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Water Mixtures as Working Fluids in Organic Rankine Cycles

Author

Listed:
  • Costante Invernizzi

    (University of Brescia, Department of Mechanical and Industrial Engineering, via Branze 38, 25123 Brescia, Italy)

  • Marco Binotti

    (Politecnico di Milano, Department of Energy, via Lambruschini 4, 20156 Milano, Italy)

  • Paola Bombarda

    (Politecnico di Milano, Department of Energy, via Lambruschini 4, 20156 Milano, Italy)

  • Gioele Di Marcoberardino

    (University of Brescia, Department of Mechanical and Industrial Engineering, via Branze 38, 25123 Brescia, Italy)

  • Paolo Iora

    (University of Brescia, Department of Mechanical and Industrial Engineering, via Branze 38, 25123 Brescia, Italy)

  • Giampaolo Manzolini

    (Politecnico di Milano, Department of Energy, via Lambruschini 4, 20156 Milano, Italy)

Abstract

This work explores the possibility to adopt in organic Rankine cycle (ORC) plants mixtures of water (acting as solvent) plus an organic compound (acting as solute) as the working fluid. Initially an evaluation of the thermodynamic properties of the mixtures is performed, in order to assess their properties, and to point out the molar fractions which entail a near-azeotropic behaviour. Four species from three different classes of chemical compounds are investigated: 2,2,2-trifluoroethanol and n-butanol for alcohols, where the first is fluorinated, acetonitrile for nitrile class and 2-methylpyrazine as a heterocyclic aromatic compound. Simultaneously, the thermal stability of the pure substances considered as the possible solute for the mixtures is experimentally investigated in order to estimate the temperature applicability range. The ORC plant performance, from a low-enthalpy geothermal heat source (hot water stream from 100 to 200 °C), adopting the selected mixtures as the working fluid is finally evaluated, and the analysis includes a preliminary discussion on the turbine design; results are compared with respect to the reference case of a hypothetical plant adopting water as the working fluid.

Suggested Citation

  • Costante Invernizzi & Marco Binotti & Paola Bombarda & Gioele Di Marcoberardino & Paolo Iora & Giampaolo Manzolini, 2019. "Water Mixtures as Working Fluids in Organic Rankine Cycles," Energies, MDPI, vol. 12(13), pages 1-17, July.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:13:p:2629-:d:246671
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    References listed on IDEAS

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    Cited by:

    1. Yıldız Koç, 2019. "Parametric Optimisation of an ORC in a Wood Chipboard Production Facility to Recover Waste Heat Produced from the Drying and Steam Production Process," Energies, MDPI, vol. 12(19), pages 1-22, September.
    2. Costante M. Invernizzi & Abubakr Ayub & Gioele Di Marcoberardino & Paolo Iora, 2019. "Pure and Hydrocarbon Binary Mixtures as Possible Alternatives Working Fluids to the Usual Organic Rankine Cycles Biomass Conversion Systems," Energies, MDPI, vol. 12(21), pages 1-17, October.
    3. Xu, Weicong & Zhao, Li & Mao, Samuel S. & Deng, Shuai, 2020. "Towards novel low temperature thermodynamic cycle: A critical review originated from organic Rankine cycle," Applied Energy, Elsevier, vol. 270(C).
    4. Abubakr Ayub & Costante M. Invernizzi & Gioele Di Marcoberardino & Paolo Iora & Giampaolo Manzolini, 2020. "Carbon Dioxide Mixtures as Working Fluid for High-Temperature Heat Recovery: A Thermodynamic Comparison with Transcritical Organic Rankine Cycles," Energies, MDPI, vol. 13(15), pages 1-18, August.
    5. Kolahchian Tabrizi, Mehrshad & Bonalumi, Davide, 2022. "Techno-economic performance of the 2-propanol/1-butanol zeotropic mixture and 2-propanol/water azeotropic mixture as a working fluid in Organic Rankine Cycles," Energy, Elsevier, vol. 246(C).

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