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Comparative Study on Chemical Kinetics Mechanisms for Methane-Based Fuel Mixtures under Engine-Relevant Conditions

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  • Amin Paykani

    (School of Physics, Engineering and Computer Science, University of Hertfordshire, Hatfield AL10 9AB, UK)

Abstract

The use of natural gas in pure or in a blended form with hydrogen and syngas in spark ignition (SI) engines has received much attention in recent years. They have higher diffusion coefficient and laminar flame speed, a small quenching distance and wider flammability limit which compensate the demerits of the lean-burn natural gas combustion. Therefore, a careful examination of the chemical kinetics of combustion of gaseous fuel blends is of great importance. In this paper, performance of the various chemical kinetics mechanisms is compared against experimental data, accumulated for methane-based fuel blends under engine-relevant conditions to find the most appropriate mechanism in engine simulations. Pure methane, methane/syngas, and methane/propane blends are mainly studied at various temperatures, pressures, and equivalence ratios. The ignition delay time and laminar flame speed are used as quantitative metrics to compare the simulation results with the data from experiments. The mechanisms were shown to be mainly consistent with the experimental data of lean and stoichiometric mixtures at high pressures. It was also shown that the GRI-3.0 and 290Rxn mechanisms have high compatibility with the ignition delay times and laminar flame speed at high pressures and lean conditions, and they can be utilized for simulations of SI engine combustion due to their lower computational cost. The results of present research provide an important contribution to the methane-based fuel blends combustion simulation under SI engine-relevant conditions.

Suggested Citation

  • Amin Paykani, 2021. "Comparative Study on Chemical Kinetics Mechanisms for Methane-Based Fuel Mixtures under Engine-Relevant Conditions," Energies, MDPI, vol. 14(10), pages 1-15, May.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:10:p:2834-:d:554894
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    References listed on IDEAS

    as
    1. Sebastian Schuh & Ajoy Kumar Ramalingam & Heiko Minwegen & Karl Alexander Heufer & Franz Winter, 2019. "Experimental Investigation and Benchmark Study of Oxidation of Methane–Propane–n-Heptane Mixtures at Pressures up to 100 bar," Energies, MDPI, vol. 12(18), pages 1-20, September.
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    3. Paykani, Amin & Frouzakis, Christos E. & Boulouchos, Konstantinos, 2019. "Numerical optimization of methane-based fuel blends under engine-relevant conditions using a multi-objective genetic algorithm," Applied Energy, Elsevier, vol. 242(C), pages 1712-1724.
    4. Hagos, Ftwi Yohaness & A. Aziz, A. Rashid & Sulaiman, Shaharin A., 2015. "Methane enrichment of syngas (H2/CO) in a spark-ignition direct-injection engine: Combustion, performance and emissions comparison with syngas and Compressed Natural Gas," Energy, Elsevier, vol. 90(P2), pages 2006-2015.
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