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Treatment of Liquid By-Products of Hydrothermal Carbonization (HTC) of Agricultural Digestate Using Membrane Separation

Author

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  • Agnieszka Urbanowska

    (Faculty of Environmental Engineering, Chair in Water and Wastewater Treatment Technology, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Małgorzata Kabsch-Korbutowicz

    (Faculty of Environmental Engineering, Chair in Water and Wastewater Treatment Technology, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Mateusz Wnukowski

    (Faculty of Mechanical and Power Engineering, Department of Boilers, Combustion and Energy Systems, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Przemysław Seruga

    (Department of Bioprocess Engineering, Wroclaw University of Economics, Komandorska 118/120, 53-345 Wrocław, Poland
    Zakład Gospodarowania Odpadami GAĆ Sp. z o.o, Gać 90, 55-200 Oława, Poland)

  • Marcin Baranowski

    (Faculty of Mechanical and Power Engineering, Department of Boilers, Combustion and Energy Systems, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Halina Pawlak-Kruczek

    (Faculty of Mechanical and Power Engineering, Department of Boilers, Combustion and Energy Systems, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Monika Serafin-Tkaczuk

    (Faculty of Mechanical and Power Engineering, Department of Boilers, Combustion and Energy Systems, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Krystian Krochmalny

    (Faculty of Mechanical and Power Engineering, Department of Boilers, Combustion and Energy Systems, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

  • Lukasz Niedzwiecki

    (Faculty of Mechanical and Power Engineering, Department of Boilers, Combustion and Energy Systems, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland)

Abstract

Agriculture affects both the quantity and the quality of water available for other purposes, which becomes problematic, especially during increasingly frequent severe droughts. This requires tapping into the resources that are typically neglected. One such resource is a by-product of anaerobic digestion, in which moisture content typically exceeds 90%. Application of hydrothermal carbonization process (HTC) to this residue could partially remove organic and inorganic material, improve dewatering, decrease the overall solid mass, sanitize the digestate, change its properties, and eliminate problems related with emissions of odors from the installation. However, a significant gap still exists in terms of the dewatering of the hydrochars and the composition of the effluents. This work presents results of experimental investigation focused on the removal of organic compounds from the HTC effluent. Results of qualitative and quantitative analysis of liquid by-products of HTC of the agricultural digestate showed that acetic acid, 3-pyridinol, 1-hydroxyacetone, and 1,3-propanediol were the main liquid organic products of the process. Application of ultrafiltration process with the use of 10 kDa membrane for liquid HTC by-product treatment allows for the reduction of chemical oxygen demand up to 30%, biological oxygen demand up to 10%, and dissolved organic carbon up to 21%.

Suggested Citation

  • Agnieszka Urbanowska & Małgorzata Kabsch-Korbutowicz & Mateusz Wnukowski & Przemysław Seruga & Marcin Baranowski & Halina Pawlak-Kruczek & Monika Serafin-Tkaczuk & Krystian Krochmalny & Lukasz Niedzwi, 2020. "Treatment of Liquid By-Products of Hydrothermal Carbonization (HTC) of Agricultural Digestate Using Membrane Separation," Energies, MDPI, vol. 13(1), pages 1-12, January.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:1:p:262-:d:305307
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    References listed on IDEAS

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    Cited by:

    1. Krystian Krochmalny & Halina Pawlak-Kruczek & Norbert Skoczylas & Mateusz Kudasik & Aleksandra Gajda & Renata Gnatowska & Monika Serafin-Tkaczuk & Tomasz Czapka & Amit K. Jaiswal & Vishwajeet & Amit A, 2022. "Use of Hydrothermal Carbonization and Cold Atmospheric Plasma for Surface Modification of Brewer’s Spent Grain and Activated Carbon," Energies, MDPI, vol. 15(12), pages 1-11, June.
    2. Agnieszka Urbanowska & Małgorzata Kabsch-Korbutowicz & Christian Aragon-Briceño & Mateusz Wnukowski & Artur Pożarlik & Lukasz Niedzwiecki & Marcin Baranowski & Michał Czerep & Przemysław Seruga & Hali, 2021. "Cascade Membrane System for Separation of Water and Organics from Liquid By-Products of HTC of the Agricultural Digestate—Evaluation of Performance," Energies, MDPI, vol. 14(16), pages 1-18, August.
    3. Ajit Singh & Andrew Gill & David Lian Keong Lim & Agustina Kasmaruddin & Taghi Miri & Anita Chakrabarty & Hui Hui Chai & Anurita Selvarajoo & Festo Massawe & Yousif Abdalla Abakr & Kumbirai Ivyne Mate, 2022. "Feasibility of Bio-Coal Production from Hydrothermal Carbonization (HTC) Technology Using Food Waste in Malaysia," Sustainability, MDPI, vol. 14(8), pages 1-23, April.
    4. Malhotra, Milan & Aboudi, Kaoutar & Pisharody, Lakshmi & Singh, Ayush & Banu, J. Rajesh & Bhatia, Shashi Kant & Varjani, Sunita & Kumar, Sunil & González-Fernández, Cristina & Kumar, Sumant & Singh, R, 2022. "Biorefinery of anaerobic digestate in a circular bioeconomy: Opportunities, challenges and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    5. Louise Delahaye & John Thomas Hobson & Matthew Peter Rando & Brenna Sweeney & Avery Bernard Brown & Geoffrey Allen Tompsett & Ayten Ates & N. Aaron Deskins & Michael Thomas Timko, 2020. "Experimental and Computational Evaluation of Heavy Metal Cation Adsorption for Molecular Design of Hydrothermal Char," Energies, MDPI, vol. 13(16), pages 1-24, August.
    6. Urbanowska, Agnieszka & Niedzwiecki, Lukasz & Wnukowski, Mateusz & Aragon-Briceño, Christian & Kabsch-Korbutowicz, Małgorzata & Baranowski, Marcin & Czerep, Michał & Seruga, Przemysław & Pawlak-Krucze, 2023. "Recovery of chemical energy from retentates from cascade membrane filtration of hydrothermal carbonisation effluent," Energy, Elsevier, vol. 284(C).
    7. Agnieszka Urbanowska & Izabela Polowczyk & Małgorzata Kabsch-Korbutowicz & Przemysław Seruga, 2020. "Characteristics of Changes in Particle Size and Zeta Potential of the Digestate Fraction from the Municipal Waste Biogas Plant Treated with the Use of Chemical Coagulation/Precipitation Processes," Energies, MDPI, vol. 13(22), pages 1-12, November.
    8. Tiago Teribele & Maria Elizabeth Gemaque Costa & Conceição de Maria Sales da Silva & Lia Martins Pereira & Lucas Pinto Bernar & Douglas Alberto Rocha de Castro & Fernanda Paula da Costa Assunção & Mar, 2023. "Hydrothermal Carbonization of Corn Stover: Structural Evolution of Hydro-Char and Degradation Kinetics," Energies, MDPI, vol. 16(7), pages 1-22, April.
    9. Magdziarz, Aneta & Mlonka-Mędrala, Agata & Sieradzka, Małgorzata & Aragon-Briceño, Christian & Pożarlik, Artur & Bramer, Eddy A. & Brem, Gerrit & Niedzwiecki, Łukasz & Pawlak-Kruczek, Halina, 2021. "Multiphase analysis of hydrochars obtained by anaerobic digestion of municipal solid waste organic fraction," Renewable Energy, Elsevier, vol. 175(C), pages 108-118.
    10. Tadeáš Ochodek & Emmanouil Karampinis & Artur Pozarlik, 2022. "Contemporary Problems in Combustion—Fuels, Their Valorisation, Emissions, Flexibility and Auxiliary Systems," Energies, MDPI, vol. 15(5), pages 1-4, February.
    11. Agnieszka Urbanowska & Małgorzata Kabsch-Korbutowicz, 2021. "The Use of Flat Ceramic Membranes for Purification of the Liquid Fraction of the Digestate from Municipal Waste Biogas Plants," Energies, MDPI, vol. 14(13), pages 1-12, July.
    12. Aragón-Briceño, C.I. & Pozarlik, A.K. & Bramer, E.A. & Niedzwiecki, Lukasz & Pawlak-Kruczek, H. & Brem, G., 2021. "Hydrothermal carbonization of wet biomass from nitrogen and phosphorus approach: A review," Renewable Energy, Elsevier, vol. 171(C), pages 401-415.
    13. Sotirios D. Kalamaras & Georgios Vitoulis & Maria Lida Christou & Themistoklis Sfetsas & Spiridon Tziakas & Vassilios Fragos & Petros Samaras & Thomas A. Kotsopoulos, 2021. "The Effect of Ammonia Toxicity on Methane Production of a Full-Scale Biogas Plant—An Estimation Method," Energies, MDPI, vol. 14(16), pages 1-13, August.

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