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An All-Solid-State Lithium Metal Battery Based on Electrodes-Compatible Plastic Crystal Electrolyte

Author

Listed:
  • Bin Zhao

    (State Key Laboratory of Electrical Insulation and Power Equipment, School of Electrical Engineering, Xi’an Jiaotong University, Xi’an 710049, China
    B.Z. and Q.W. contributed equally to this work.)

  • Qi Wang

    (State Key Laboratory of Electrical Insulation and Power Equipment, School of Electrical Engineering, Xi’an Jiaotong University, Xi’an 710049, China
    B.Z. and Q.W. contributed equally to this work.)

  • Boheng Yuan

    (State Key Laboratory of Electrical Insulation and Power Equipment, School of Electrical Engineering, Xi’an Jiaotong University, Xi’an 710049, China)

  • Yafei Lu

    (State Key Laboratory of Electrical Insulation and Power Equipment, School of Electrical Engineering, Xi’an Jiaotong University, Xi’an 710049, China)

  • Xiaogang Han

    (State Key Laboratory of Electrical Insulation and Power Equipment, School of Electrical Engineering, Xi’an Jiaotong University, Xi’an 710049, China
    Key Laboratory of Smart Grid of Shanxi Province, Xi’an 710049, China)

Abstract

Solid-state plastic crystal electrolytes (SPCEs) have attracted much attention due to their high ionic conductivity at room temperature and polymer-like plasticity. Herein, we made a LiFePO 4 ||Li solid state battery based on SPCEs. A SPCE film is made up of glass fiber, succinonitrile (SN), lithium bis (triflu-romethanesulphonyl) imid (LiTFSI), and LiNO 3 . Glass fiber is introduced to improve the mechanical property, and LiNO 3 served as an additive to stabilize electrolyte/Li interface. The SPCE film delivers a high ionic conductivity of 7.3 × 10 −4 S cm −1 at room temperature and has excellent stability with Li-metal anode. SPCE is also infused into cathode electrode and used as the interface with cathode particles, which can access a large interface contact area and deform reversibly with volume change. The LiFePO 4 ||Li solid state battery based on SPCE can work well at ambient temperature, which shows a high initial specific capacity of 121.4 mAh g −1 and has 86.9% retention after 90 cycles at 0.5 C.

Suggested Citation

  • Bin Zhao & Qi Wang & Boheng Yuan & Yafei Lu & Xiaogang Han, 2021. "An All-Solid-State Lithium Metal Battery Based on Electrodes-Compatible Plastic Crystal Electrolyte," Energies, MDPI, vol. 14(21), pages 1-9, October.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:21:p:6946-:d:662197
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    References listed on IDEAS

    as
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