IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i6p2835-d1101041.html
   My bibliography  Save this article

Coffee Husks Valorization for Levoglucosan Production and Other Pyrolytic Products through Thermochemical Conversion by Fast Pyrolysis

Author

Listed:
  • Euripedes Garcia Silveira Junior

    (Center of Sciences and Agricultural Technologies (CCTA), State University of Northern of Rio de Janeiro, Campos dos Goytacazes 28013-602, RJ, Brazil)

  • Victor Haber Perez

    (Center of Sciences and Agricultural Technologies (CCTA), State University of Northern of Rio de Janeiro, Campos dos Goytacazes 28013-602, RJ, Brazil)

  • Solciaray Cardoso Soares Estefan de Paula

    (Center of Sciences and Agricultural Technologies (CCTA), State University of Northern of Rio de Janeiro, Campos dos Goytacazes 28013-602, RJ, Brazil)

  • Thays da Costa Silveira

    (Center of Sciences and Agricultural Technologies (CCTA), State University of Northern of Rio de Janeiro, Campos dos Goytacazes 28013-602, RJ, Brazil)

  • Fabio Lopes Olivares

    (Bioscience and Biotechnology Center (CBB), State University of Northern of Rio de Janeiro, Campos dos Goytacazes 28013-602, RJ, Brazil)

  • Oselys Rodriguez Justo

    (Industrial Engineering School, Estácio de Sá University, Campos dos Goytacazes 28020-740, RJ, Brazil)

Abstract

Levoglucosan is an anhydrosugar from biomass that has important applications as a platform for obtaining many value-added derivatives with high demand in the chemical industry and bioproducts by fermentation, including biofuels, among others. Thus, the experimental strategy was to intensify the levoglucosan production in the condensable fraction (bio-oil) from pyrolysis gases using different biomass pretreatments before fast pyrolysis according to the following conditions: (a) biomass washing with 10% acetic acid; (b) biomass washing with 0.1% HNO 3 , followed by impregnation with 0.1% H 2 SO 4 ; and (c) biomass impregnation with 0.1% H 2 SO 4 . The pyrolysis was carried out in a pyroprobe reactor, coupled to GC/MS to verify the progress of the chemicals formed at 400, 500, and 600 °C. Although levoglucosan was the main target, the programs showed more than 200 pyrolytic compounds of which more than 40 were identified, including organic acids, ketones, aldehydes, furans, and phenols. Then, principal component analysis (PCA) allowed for the discrimination of the simultaneous effect of biomass acid treatment and pyrolysis temperature on the formation of the pyrolytic products. All treated biomasses with acids resulted in a levoglucosan yield increase, but the best result was achieved with acetic acid at 500 °C which resulted from 7-fold higher levoglucosan production with changes in the profiles by-products formed concerning untreated biomass. This result was attributed to the alkali and alkaline earth metals reduction and partial removal of lignin content and extractives by acid washing, increasing the cellulose and hemicellulose relative content in the treated biomass. This hypothesis was also confirmed by scanning electron microscope (SEM) and Fourier transform infrared (FTIR) qualitative analysis. Thus, the results achieved in this work show the potential of this biomass for levoglucosan production and other pyrolytic products, thereby being able to mitigate the environmental impact of this agricultural residue and contribute to the development of the coffee agro-industrial chain and the production of bioenergy from lignocellulosic biomass.

Suggested Citation

  • Euripedes Garcia Silveira Junior & Victor Haber Perez & Solciaray Cardoso Soares Estefan de Paula & Thays da Costa Silveira & Fabio Lopes Olivares & Oselys Rodriguez Justo, 2023. "Coffee Husks Valorization for Levoglucosan Production and Other Pyrolytic Products through Thermochemical Conversion by Fast Pyrolysis," Energies, MDPI, vol. 16(6), pages 1-23, March.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:6:p:2835-:d:1101041
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/6/2835/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/16/6/2835/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Marcin Bielecki & Valentina Zubkova & Andrzej Strojwas, 2022. "Influence of Densification on the Pyrolytic Behavior of Agricultural Biomass Waste and the Characteristics of Pyrolysis Products," Energies, MDPI, vol. 15(12), pages 1-20, June.
    2. Cassie Marie Welker & Vimal Kumar Balasubramanian & Carloalberto Petti & Krishan Mohan Rai & Seth DeBolt & Venugopal Mendu, 2015. "Engineering Plant Biomass Lignin Content and Composition for Biofuels and Bioproducts," Energies, MDPI, vol. 8(8), pages 1-23, July.
    3. Lubwama, Michael & Yiga, Vianney Andrew, 2018. "Characteristics of briquettes developed from rice and coffee husks for domestic cooking applications in Uganda," Renewable Energy, Elsevier, vol. 118(C), pages 43-55.
    4. Lubwama, Michael & Yiga, Vianney Andrew & Muhairwe, Frank & Kihedu, Joseph, 2020. "Physical and combustion properties of agricultural residue bio-char bio-composite briquettes as sustainable domestic energy sources," Renewable Energy, Elsevier, vol. 148(C), pages 1002-1016.
    5. Setter, C. & Oliveira, T.J.P., 2022. "Evaluation of the physical-mechanical and energy properties of coffee husk briquettes with kraft lignin during slow pyrolysis," Renewable Energy, Elsevier, vol. 189(C), pages 1007-1019.
    6. Dal-Bó, Vanessa & Lira, Taisa & Arrieche, Leonardo & Bacelos, Marcelo, 2019. "Process synthesis for coffee husks to energy using hierarchical approaches," Renewable Energy, Elsevier, vol. 142(C), pages 195-206.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Okey Francis Obi & Ralf Pecenka & Michael J. Clifford, 2022. "A Review of Biomass Briquette Binders and Quality Parameters," Energies, MDPI, vol. 15(7), pages 1-22, March.
    2. Kipngetich, P. & Kiplimo, R. & Tanui, J.K. & Chisale, P.C., 2022. "Optimization of combustion parameters of carbonized rice husk briquettes in a fixed bed using RSM technique," Renewable Energy, Elsevier, vol. 198(C), pages 61-74.
    3. Work, James & Hauer, Grant & Luckert, M.K. (Marty), 2018. "What ethanol prices would induce growers to switch from agriculture to poplar in Alberta? A multiple options approach," Journal of Forest Economics, Elsevier, vol. 33(C), pages 51-62.
    4. Czekała, Wojciech & Łukomska, Aleksandra & Pulka, Jakub & Bojarski, Wiktor & Pochwatka, Patrycja & Kowalczyk-Juśko, Alina & Oniszczuk, Anna & Dach, Jacek, 2023. "Waste-to-energy: Biogas potential of waste from coffee production and consumption," Energy, Elsevier, vol. 276(C).
    5. Arkadiusz Dyjakon & Tomasz Noszczyk, 2019. "The Influence of Freezing Temperature Storage on the Mechanical Durability of Commercial Pellets from Biomass," Energies, MDPI, vol. 12(13), pages 1-13, July.
    6. Cardarelli, Alessandro & Pinzi, Sara & Barbanera, Marco, 2022. "Effect of torrefaction temperature on spent coffee grounds thermal behaviour and kinetics," Renewable Energy, Elsevier, vol. 185(C), pages 704-716.
    7. Marcin Bielecki & Valentina Zubkova & Andrzej Strojwas, 2023. "An Analysis of the Influence of Low Density Polyethylene, Novolac, and Coal Tar Pitch Additives on the Decrease in Content of Impurities Emitted from Densified Pea Husks during the Process of Their Py," Energies, MDPI, vol. 16(6), pages 1-16, March.
    8. Lacrimioara Senila & Ioan Tenu & Petru Carlescu & Daniela Alexandra Scurtu & Eniko Kovacs & Marin Senila & Oana Cadar & Marius Roman & Diana Elena Dumitras & Cecilia Roman, 2022. "Characterization of Biobriquettes Produced from Vineyard Wastes as a Solid Biofuel Resource," Agriculture, MDPI, vol. 12(3), pages 1-13, February.
    9. Kasmuri, N.H. & Kamarudin, S.K. & Abdullah, S.R.S. & Hasan, H.A. & Som, A.Md., 2017. "Process system engineering aspect of bio-alcohol fuel production from biomass via pyrolysis: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 914-923.
    10. Phisamas Hwangdee & Singrun Charee & Watcharin Kheowkrai & Chaiyan Junsiri & Kittipong Laloon, 2022. "Application of the Simplex-Centroid Mixture Design to Biomass Charcoal Powder Formulation Ratio for Biomass Charcoal Briquettes," Sustainability, MDPI, vol. 14(7), pages 1-15, March.
    11. Tiziana Maria Sirangelo & Richard Andrew Ludlow & Tatiana Chenet & Luisa Pasti & Natasha Damiana Spadafora, 2023. "Multi-Omics and Genome Editing Studies on Plant Cell Walls to Improve Biomass Quality," Agriculture, MDPI, vol. 13(4), pages 1-19, March.
    12. Alkasrawi, Malek & Al-Othman, Amani & Tawalbeh, Muhammad & Doncan, Shona & Gurram, Raghu & Singsaas, Eric & Almomani, Fares & Al-Asheh, Sameer, 2021. "A novel technique of paper mill sludge conversion to bioethanol toward sustainable energy production: Effect of fiber recovery on the saccharification hydrolysis and fermentation," Energy, Elsevier, vol. 223(C).
    13. Li Ji & Pengfei Li & Fuhou Lei & Xianliang Song & Jianxin Jiang & Kun Wang, 2020. "Coproduction of Furfural, Phenolated Lignin and Fermentable Sugars from Bamboo with One-Pot Fractionation Using Phenol-Acidic 1,4-Dioxane," Energies, MDPI, vol. 13(20), pages 1-17, October.
    14. Sunday Yusuf Kpalo & Mohamad Faiz Zainuddin & Latifah Abd Manaf & Ahmad Muhaimin Roslan & Nik Nor Rahimah Nik Ab Rahim, 2022. "Techno-Economic Viability Assessment of a Household Scale Agricultural Residue Composite Briquette Project for Rural Communities in Nigeria," Sustainability, MDPI, vol. 14(15), pages 1-19, August.
    15. Wang, Dongji & Liu, Liansheng & Yuan, Ye & Yang, Hua & Zhou, Yixing & Duan, Ruanze, 2020. "Design and key heating power parameters of a newly-developed household biomass briquette heating boiler," Renewable Energy, Elsevier, vol. 147(P1), pages 1371-1379.
    16. Marek Wróbel & Marcin Jewiarz & Krzysztof Mudryk & Adrian Knapczyk, 2020. "Influence of Raw Material Drying Temperature on the Scots Pine ( Pinus sylvestris L.) Biomass Agglomeration Process—A Preliminary Study," Energies, MDPI, vol. 13(7), pages 1-17, April.
    17. Cai, Junmeng & He, Yifeng & Yu, Xi & Banks, Scott W. & Yang, Yang & Zhang, Xingguang & Yu, Yang & Liu, Ronghou & Bridgwater, Anthony V., 2017. "Review of physicochemical properties and analytical characterization of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 309-322.
    18. Dal-Bó, Vanessa & Lira, Taisa & Arrieche, Leonardo & Bacelos, Marcelo, 2019. "Process synthesis for coffee husks to energy using hierarchical approaches," Renewable Energy, Elsevier, vol. 142(C), pages 195-206.
    19. Ishtiaq Ahmed & Muhammad Anjum Zia & Huma Afzal & Shaheez Ahmed & Muhammad Ahmad & Zain Akram & Farooq Sher & Hafiz M. N. Iqbal, 2021. "Socio-Economic and Environmental Impacts of Biomass Valorisation: A Strategic Drive for Sustainable Bioeconomy," Sustainability, MDPI, vol. 13(8), pages 1-32, April.
    20. Song, Biao & Almatrafi, Eydhah & Tan, Xiaofei & Luo, Songhao & Xiong, Weiping & Zhou, Chengyun & Qin, Meng & Liu, Yang & Cheng, Min & Zeng, Guangming & Gong, Jilai, 2022. "Biochar-based agricultural soil management: An application-dependent strategy for contributing to carbon neutrality," Renewable and Sustainable Energy Reviews, Elsevier, vol. 164(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:6:p:2835-:d:1101041. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.