IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i15p5639-d879533.html
   My bibliography  Save this article

Feasibility of Thermal Utilization of Primary and Secondary Sludge from a Biological Wastewater Treatment Plant in Kaliningrad City

Author

Listed:
  • Yuliya Kulikova

    (Institute of Living Systems, Immanuel Kant BFU, 236041 Kaliningrad, Russia)

  • Olga Babich

    (Institute of Living Systems, Immanuel Kant BFU, 236041 Kaliningrad, Russia)

  • Anna Tsybina

    (Environmental Protection Department, Perm National Research Polytechnic University, 614000 Perm, Russia)

  • Stanislav Sukhikh

    (Institute of Living Systems, Immanuel Kant BFU, 236041 Kaliningrad, Russia)

  • Ivan Mokrushin

    (Department of Inorganic Chemistry, Chemical Technology and Technosphere Safety of Perm State National Research University, 614990 Perm, Russia)

  • Svetlana Noskova

    (Institute of Living Systems, Immanuel Kant BFU, 236041 Kaliningrad, Russia)

  • Nikolaj Orlov

    (Institute of Living Systems, Immanuel Kant BFU, 236041 Kaliningrad, Russia)

Abstract

Hydrothermal liquefaction (HTL) of sewage sludge is considered in the article as an analogue of the natural processes of oil formation (catagenesis). A comparison of the physicochemical composition of primary and secondary sludge with type II kerogen (natural precursor of oil) showed their similarity. Both types of sludge have a slightly higher level of oxygen and nitrogen. The study tested the hypothesis that the elements included in the inorganic part of the oil source rocks can have a catalytic effect on the oil formation processes. For the conducted studies of sludge HTL, the catalysts containing cations and substances found in oil source rocks were chosen: as homogeneous catalysts (KOH, NaOH, NH 4 Fe(SO 4 ) 2 , CoCl 6 , NiSO 4 , CuSO 4 , ZnSO 4 , MoO 3 ) and as heterogeneous catalysts (MgO, Zeolite, Al 2 O 3 ). The effectiveness of catalysts containing metal ions, zeolite and aluminum oxide has been proven. The highest biocrude yield was achieved in a process with NiSO 4 as the catalyst in a dose 2 g per 10 g of sludge: oil yield increased by 34.9% and 63.4% in the processing of primary and secondary sludge, respectively. The use of catalysts provided an increase in fuel HHV by 10.8–12.5%, which is associated with a decrease in oxygen content (by 10.8–43.2%) with a simultaneous increase in carbon (by 7.9–10.9%) and hydrogen (by 6.5–18.7%) content.

Suggested Citation

  • Yuliya Kulikova & Olga Babich & Anna Tsybina & Stanislav Sukhikh & Ivan Mokrushin & Svetlana Noskova & Nikolaj Orlov, 2022. "Feasibility of Thermal Utilization of Primary and Secondary Sludge from a Biological Wastewater Treatment Plant in Kaliningrad City," Energies, MDPI, vol. 15(15), pages 1-14, August.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:15:p:5639-:d:879533
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/15/5639/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/15/5639/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Oladejo, Jumoke M. & Adegbite, Stephen & Pang, Cheng Heng & Liu, Hao & Parvez, Ashak M. & Wu, Tao, 2017. "A novel index for the study of synergistic effects during the co-processing of coal and biomass," Applied Energy, Elsevier, vol. 188(C), pages 215-225.
    2. Xu, Donghai & Lin, Guike & Liu, Liang & Wang, Yang & Jing, Zefeng & Wang, Shuzhong, 2018. "Comprehensive evaluation on product characteristics of fast hydrothermal liquefaction of sewage sludge at different temperatures," Energy, Elsevier, vol. 159(C), pages 686-695.
    3. Ayaz A. Shah & Saqib S. Toor & Tahir H. Seehar & Rasmus S. Nielsen & Asbjørn H. Nielsen & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Bio-Crude Production through Aqueous Phase Recycling of Hydrothermal Liquefaction of Sewage Sludge," Energies, MDPI, vol. 13(2), pages 1-18, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yuliya Kulikova & Marina Krasnovskikh & Natalia Sliusar & Nikolay Orlov & Olga Babich, 2023. "Analysis and Comparison of Bio-Oils Obtained by Hydrothermal Liquefaction of Organic Waste," Sustainability, MDPI, vol. 15(2), pages 1-17, January.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ayaz Ali Shah & Saqib Sohail Toor & Asbjørn Haaning Nielsen & Thomas Helmer Pedersen & Lasse Aistrup Rosendahl, 2021. "Bio-Crude Production through Recycling of Pretreated Aqueous Phase via Activated Carbon," Energies, MDPI, vol. 14(12), pages 1-20, June.
    2. Yuliya Kulikova & Marina Krasnovskikh & Natalia Sliusar & Nikolay Orlov & Olga Babich, 2023. "Analysis and Comparison of Bio-Oils Obtained by Hydrothermal Liquefaction of Organic Waste," Sustainability, MDPI, vol. 15(2), pages 1-17, January.
    3. Chen, Lichun & Wen, Chang & Wang, Wenyu & Liu, Tianyu & Liu, Enze & Liu, Haowen & Li, Zexin, 2020. "Combustion behaviour of biochars thermally pretreated via torrefaction, slow pyrolysis, or hydrothermal carbonisation and co-fired with pulverised coal," Renewable Energy, Elsevier, vol. 161(C), pages 867-877.
    4. Tahir H. Seehar & Saqib S. Toor & Ayaz A. Shah & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Biocrude Production from Wheat Straw at Sub and Supercritical Hydrothermal Liquefaction," Energies, MDPI, vol. 13(12), pages 1-18, June.
    5. Shi, Kaiqi & Oladejo, Jumoke Mojisola & Yan, Jiefeng & Wu, Tao, 2019. "Investigation on the interactions among lignocellulosic constituents and minerals of biomass and their influences on co-firing," Energy, Elsevier, vol. 179(C), pages 129-137.
    6. Xu, Zhi-Xiang & Song, Hao & Zhang, Shu & Tong, Si-Qi & He, Zhi-Xia & Wang, Qian & Li, Bin & Hu, Xun, 2019. "Co-hydrothermal carbonization of digested sewage sludge and cow dung biogas residue: Investigation of the reaction characteristics," Energy, Elsevier, vol. 187(C).
    7. Inayat, Muddasser & Sulaiman, Shaharin A. & Kurnia, Jundika Candra & Shahbaz, Muhammad, 2019. "Effect of various blended fuels on syngas quality and performance in catalytic co-gasification: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 252-267.
    8. Prestigiacomo, Claudia & Proietto, Federica & Laudicina, Vito Armando & Siragusa, Angelo & Scialdone, Onofrio & Galia, Alessandro, 2021. "Catalytic hydrothermal liquefaction of municipal sludge assisted by formic acid for the production of next-generation fuels," Energy, Elsevier, vol. 232(C).
    9. Liu, Xuan & Burra, Kiran G. & Wang, Zhiwei & Li, Jinhu & Che, Defu & Gupta, Ashwani K., 2020. "On deconvolution for understanding synergistic effects in co-pyrolysis of pinewood and polypropylene," Applied Energy, Elsevier, vol. 279(C).
    10. Kamaldeep Sharma & Ayaz A. Shah & Saqib S. Toor & Tahir H. Seehar & Thomas H. Pedersen & Lasse A. Rosendahl, 2021. "Co-Hydrothermal Liquefaction of Lignocellulosic Biomass in Supercritical Water," Energies, MDPI, vol. 14(6), pages 1-13, March.
    11. Zhao, Kaige & Li, Wanqing & Yu, Yingying & Chen, Guanyi & Yan, Beibei & Cheng, Zhanjun & Zhao, Hai & Fang, Yang, 2023. "Speciation and transformation of nitrogen in the hydrothermal liquefaction of wastewater-treated duckweed for the bio-oil production," Renewable Energy, Elsevier, vol. 204(C), pages 661-670.
    12. Xu, Donghai & Wang, Yang & Lin, Guike & Guo, Shuwei & Wang, Shuzhong & Wu, Zhiqiang, 2019. "Co-hydrothermal liquefaction of microalgae and sewage sludge in subcritical water: Ash effects on bio-oil production," Renewable Energy, Elsevier, vol. 138(C), pages 1143-1151.
    13. Qian, Lili & Wang, Shuzhong & Savage, Phillip E., 2020. "Fast and isothermal hydrothermal liquefaction of sludge at different severities: Reaction products, pathways, and kinetics," Applied Energy, Elsevier, vol. 260(C).
    14. Ayaz A. Shah & Saqib S. Toor & Tahir H. Seehar & Rasmus S. Nielsen & Asbjørn H. Nielsen & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Bio-Crude Production through Aqueous Phase Recycling of Hydrothermal Liquefaction of Sewage Sludge," Energies, MDPI, vol. 13(2), pages 1-18, January.
    15. Guo, Feiqiang & Li, Xiaolei & Wang, Yan & Liu, Yuan & Li, Tiantao & Guo, Chenglong, 2017. "Characterization of Zhundong lignite and biomass co-pyrolysis in a thermogravimetric analyzer and a fixed bed reactor," Energy, Elsevier, vol. 141(C), pages 2154-2163.
    16. Oladejo, Jumoke & Adegbite, Stephen & Gao, Xiang & Liu, Hao & Wu, Tao, 2018. "Catalytic and non-catalytic synergistic effects and their individual contributions to improved combustion performance of coal/biomass blends," Applied Energy, Elsevier, vol. 211(C), pages 334-345.
    17. Ling Du & Hasan Dinçer & İrfan Ersin & Serhat Yüksel, 2020. "IT2 Fuzzy-Based Multidimensional Evaluation of Coal Energy for Sustainable Economic Development," Energies, MDPI, vol. 13(10), pages 1-21, May.
    18. Barbanera, M. & Cotana, F. & Di Matteo, U., 2018. "Co-combustion performance and kinetic study of solid digestate with gasification biochar," Renewable Energy, Elsevier, vol. 121(C), pages 597-605.
    19. Xie, Candie & Liu, Jingyong & Xie, Wuming & Kuo, Jiahong & Lu, Xingwen & Zhang, Xiaochun & He, Yao & Sun, Jian & Chang, Kenlin & Xie, Wenhao & Liu, Chao & Sun, Shuiyu & Buyukada, Musa & Evrendilek, Fa, 2018. "Quantifying thermal decomposition regimes of textile dyeing sludge, pomelo peel, and their blends," Renewable Energy, Elsevier, vol. 122(C), pages 55-64.
    20. Prestigiacomo, Claudia & Laudicina, Vito Armando & Siragusa, Angelo & Scialdone, Onofrio & Galia, Alessandro, 2020. "Hydrothermal liquefaction of waste biomass in stirred reactors: One step forward to the integral valorization of municipal sludge," Energy, Elsevier, vol. 201(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:15:p:5639-:d:879533. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.