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Carbon Dioxide Mixtures as Working Fluid for High-Temperature Heat Recovery: A Thermodynamic Comparison with Transcritical Organic Rankine Cycles

Author

Listed:
  • Abubakr Ayub

    (Department of Mechanical and Industrial Engineering, University of Brescia, via Branze, 38, 25123 Brescia, Italy)

  • Costante M. Invernizzi

    (Department of Mechanical and Industrial Engineering, University of Brescia, via Branze, 38, 25123 Brescia, Italy)

  • Gioele Di Marcoberardino

    (Department of Mechanical and Industrial Engineering, University of Brescia, via Branze, 38, 25123 Brescia, Italy)

  • Paolo Iora

    (Department of Mechanical and Industrial Engineering, University of Brescia, via Branze, 38, 25123 Brescia, Italy)

  • Giampaolo Manzolini

    (Energy Department, Politecnico di Milano, 20156 Milan, Italy)

Abstract

This study aims to provide a thermodynamic comparison between supercritical CO 2 cycles and ORC cycles utilizing flue gases as waste heat source. Moreover, the possibility of using CO 2 mixtures as working fluids in transcritical cycles to enhance the performance of the thermodynamic cycle is explored. ORCs operating with pure working fluids show higher cyclic thermal and total efficiencies compared to supercritical CO 2 cycles; thus, they represent a better option for high-temperature waste heat recovery provided that the thermal stability at a higher temperature has been assessed. Based on the improved global thermodynamic performance and good thermal stability of R134a, CO 2 -R134a is investigated as an illustrative, promising working fluid mixture for transcritical power cycles. The results show that a total efficiency of 0.1476 is obtained for the CO 2 -R134a mixture (0.3 mole fraction of R134a) at a maximum cycle pressure of 200 bars, which is 15.86% higher than the supercritical carbon dioxide cycle efficiency of 0.1274, obtained at the comparatively high maximum pressure of 300 bars. Steam cycles, owing to their larger number of required turbine stages and lower power output, did not prove to be a suitable option in this application.

Suggested Citation

  • Abubakr Ayub & Costante M. Invernizzi & Gioele Di Marcoberardino & Paolo Iora & Giampaolo Manzolini, 2020. "Carbon Dioxide Mixtures as Working Fluid for High-Temperature Heat Recovery: A Thermodynamic Comparison with Transcritical Organic Rankine Cycles," Energies, MDPI, vol. 13(15), pages 1-18, August.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:15:p:4014-:d:394217
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    References listed on IDEAS

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    1. Ziółkowski, Paweł & Badur, Janusz & Ziółkowski, Piotr Józef, 2019. "An energetic analysis of a gas turbine with regenerative heating using turbine extraction at intermediate pressure - Brayton cycle advanced according to Szewalski's idea," Energy, Elsevier, vol. 185(C), pages 763-786.
    2. Lecompte, Steven & Huisseune, Henk & van den Broek, Martijn & Vanslambrouck, Bruno & De Paepe, Michel, 2015. "Review of organic Rankine cycle (ORC) architectures for waste heat recovery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 47(C), pages 448-461.
    3. Vivian, Jacopo & Manente, Giovanni & Lazzaretto, Andrea, 2015. "A general framework to select working fluid and configuration of ORCs for low-to-medium temperature heat sources," Applied Energy, Elsevier, vol. 156(C), pages 727-746.
    4. Kevin McDonnell & Levente Molnár & Mary Harty & Fionnuala Murphy, 2020. "Feasibility Study of Carbon Dioxide Plume Geothermal Systems in Germany−Utilising Carbon Dioxide for Energy," Energies, MDPI, vol. 13(10), pages 1-24, May.
    5. Invernizzi, Costante M. & Iora, Paolo, 2016. "The exploitation of the physical exergy of liquid natural gas by closed power thermodynamic cycles. An overview," Energy, Elsevier, vol. 105(C), pages 2-15.
    6. Costante M. Invernizzi & Abubakr Ayub & Gioele Di Marcoberardino & Paolo Iora, 2019. "Pure and Hydrocarbon Binary Mixtures as Possible Alternatives Working Fluids to the Usual Organic Rankine Cycles Biomass Conversion Systems," Energies, MDPI, vol. 12(21), pages 1-17, October.
    7. Danieli, Piero & Rech, Sergio & Lazzaretto, Andrea, 2019. "Supercritical CO2 and air Brayton-Joule versus ORC systems for heat recovery from glass furnaces: Performance and economic evaluation," Energy, Elsevier, vol. 168(C), pages 295-309.
    8. Xu, Weicong & Zhao, Li & Mao, Samuel S. & Deng, Shuai, 2020. "Towards novel low temperature thermodynamic cycle: A critical review originated from organic Rankine cycle," Applied Energy, Elsevier, vol. 270(C).
    9. Invernizzi, Costante & Bombarda, Paola, 1997. "Thermodynamic performance of selected HCFS for geothermal applications," Energy, Elsevier, vol. 22(9), pages 887-895.
    10. Costante Mario Invernizzi, 2017. "Prospects of Mixtures as Working Fluids in Real-Gas Brayton Cycles," Energies, MDPI, vol. 10(10), pages 1-15, October.
    11. Costante Invernizzi & Marco Binotti & Paola Bombarda & Gioele Di Marcoberardino & Paolo Iora & Giampaolo Manzolini, 2019. "Water Mixtures as Working Fluids in Organic Rankine Cycles," Energies, MDPI, vol. 12(13), pages 1-17, July.
    12. Astolfi, Marco & Alfani, Dario & Lasala, Silvia & Macchi, Ennio, 2018. "Comparison between ORC and CO2 power systems for the exploitation of low-medium temperature heat sources," Energy, Elsevier, vol. 161(C), pages 1250-1261.
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    Cited by:

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    4. Ziwei Chen & Beini He & Xidong Wang, 2023. "Advanced Utilization Technologies of Secondary Energy and Resources from Energy-Intensive Industries," Energies, MDPI, vol. 16(7), pages 1-3, March.
    5. Mikielewicz, Jarosław & Ochrymiuk, Tomasz & Cenian, Adam, 2022. "Comparison of traditional with low temperature district heating systems based on organic Rankine cycle," Energy, Elsevier, vol. 245(C).
    6. Di Marcoberardino, G. & Morosini, E. & Manzolini, G., 2022. "Preliminary investigation of the influence of equations of state on the performance of CO2 + C6F6 as innovative working fluid in transcritical cycles," Energy, Elsevier, vol. 238(PB).
    7. Mikielewicz, Jarosław & Mikielewicz, Dariusz, 2023. "Comparison of traditional district heating with low temperature district heating systems featuring organic Rankine cycle and heat pump," Energy, Elsevier, vol. 281(C).
    8. Mikielewicz, Dariusz & Mikielewicz, Jarosław, 2022. "Analysis of Organic Rankine Cycle efficiency and vapor generator heat transfer surface in function of the reduced pressure," Energy, Elsevier, vol. 261(PB).

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