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Enhancing CO2 desorption performance in rich MEA solution by addition of SO42−/ZrO2/SiO2 bifunctional catalyst

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  • Ali Saleh Bairq, Zain
  • Gao, Hongxia
  • Huang, Yufei
  • Zhang, Haiyan
  • Liang, Zhiwu

Abstract

A significant impediment to the widespread adoption of amine-based post-combustion technique for CO2 capture from flue gas is the huge energy demand for amine solvent regeneration. In this study, five novel bifunctional heterogeneous catalysts e.g., SO42−/ZrO2/SiO2 with different molar ratios of zirconia and SO42−/ZrO2 as a parent catalyst were synthesized and applied to evaluate their effectiveness in enhancing the CO2 desorption and solvent regeneration of 5M monoethanolamine solution with CO2 loading of 0.5 ± 0.01 mol CO2/mol monoethanolamine at 97 °C. The catalysts were characterized by Fourier transform-infrared spectrometry, pyridine-infrared spectroscopy, X-ray diffraction, N2-adsorption-desorption, and ammonia-temperature programmed desorption. The results demonstrated that these catalysts can significantly reduce the heat duty for CO2 desorption by 36.48% compared to without catalyst and enhance desorption rate by 35.1%. The results also showed that SO42−/ZrO2/SiO215% presented the highest efficiency compared to the other SO42−/ZrO2/SiO2 ratios and the super solid acid catalyst SO42−/ZrO2. Additionally, to investigate if the catalysts induce any unfavorable effects on the amine, the absorption of CO2 by regenerated amine solvent was studied. Finally, a reaction mechanism for the amine solvent regeneration with the synthesized catalyst e.g., SO42−/ZrO2/SiO2 was suggested.

Suggested Citation

  • Ali Saleh Bairq, Zain & Gao, Hongxia & Huang, Yufei & Zhang, Haiyan & Liang, Zhiwu, 2019. "Enhancing CO2 desorption performance in rich MEA solution by addition of SO42−/ZrO2/SiO2 bifunctional catalyst," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    • Handle: RePEc:eee:appene:v:252:y:2019:i:c:12
    DOI: 10.1016/j.apenergy.2019.113440
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    Cited by:

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    3. Siti Aishah Mohd Rozaiddin & Kok Keong Lau, 2022. "A Review on Enhancing Solvent Regeneration in CO 2 Absorption Process Using Nanoparticles," Sustainability, MDPI, vol. 14(8), pages 1-33, April.
    4. Kim, Dongin & Han, Jeehoon, 2020. "Techno-economic and climate impact analysis of carbon utilization process for methanol production from blast furnace gas over Cu/ZnO/Al2O3 catalyst," Energy, Elsevier, vol. 198(C).
    5. Guo, Jian & Zhong, Minghao & Chen, Shuran, 2022. "Analysis and simulation of BECCS vertical integration model in China based on evolutionary game and system dynamics," Energy, Elsevier, vol. 252(C).
    6. Chen, Jianan & Huang, Zhu, 2022. "Spontaneous condensation of carbon dioxide in flue gas at supersonic state," Energy, Elsevier, vol. 254(PC).

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