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Recent Advancements in Pd-Based Membranes for Hydrogen Separation

Author

Listed:
  • Nadia Cerone

    (Energy Technologies and Renewable Sources Department, ENEA, ss Ionica 106, 75026 Rotondella, Italy)

  • Giuseppe Domenico Zito

    (Department of Mechanics, Mathematics and Management, Polytechnic University of Bari, Via Orabona 4, 70125 Bari, Italy)

  • Carmine Florio

    (Energy Technologies and Renewable Sources Department, ENEA, ss Ionica 106, 75026 Rotondella, Italy)

  • Laura Fabbiano

    (Department of Mechanics, Mathematics and Management, Polytechnic University of Bari, Via Orabona 4, 70125 Bari, Italy)

  • Francesco Zimbardi

    (Energy Technologies and Renewable Sources Department, ENEA, ss Ionica 106, 75026 Rotondella, Italy)

Abstract

The use of hydrogen is pivotal for the energy and industrial transition in order to mitigate the effects of climate change. As technologies like fuel cells, e-fuels, and the semiconductor industry increasingly demand pure hydrogen, the development of efficient separation methods is crucial. While traditional methods such as pressure-swing adsorption are common, palladium (Pd)-based membranes are a promising alternative due to their energetic efficiency. This review summarizes the recent advances in Pd-based membranes for hydrogen separation over the last six years. It provides a theoretical overview of hydrogen permeation through membranes and examine the characteristics of various Pd alloys adopted in membrane fabrication, discussing the advantages and disadvantages of binary and ternary alloys, for different membrane types, including self-supported and supported membranes, as well as the role of intermediate layers. Additionally, the membrane characteristics used in some recent works on self-supported and supported Pd membranes are analyzed, focusing on operational parameters like permeability, selectivity, and durability. Finally, this review emphasizes the significant progress made in enhancing membrane performance and discusses future directions for industrial applications.

Suggested Citation

  • Nadia Cerone & Giuseppe Domenico Zito & Carmine Florio & Laura Fabbiano & Francesco Zimbardi, 2024. "Recent Advancements in Pd-Based Membranes for Hydrogen Separation," Energies, MDPI, vol. 17(16), pages 1-15, August.
    • Handle: RePEc:gam:jeners:v:17:y:2024:i:16:p:4095-:d:1458491
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    References listed on IDEAS

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    1. Chen, Wei-Hsin & Chen, Chia-Yang, 2020. "Water gas shift reaction for hydrogen production and carbon dioxide capture: A review," Applied Energy, Elsevier, vol. 258(C).
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    1. Omidifar, Mina & Babaluo, Ali Akbar, 2025. "Fabrication of the composite Pd-Ag-Ni membrane by the electroless plating technique for H2 purification," Renewable Energy, Elsevier, vol. 243(C).

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