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Influence of Densification on the Pyrolytic Behavior of Agricultural Biomass Waste and the Characteristics of Pyrolysis Products

Author

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  • Marcin Bielecki

    (The Institute of Chemistry, Jan Kochanowski University in Kielce, Uniwersytecka Str. 7, 25-406 Kielce, Poland)

  • Valentina Zubkova

    (The Institute of Chemistry, Jan Kochanowski University in Kielce, Uniwersytecka Str. 7, 25-406 Kielce, Poland)

  • Andrzej Strojwas

    (The Institute of Chemistry, Jan Kochanowski University in Kielce, Uniwersytecka Str. 7, 25-406 Kielce, Poland)

Abstract

TG/FT-IR techniques, UV-spectroscopy, microwave extraction, XRD and SEM were used to study how densification of the three types of agricultural biomass wastes (wheat straw, soft wood, and sunflower husk) changes the composition and structure of their pyrolysis products. It was determined that densification changes the composition of volatile products of pyrolysis at the temperature of 420 °C: sunflower husk emits 4.9 times less saturated and unsaturated hydrocarbons and 1.9 times less compounds with carbonyl group; soft wood emits 1.8 times more saturated and unsaturated hydrocarbons and compounds with carbonyl groups and 1.3 times more alcohols and phenols; and wheat straw emits 2 times more compounds with carbonyl groups. These changes are probably caused by the differences in interaction of formed volatiles with the surface of chars. These differences can be caused by distinct places of cumulation of inorganic components in the densified samples. In the densified char, the inorganics cumulate on the surface of sunflower husk whereas for wheat straw they cumulate inside the sample. In the case of soft wood, the inorganics cumulate both inside and on the surface. The decreased contribution of hydrocarbons in volatiles can be connected with the morphology of nano-particles formed in inorganics.

Suggested Citation

  • Marcin Bielecki & Valentina Zubkova & Andrzej Strojwas, 2022. "Influence of Densification on the Pyrolytic Behavior of Agricultural Biomass Waste and the Characteristics of Pyrolysis Products," Energies, MDPI, vol. 15(12), pages 1-20, June.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:12:p:4257-:d:835369
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    References listed on IDEAS

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    1. Marcin Bielecki & Valentina Zubkova & Andrzej Strojwas, 2023. "An Analysis of the Influence of Low Density Polyethylene, Novolac, and Coal Tar Pitch Additives on the Decrease in Content of Impurities Emitted from Densified Pea Husks during the Process of Their Py," Energies, MDPI, vol. 16(6), pages 1-16, March.
    2. Euripedes Garcia Silveira Junior & Victor Haber Perez & Solciaray Cardoso Soares Estefan de Paula & Thays da Costa Silveira & Fabio Lopes Olivares & Oselys Rodriguez Justo, 2023. "Coffee Husks Valorization for Levoglucosan Production and Other Pyrolytic Products through Thermochemical Conversion by Fast Pyrolysis," Energies, MDPI, vol. 16(6), pages 1-23, March.

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