages 180-189.
    17. Zhang, Xiaowen & Huang, Yufei & Gao, Hongxia & Luo, Xiao & Liang, Zhiwu & Tontiwachwuthikul, Paitoon, 2019. "Zeolite catalyst-aided tri-solvent blend amine regeneration: An alternative pathway to reduce the energy consumption in amine-based CO2 capture process," Applied Energy, Elsevier, vol. 240(C), pages 827-841.
    18. Song, Chunfeng & Liu, Qingling & Ji, Na & Deng, Shuai & Zhao, Jun & Kitamura, Yutaka, 2017. "Natural gas purification by heat pump assisted MEA absorption process," Applied Energy, Elsevier, vol. 204(C), pages 353-361.
    19. Wang, Xianfeng & Akhmedov, Novruz G. & Hopkinson, David & Hoffman, James & Duan, Yuhua & Egbebi, Adefemi & Resnik, Kevin & Li, Bingyun, 2016. "Phase change amino acid salt separates into CO2-rich and CO2-lean phases upon interacting with CO2," Applied Energy, Elsevier, vol. 161(C), pages 41-47.
    20. Xiao, Min & Zheng, Wenchao & Liu, Helei & Luo, Xiao & Gao, Hongxia & Liang, Zhiwu, 2021. "Thermodynamic analysis of carbamate formation and carbon dioxide absorption in N-methylaminoethanol solution," Applied Energy, Elsevier, vol. 281(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:218:y:2018:i:c:p:417-429. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.